Citation: FU Ying, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)][J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2269-2274. doi: 10.3866/PKU.WHXB20110908 shu

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]

1.
Beijing National Laboratory for Molecular Sciences BNLMS, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 20 May 2011
Available Online: 5 July 2011
Fund Project: 国家重大基础研究计划(973) (2010CB833103)资助项目 (973) (2010CB833103)

The solvothermal reactions of Sr(NO₃)₂ with 1,4-benzenedicarboxylic acid (BDC) in a mixture of H₂O/N,N'-dimethylformamide (DMF) resulted in a novel coordination polymer, [Sr(BDC) (H₂O)] (1), which was characterized by single crystal and variable temperature powder X-ray diffraction (VTPXRD), elemental analysis, infra-red (IR) spectroscopy, and thermogravimetric-mass spectrometric (TG-MS) analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with a=1.1854(2) nm, b=0.7122 (1) nm, and c=2.0031(4) nm. It is a three-dimensional (3D) framework consisting of zigzag chains that are formed by face-shared SrO₈ square antiprisms and bridging BDC ligands. TG-MS and VTPXRD studies revealed that the framework of compound 1 exhibited a high thermal stability.
- 1,4-Benzenedicarboxylic acid,
- Strontium,
- Solvothermal synthesis,
- Structure,
- Thermal property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H2O)]

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]