Citation: YUAN Wen-Hui, LI Bao-Qing, LI Li. Superior Graphene for Hydrogen Adsorption Prepared by the Improved Liquid Oxidation-Reduction Method[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2244-2250. doi: 10.3866/PKU.WHXB20110838 shu

Superior Graphene for Hydrogen Adsorption Prepared by the Improved Liquid Oxidation-Reduction Method

1.
1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China;
2. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 7 April 2011
Available Online: 28 June 2011
Fund Project: 国家自然科学基金(20976057)资助项目 (20976057)

Graphite oxide ( ) was prepared from liquid oxidation based on Hummers method and the graphene was then prepared using sodium borohydride to reduce the exfoliated graphite oxide by ultrasonication during which moderate sodium dodecyl benzene sulfonate (SDBS) was added into the suspension to reduce the agglomeration among the graphene layers and to obtain a stable graphene suspension. The as-prepared graphene was characterized by X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM). XRD results show that the crystal structures are different among graphite, graphite oxide, and graphene. SEM and TEM images show that graphene possesses a gridding structure, a smooth surface, and few defects. AFM analysis indicates that the thickness of the single layer graphene is about 1.3 nm while there are still a few double layers in the sample. The BET specific surface area of the graphene was about 1206 m²·g^-1 and its H₂ adsorption properties were investigated under high pressure. The samples prepared by liquid oxidation-reduction were compared with that prepared by the improved liquid oxidation-reduction method, which indicates that the addition of SDBS effectively reduces agglomeration among the graphene layers and this generates high quality graphene. The adsorption capacities of H₂ on graphene at 25 and 55 °C reached 1.7%(w) and 1.1%(w), respectively, which are much higher than that reported previously.
- Graphene,
- Graphite oxide,
- Hydrogen adsorption,
- Oxidation-reduction,
- Ultrasonic exfoliated
1. [1]
  (1) Haryanto, A.; Fernando, S.; Murali, N.; Adhikari, S. Energy and Fuels 2005, 19 (5), 2098.
2. [2]
  (2) Barelli, L.; Bidini, G.; Gallorini, F.; Servili, S. Energy 2008, 33 (4), 554.
3. [3]
  (3) Rosen, M. A. Energy 2010, 35, 1068.
4. [4]
  (4) Dillon, A. C.; Jones, K. M.; Bekkedahl, T. A.; Kiang, C. H.; Bethune, D. S.; Heben, M. J. Nature 1997, 386, 377.
5. [5]
  (5) Liu, C.; Fan, Y. Y.; Liu, M.; Cong, H. T.; Cheng, H. M.; Dresselhaus, M. S. Science 1999, 286, 1127.
6. [6]
  (6) Zhou, L.; Zhou, Y. P.; Sun, Y. Int. J. Hydrog. Energy 2004, 29 (5), 475.
7. [7]
  (7) Fan, Y. Y.; Liao, B.; Liu, M.;Wei, Y. L.; Lu, M. Q.; Cheng, H. M. Carbon 1999, 37, 1649.
8. [8]
  (8) Gupta, B. K.; Srivastava, O. N. Int. J. Hydrog. Energy 2001, 26, 857.
9. [9]
  (9) Zhou, L.; Zhou, Y. P.; Sun, Y. Int. J. Hydrog. Energy 2004, 29 (3), 319.
10. [10]
  (10) Huang, G. R.; Chen, J. Carbon Technologies 2009, 1 (28), 35.
11. [11]
  (11) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science 2004, 306, 666.
12. [12]
  (12) Allen, M. J.; Tung, V. C.; Kaner, R. B. Chem. Rev. 2010, 110, 132.
13. [13]
  (13) Stoller, M. D.; Park, S.; Zhu, Y.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8 (10), 3498.
14. [14]
  (14) Yang, N.; Zhai, J.;Wang, D.; Chen, Y.; Jiang, L. ACS Nano 2010, 4, 887.
15. [15]
  (15) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin. 2010, 26 (8), 2073. [胡耀娟, 金娟, 张卉, 吴萍, 蔡称心. 物理化学学报, 2010, 26 (8), 2073.]
16. [16]
  (16) Sridhar, V.; Jeon, J. H.; Oh, I. K. Carbon 2010, 48(10), 2953.
17. [17]
  (17) Wen, Z. L.; Yang, S. D.; Song, Q. J.; Hao, L.; Zhang, X. G. Acta Phys. -Chim. Sin. 2010, 26 (6), 1570. [温祝亮, 杨苏东, 宋启军, 郝亮, 张校刚. 物理化学学报, 2010, 26 (6), 1570.]
18. [18]
  (18) Wu, X. Q.; Zong, R. L.; Mou, H. J.; Zhu, Y. F. Acta Phys. -Chim. Sin. 2010, 26 (11), 3002. [吴小琴, 宗瑞隆, 牟豪杰, 朱永法. 物理化学学报, 2010, 26 (11), 3002.]
19. [19]
  (19) Li, Y. X.;Wei, Z. D.; Zhao, Q. L.; Ding,W.; Zhang, Q.; Chen, S. G. Acta Phys. -Chim. Sin. 2011, 27 (4), 858. [李云霞, 魏子栋, 赵巧玲, 丁炜, 张骞, 陈四国. 物理化学学报, 2011, 27 (4), 858.]
20. [20]
  (20) Srinivas, G.; Zhu, Y.W.; Piner, R.; Skipper, R.; Ellerby, M.; Ruoff, R. Carbon 2010, 48 (3), 630.
21. [21]
  (21) Ghosh, A.; Subrahmanyam, K. S.; Krishna, K. S.; Datta, S.; vindaraj, A.; Pati, S. K.; Rao, C. N. R. J. Phys. Chem. C 2008, 112, 15704.
22. [22]
  (22) Ma, L. P.;Wu, Z. S.; Li, J.;Wu, E. D.; Ren,W. C.; Cheng, H. M. Hydrogen Energy 2009, 34 (5), 2329.
23. [23]
  (23) Bourlinos, A. B.; urnis, D.; Petridis, D.; Szabó, T.; Szeri, A.; Dékány, I. Langmuir 2003, 19, 6050.
24. [24]
  (24) Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.;Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Carbon 2007, 45, 1558.
25. [25]
  (25) Lotya, M.; King, P. J.; Khan, U.; De, S.; Coleman, J. N. ACS Nano 2010, 4 (6), 3155.
26. [26]
  (26) Xu, Y. X.; Bai, H.; Lu, G.W.; Li, C.; Shi, G. Q. J. Am. Chem. Soc. 2008, 130 (18), 5856.
27. [27]
  (27) Hummers, S.; Offeman, R. J. Am. Chem. Soc. 1958, 80 (6), 1339.
28. [28]
  (28) Wang, J.; Han, Z. D. Polym. Adv. Technol. 2006, 17 (4), 335.
29. [29]
  (29) Lee, S.; Lim, S.; Lim, E.; Lee, K. K. Journal of Physics and Chemistry of Solids 2010, 71 (4), 483.
30. [30]
  (30) Ferrari, A. C.; Robertson, J. J. Phys. Rev. B 2000, 61 (20),14095.
31. [31]
  (31) mez-Navarro, C.;Weitz, R. T.; Bittner, A. M.; Scolari, M.; Mews, A.; Burghard, M.; Kern, K. Nano Lett. 2007, 7 (11), 3499.
32. [32]
  (32) Jung, I.; Pelton, M.; Piner, R.; Dikin, D.A.; Stankovich, S.; Watcharotone, S. Nano. Lett. 2007, 7 (12), 3569.
33. [33]
  (33) Szabo, T.; Berkesi, O.; Dekany, I. Carbon 2005, 43 (15), 3186.
34. [34]
  (34) Jhi, S. H.; Kwon, Y. K.; Bradley, K. P.; Gabriel, J. C. Solid State Communications 2004, 129, 769.
35. [35]
  (35) Gigras, A.; Bhatia, S. K.; Anil Kumar, A.V.; Myers, A. L. Carbon 2007, 45 (5), 1043.
36. [36]
  (36) Bhatia, S. K.; Myers, A. L. Langmuir 2006, 22 (4), 1688.
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