Citation: WANG Xiao-Rong, HAO Guang-Ping, LU An-Hui, LI Wen-Cui. Adsorption and Release Behavior of Vitamin B12 in Tubular Structured Ordered Mesoporous Carbon[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2239-2243. doi: 10.3866/PKU.WHXB20110834 shu

Adsorption and Release Behavior of Vitamin B12 in Tubular Structured Ordered Mesoporous Carbon

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China

Received Date: 18 April 2011
Available Online: 27 June 2011
Fund Project: 高等学校博士学科点专项科研基金(20100041110017) 资助项目 (20100041110017)

Ordered mesoporous carbon with hexa nal arrays consisting of tubular-type pores (CMK-5) was synthesized via a nanocasting process by the direct use of SBA-15 as a template, furfuryl alcohol as a carbon source and oxalic acid as the catalyst. The structure of CMK-5 was analyzed by different techniques including scanning electron microscopy, powder X-ray diffraction and N₂ adsorption analysis. The specific surface area and pore volume were found to be 1856 m²·g^-1 and 2.10 cm³·g^-1, respectively, with mesopore sizes concentrated at 3.1 and 5.5 nm. Because of the unique structure the adsorption capacities of CMK-5 towards vitamin B12 was found to be as high as 943 mg·g^-1 in a short period of 120 min, which is significantly higher than that of commercial activated carbon. The composites of CMK-5 and vitamin B12 without any treatment gave slow-release performance in a simulated body fluid. The concentration of the release solutions remained 9 mg·L^-1 under dynamic conditions. A high loading capacity and slow release rate of vitamin B12 on the CMK-5 support suggested that CMK-5 might have a potential application in drug delivery.
- Ordered mesoporous carbon,
- Dual-model pore channel,
- Vitamin B12,
- Adsorption,
- Drug release
1. [1]
  (1) Hartmann, M. Chem. Mater. 2005, 17, 4577.
2. [2]
  (2) Wang, S. B. Microporous Mesoporous Mat. 2009, 117, 1.
3. [3]
  (3) Uhrich, K. E.; Cannizzaro, S. M.; Langer, R. S.; Shakesheff, K. M. Chem. Rev. 1999, 99, 3181.
4. [4]
  (4) He, Q. J.; Shi, J. L. J. Mater. Chem. 2011, 21, 5845.
5. [5]
  (5) Vallet-Regi, M.; Rámila, A.; Real, R. P.; Pérez-Pariente, J. Chem. Mater. 2003, 15, 500.
6. [6]
  (6) Yang, J. B.; Ling, L. C.; Liu, L.; Kang, F. Y.; Huang, Z. H.;Wu, H. Carbon 2002, 40, 911.
7. [7]
  (7) Lu, Y. M.; ng, Q. M.; Liang, J. Acta Phys. -Chim. Sin. 2009, 25 (8), 1697. [卢月美, 巩前明, 梁吉. 物理化学学报, 2009, 25 (8), 1697.]
8. [8]
  (8) Yang, J. B.; Kang, F. Y; Huang, Z. H. J. Tsinghua.Univ. (Sci. Tech.) 2002, 16 (5), 688. [杨俊兵, 康飞宇, 黄正宏. 清华大学学报(自然科学版), 2002, 16 (5), 688.]
9. [9]
  (9) Sheng,W. Z.; Zheng, J. T. J. Mater. Sci. 2004, 39, 4693.
10. [10]
  (10) Yang, Q.;Wang, S. C.; Fan, P.W.;Wang, L. F.; Di, Y.; Lin, K. F.; Xiao, F. S. Chem. Mater. 2005, 17, 5999.
11. [11]
  (11) Doadrio, A. L.; Sousa, E. M. B.; Doadrio, J. C.; Pariente, J. P.; Izquierdo-Barba, I.; Vallet-Regí, M. J. Control. Release 2004, 97, 125.
12. [12]
  (12) Arcos, D.; López-Noriega, A.; Ruiz-Hern?ndez, E.; Terasaki, O.; Vallet-Regí, M. Chem. Mater. 2009, 21, 1000.
13. [13]
  (13) Yu, H.; Zhai, Q. Z. Microporous Mesoporous Mat. 2009, 123, 298.
14. [14]
  (14) Lu, A. H.; Nitz, J. J.; Comotti, M.;Weidenthaler, C.; Schlichte, K.; Lehmann, C.W.; Terasaki, O.; Schüth, F. J. Am. Chem. Soc. 2010, 132, 14152.
15. [15]
  (15) Peng, X.; Cao, D. P.;Wang,W. C. Langmuir 2009, 25 (18), 10863.
16. [16]
  (16) Kor?nyi, T. I.; Vít, Z. K.; Nagy, J. B. Catal. Today 2008, 130, 80.
17. [17]
  (17) Hao, G. P.; Li,W. C.;Wang, S.; Zhang, S. F.; Lu, A. H. Carbon 2010, 48, 3330.
18. [18]
  (18) He, J. L. Preparation of Porous Carbons and Its Performance on Adsorption. Master Dissertation, Hunan University, Changsha, 2006. [何姣莲. 中孔炭的制备及其吸附性能研究[D]. 长沙: 湖南大学, 2006.]
19. [19]
  (19) Lu, A. H.; Li,W. C.; Schmidt,W.; Kiefer,W.; Schüth, F. Carbon 2004, 42, 2939.
20. [20]
  (20) Oyane, A.; Kim, H. M.; Furuya, T.; Kokubo, T.; Miyazaki, T. J. Biomed. Mater. Res. A 2003, 65A (2), 188.
21. [21]
  (21) Lu, A. H.; Schmidt,W.; Spliethoff, B.; Schüth, F. Adv. Mater. 2003, 15, 1602.
22. [22]
  (22) Zhuo, G.; Zhu, G. S.; Gao, B.; Zhang, D. L.; Tian, G.; Chen, Y.; Zhang,W.W.; Qiu, S. L. Carbon 2005, 43, 2344.
23. [23]
  (23) Zhuo, G.;Wang, L. F.; Gao, Z.; Zhang,W.W. Chin. Chem. Lett. 2007, 18, 233.
24. [24]
  (24) Liu, C. Y.;Wang, S.Y.; Rong, Z. H.;Wang, X. Q.; Gu, G. N.; Sun,W. J. J. Non-Cryst. Solids 2010, 356, 1246.
25. [25]
  (25) Joo, S. H.; Choi, S. J.; Oh, I.; Kwak, J.; Liu, Z.; Terasaki, O.; Ryoo, R. Nature 2001, 412, 169.
26. [26]
  (26) Ryoo, R.; Joo, S. H.; Kruk, M.; Jaroniec, M. Adv. Mater. 2001, 13, 677.
27. [27]
  (27) Lu, A. H.; Schüth, F. Adv. Mater. 2006, 18, 1793.
28. [28]
  (28) Lund, K.; Muroyama, N.; Terasaki, O. Microporous Mesoporous Mat. 2010, 128, 71.
29. [29]
  (29) Luo, B.; Song, X. J.; Zhang, F.; Xia, A.; Yang,W. Y.; Hu, J. H.; Wang, C. C. Langmuir 2010, 26, 1674.
30. [30]
  (30) Shome, A.; Debnath, S.; Das, P. K. Langmuir 2008, 24, 4280.
31. [31]
  (31) Song, F.; Zhang, L. M.; Shi, J. F.; Li, N. N. Colloids. Surf. B: Biointerfaces 2010, 79, 142.
32. [32]
  (32) Wen, X.; Cao, X. L.; Yin, Z. H.;Wang, T.; Zhao, C. S. Carbohydr. Polym. 2009, 78 (5), 193.
1. [1]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
2. [2]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
5. [5]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
9. [9]
  Yukun Xing , Xiaoyu Xie , Fangfang Chen . A Sunlit Gift: Vitamin D. University Chemistry, 2024, 39(9): 28-34. doi: 10.12461/PKU.DXHX202402006
10. [10]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
11. [11]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
12. [12]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
13. [13]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
14. [14]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
15. [15]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
16. [16]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
17. [17]
  Liwei Wang , Guangran Ma , Li Wang , Fugang Xu . A Comprehensive Analytical Chemistry Experiment: Colorimetric Detection of Vitamin C Using Nanozyme and Smartphone. University Chemistry, 2024, 39(8): 255-262. doi: 10.3866/PKU.DXHX202312094
18. [18]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
19. [19]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
20. [20]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

Get Citation

PDF

XML

Metrics

PDF Downloads(975)
Abstract views(3226)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142