Citation: LIU Yun-Long, WANG Wen-Jun, GAO Xue-Xi, XU Jian-Hua. Second Harmonic Generation Properties of Centrosymmetric Bisphthalocyaninato Thulium in Langmuir-Blodgett Films[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1985-1989. doi: 10.3866/PKU.WHXB20110818 shu

Second Harmonic Generation Properties of Centrosymmetric Bisphthalocyaninato Thulium in Langmuir-Blodgett Films

1.
1. School of Physical Science & Information Technology, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China;
2. State Key Laboratory of Precision Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062, P. R. China

Received Date: 6 April 2011
Available Online: 20 June 2011
Fund Project: 国家自然科学基金(10874063) (10874063) 山东省科技攻关项目(2010GGX10127) (2010GGX10127)山东省高等学校科技计划项目(J10LA60)资助 (J10LA60)

The second order nonlinear optical properties of sandwich thulium bisphthalocyanine (TmPc₂) molecule Langmuir-Blodgett (LB) films were investigated using the second harmonic generation (SHG)method. The dependence of the second harmonic intensity on the incident angle of the fundamental beam was measured and the mechanisms of nonlinearity were discussed briefly. The experimental results indicated that the second harmonic signal intensity was very strong and its maximum was obtained at an incident angle of 45°. The second order nonlinear optical susceptibility χ⁽²⁾ was about 1.152×10^-8 esu and the hyperpolarizability β was about 1.905×10^-30 esu. By measuring the polarization properties of the second harmonic signal for the LB film and comparing this with the theoretical analysis, we found that the origin of the second harmonic generation was attributed to the electric quadrupole mechanism for the TmPc₂ molecule.
- Terbium bisphthalocyanine,
- Langmuir-Blodgett film,
- Nonlinear optics,
- Second harmonic generation,
- Electric quadrupole mechanism
1. [1]
  
  (1) Ho, Z. Z.; Ju, C. Y.; Hetherington,W. M., III. J. Appl. Phys. 1987, 62, 716.
2. [2]
  (2) Liu, Y. Q.; Xu, Y.; Zhu, D. B.;Wada, T.; Sasabe, H.; Zhao, X. S.; Xie, X. M. J. Phys. Chem. 1995, 99, 6957.
3. [3]
  (3) Dennis, K. P. Ng; Jiang, J. Z. Chem. Soc. Rev. 1997, 26, 433.
4. [4]
  (4) He, Y.; Xiong, Y. J.; Zhu, Q. H.; Kong, F. A. Acta Phys. -Chim. Sin. 1999, 15, 636. [何勇, 熊轶嘉, 朱起鹤, 孔繁敖. 物理化学学报, 1999, 15, 636.]
5. [5]
  (5) Diaz-Garcia, M. A.; Ledoux, I.; Duro, J. A.; Torres, T.; Agullo-Lopez, F.; Zyss, J. J. Phys. Chem. 1994, 98, 8761.
6. [6]
  (6) Wang, Y. F.; Zhang, X. R.; Ye, Y. C.; Liang, D. J.;Wang, Y.;Wu, K. Acta Phys.-Chim. Sin. 2010, 26, 933. [王永峰, 张鑫然, 叶迎春, 梁德建, 王远, 吴凯. 物理化学学报, 2010, 26, 933.]
7. [7]
  (7) Souto, J.; De Saja, J. A.; Aroca, R.; Rodriguez, M. L. Synth. Met. 1993, 54, 229.
8. [8]
  (8) Shirk, J. S.; Lindle, J. R.; Bartoli, F. J.; Hoffman, C. A.; Kafafi, Z. H.; Snow, A.W. Appl. Phys. Lett. 1989, 55, 1287.
9. [9]
  (9) Kanbara, H.; Maruno, T.; Yamashita, A.; Matsumoto, S.; Hayashi, T.; Konami, H.; Tanaka, N. J. Appl. Phys. 1996, 80, 3674.
10. [10]
  (10) Feng, J. K.; Li, J.; Sun, J. Z. Acta Chim. Sin. 1994, 52, 539. [封继康, 李君, 孙家钟. 化学学报, 1994, 52, 539.]
11. [11]
  (11) Sastre, A.; Díaz-García, M. A.; Del-Rey, B.; Dhenaut, C.; Zyss, J.; Ledoux, I.; Agulló-López, F.; Torres, T. J. Phys. Chem. A 1997, 101, 9773.
12. [12]
  (12) Kumagai, K.; Mizutani, G.; Tsukioka, H.; Yamauchi, T.; Ushioda, S. Phys. Rev. B 1993, 48, 14488.
13. [13]
  (13) Hoshi, H.; Yamada, T.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Phys. Rev. B 1995, 52, 12355.
14. [14]
  (14) Yamada, T.; Hoshi, H.; Manaka, T.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Phys. Rev. B 1996, 53, 13314.
15. [15]
  (15) Liu, Y. L.;Wang,W. J.; Gao, X. X.; Li, S. H. Spectroscopy and Spectral Analysis 2008, 28, 422. [刘云龙, 王文军, 高学喜, 李淑红. 光谱学与光谱分析, 2008, 28, 422.]
16. [16]
  (16) Ashwell, G. J.; Hargreaves, R. C.; Baldwin, C. E.; Bahra, G. S.; Brown, C. R. Nature 1992, 357, 393.
17. [17]
  (17) Jerphagnon, J.; Kurtz, S. K. Phys. Rev. B 1970, 1, 1739.
18. [18]
  (18) Liu, Y. Q.; Shigehara, K.; Hara, M.; Yamada, A. J. Am. Chem. Soc. 1991, 113, 440.
19. [19]
  (19) Lupo, D.; Prass,W.; Scheunemann, U.; Laschewsky, A.; Ringsdorf, R.; Ledoux, I. J. Opt. Soc. Am. B 1988, 5, 300.
20. [20]
  (20) Jiang, J. Z.; Liu,W.; Lin, J. M.;Wu, J. P. Chemistry 1997, 7, 14. [姜建壮, 刘伟, 林吉茂, 吴基培. 化学通报, 1997, 7, 14.]
21. [21]
  (21) Liu, Y. L.;Wang,W. J.; Gao, X. X.; Li, S. H.; Li, Y. Spectroscopy and Spectral Analysis 2008, 28, 2375. [刘云龙, 王文军, 高学喜, 李淑红, 李云. 光谱学与光谱分析, 2008, 28, 2375.]
22. [22]
  (22) Pershan, P. S. Phys. Rev. 1963, 130, 919.
23. [23]
  (23) Bloembergen, N.; Chang, R. K.; Jha, S. S.; Lee, C. H. Phys. Rev. 1968, 174, 813.
24. [24]
  (24) Yamada, T.; Hoshi, H.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Jpn. J. Appl. Phys. 1995, 34, L299.
25. [25]
  (25) Adler, E. Phys. Rev. 1964, 134, A728.
26. [26]
  (26) Qin, S. J.; You,W. M.; Su, Z. B. Phys. Rev. B 1993, 48, 17562.
1. [1]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
2. [2]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
3. [3]
  Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
4. [4]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
5. [5]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
6. [6]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
7. [7]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
8. [8]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
9. [9]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
10. [10]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
11. [11]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
12. [12]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
13. [13]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
14. [14]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
15. [15]
  Xianggui Kong , Wenying Shi . Comprehensive Chemical Experimental Design of Optically Encrypted Materials. University Chemistry, 2025, 40(3): 355-362. doi: 10.12461/PKU.DXHX202406067
16. [16]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Yuyang Xu , Ruying Yang , Yanzhe Zhang , Yandong Liu , Keyi Li , Zehui Wei . Research Progress of Aflatoxins Removal by Modern Optical Methods. University Chemistry, 2024, 39(11): 174-181. doi: 10.12461/PKU.DXHX202402064
19. [19]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
20. [20]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

Get Citation

PDF

XML

Metrics

PDF Downloads(824)
Abstract views(2387)
HTML views(88)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142