Citation: JIA Li-Hui, LIU An-Chang, MU Zong-E, CHEN Yun-Feng. Magnetostructural Correlation Study of a Novel Strong Antiferromagnetic Dimer Copper(II) Coordination Complex with Mono-Methyl Phthalate[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1595-1599. doi: 10.3866/PKU.WHXB20110736 shu

Magnetostructural Correlation Study of a Novel Strong Antiferromagnetic Dimer Copper(II) Coordination Complex with Mono-Methyl Phthalate

1.
1. Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Chemical and Technology, Wuhan 430074, P. R. China;
2. School of Physics, Huazhong University of Science and Technology, Wuhan 430074, P. R. China

Received Date: 29 March 2011
Available Online: 3 June 2011
Fund Project: 国家自然科学基金(21002076)资助项目 (21002076)

We prepared and obtained a novel dinuclear copper(II) coordination complex [Cu₂(mMP)₂(H₂O)₂]₂·2H₂O (1) using mono-methyl phthalate as a ligand (mMP is a mono-methyl phthalate or 1,2- benzenedicarboxylate monomethyl ester). The crystal structure of complex 1 was characterized by elemental analysis, IR spectroscopy, and X-ray analysis. This tetra-carboxylato-bridged dinuclear complex adopts a dimeric paddle-wheel cage structure and the coordination configuration around each copper(II) cation is square-pyramidal with four oxygen atoms of the carboxylate groups from four different mono- methyl phthalate ligands and one oxygen atom of water at the apical position. Intermolecular hydrogen bonds are found between the hydrogen atoms of the coordinated or uncoordinated water and the oxygen atoms of the carboxyl from the adjacent molecules and it forms a three-dimensional (3D) network structure. The magnetic data for complex 1 indicate a strong intramolecular antiferromagnetic interaction between the two paramagnetic metal ions with a magnetic coupling constant of 2J=-324 cm^-1. In this paper, we analyzed the magnetostructural correlation of complex 1 in detail and discuss the main factor that determines the strong antiferromagnetic interaction in dimeric copper(II) carboxylates. Compared with the structure and the magnetic property of other related complexes, the main factor that determines the strong antiferromagnetic interaction in the dimeric copper(II) carboxylate is an electronic structure of the bridging O－C－O moiety.
- Magnetostructural correlation,
- Strong antiferromagnetic interaction,
- tetra-carboxylato-bridged dinuclear copper(II),
- Mono-methyl phthalate,
- Electronic structure
1. [1]
  
  (1) Kahn, O. Molecular Magnetism;Weinheim: VCH, 1993.
2. [2]
  (2) Gatteschi, D.; Kahn, O.; Miller, J. S. Magnetic Molecualr Materials, NATO ASI Series E198; Dordrecht: Kluwer, 1991.
3. [3]
  (3) Mroziński, J. Coord. Chem. Rev. 2005, 249, 2534.
4. [4]
  (4) Steel, P. J. Coord. Chem. Rev. 1990, 106, 227.
5. [5]
  (5) Kahn, O. Angew. Chem. Int. Edit. 1985, 24, 834.
6. [6]
  (6) Carlin, R. L. Magnetochemistry; Springer-Verlag: Berlin, 1986; pp 34-126.
7. [7]
  (7) Mortensen, G. K.; Main, K. M.; Andersson, A. M.; Leffers, H.; Skakkeb?k, N. E. Anal. Bioanal. Chem. 2005, 382, 1084.
8. [8]
  (8) Main, K. M.; Mortensen, G. K.; Kaleva, M. M.; Boisen, K. A.; Damgaard, I. N.; Chellakooty, M.; Schmidt, I. M.; Suomi, A. M.; Virtanen, H. E.; Petersen, J. H.; Andersson, A. M.; Toppari, S.; Niels, E. Environmental Health Perspectives 2006, 114 (2), 270.
9. [9]
  (9) Alfonso, L.; Zimnik, S.; Heinz, N. Toxicology and Applied Pharmacology 2003, 188 (1), 14.
10. [10]
  (10) Sussanne, J.; Anders, B. Environmental Toxicology and Chemistry 2003, 22 (12), 3037.
11. [11]
  (11) Jia, L. H.; Liu, Z. L.; Liu,W.; Gu, Y. F.; Yao, K. L. Chin. J. Inorg. Chem. 2008, 24 (2), 289. [贾丽慧, 刘祖黎, 刘蔚, 谷云飞, 姚凯伦. 无机化学学报, 2008, 24 (2), 289.]
12. [12]
  (12) Mulay, L. N.; Boudreaux, E. A. Theroy and Applications of Molecular Diamagnetism;Wiley: New York, 1976.
13. [13]
  (13) Sheldrick, G. M. SHELXL-97; Program zur Verfeinerung von Kristallstrukturen: Göttingen, 1997.
14. [14]
  (14) Sheldrick, G. M. SHELXS-97; Program zur Lösung von Kristallstrukturen: Göttingen, 1997.
15. [15]
  (15) Melnik, M.; Kabešová, M.; Koman, M.; Macášková, L?.; Garaj, J.; Holloway, C. E.; Valent, A. J. Coord. Chem. 1988, 45, 147.
16. [16]
  (16) Kato, M.; Muto, Y. Coord. Chem. Rev. 1988, 92, 45
17. [17]
  (17) Doedens, R. J. Prog. Inorg. Chem. 1976, 21, 209.
18. [18]
  (18) Erre, L. S.; Micera, G.; Piu, P.; Cariati, F.; Ciani, G. Inorg. Chem. 1985, 24, 2297.
19. [19]
  (19) Brown, G. M.; Chidambaram, R. Acta Cryst. B 1973, 29, 2393.
20. [20]
  (20) Meester, P.; Fletcher, S. R.; Skapski, A. C. J. Chem. Soc. Dalton Trans. 1973, 2575.
21. [21]
  (21) Harrison,W.; Rettig, S.; Trotter, J. J. Chem. Soc. Dolton Trans. 1972, 1852.
22. [22]
  (22) Koh, Y. B.; Christoph, G. G. Inorg. Chem. 1979, 18, 1122.
23. [23]
  (23) Brian, R. F.; White, D. H. Acta Cryst. B 1982, 38, 1014.
24. [24]
  (24) Bleaney, B.; Bowers, K. D. Proc. R. Soc. A 1952, 214, 451.
25. [25]
  (25) Agterberg, P. F.; Kluit, J. H.; Driessen,W. L.; Reedijk, J. Inorg. Chim. Acta 1998, 267, 183.
26. [26]
  (26) Kawata, T.; Uekusa, H.; Ohba, S.; Furukawa, T.; Tokii, T.; Muto, Y.; Kato, M. Acta Cryst. B 1992, 48, 253.
27. [27]
  (27) Kahn, O. Magnetostructural Correlations in Exchange Coupled Systems; Dordrecht: Reidel, 1985; pp 35-56.
28. [28]
  (28) (a) odenough, J. B. Phys. Rev. 1955, 100, 564; J. Phys. Chem. Solids 1958, 6, 287.(b) odenough, J. B. Magnetism and the Chemical Bond; Interscience: New York, 1963.(c) Kanamori, J. J. Phys. Chem. Solids 1959, 10, 87.
1. [1]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
2. [2]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
5. [5]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
6. [6]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
9. [9]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
10. [10]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
11. [11]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
12. [12]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
13. [13]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
14. [14]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
15. [15]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
16. [16]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
17. [17]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
18. [18]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
19. [19]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
20. [20]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370

Get Citation

PDF

XML

Metrics

PDF Downloads(1060)
Abstract views(2606)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142