Citation: ZHAO Peng-Fei, JI Sheng-Fu, WEI Ni, MA Qian, LIU Hui, LI Cheng-Yue. Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1737-1742. doi: 10.3866/PKU.WHXB20110728 shu

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 29 December 2010
Available Online: 1 June 2011
Fund Project: 国家基础研究重大项目计划(973) (2006CB202503)基金资助 (973) (2006CB202503)

The catalyst precursors of B-Ni₂P/SBA-15 were synthesized by co-impregnation using (NH₄)₂HPO₄ as the source of phosphorus, Ni(NO)₃ as the source of nickel and H₃BO₃ as the source of boron. The B-Ni₂P/SBA-15 catalysts with an initial P/Ni molar ratio of 0.8 and a boron content from 0.35% to 2.10%(w) were prepared by temperature-programmed reduction in a H₂ flow. The structure of the catalysts was characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscopy (TEM) and NH₃ temperature-programmed desorption (NH₃-TPD). The catalytic performances of hydrodesulfurization (HDS) were evaluated in a fixed-bed microreactor using dibenzothiophene (DBT) as a model compound. The results showed that the B-Ni₂P/SBA-15 catalysts still retained mesoporous structure. The Ni₂P phase was mainly active phases in all the catalysts. The proper addition of boron reduced the Ni₂P active phases but increased the specific surface area of the catalysts. The amount of acid in B-Ni₂P/SBA-15 also increased with addition of boron. When the reaction temperature was increased from 300 to 360 ℃, the HDS conversion of DBT over the catalyst clearly improved with an increase in the content of boron. The B-Ni₂P/SBA-15 catalyst with a boron content of 1.40%(w) had the best catalytic activity. The mechanism of the HDS of DBT consisted of main direct desulfurization (DDS) over the B-Ni₂P/SBA-15 catalysts.
- Hydrodesulfurization,
- SBA-15,
- Ni₂P,
- Dibenzothiophene,
- Boron
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni2P/SBA-15 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts