Citation: ZHAO Peng-Fei, JI Sheng-Fu, WEI Ni, MA Qian, LIU Hui, LI Cheng-Yue. Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni2P/SBA-15 Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1737-1742. doi: 10.3866/PKU.WHXB20110728 shu

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni2P/SBA-15 Catalysts

  • Received Date: 29 December 2010
    Available Online: 1 June 2011

    Fund Project: 国家基础研究重大项目计划(973) (2006CB202503)基金资助 (973) (2006CB202503)

  • The catalyst precursors of B-Ni2P/SBA-15 were synthesized by co-impregnation using (NH4)2HPO4 as the source of phosphorus, Ni(NO)3 as the source of nickel and H3BO3 as the source of boron. The B-Ni2P/SBA-15 catalysts with an initial P/Ni molar ratio of 0.8 and a boron content from 0.35% to 2.10%(w) were prepared by temperature-programmed reduction in a H2 flow. The structure of the catalysts was characterized by X-ray diffraction (XRD), N2 adsorption-desorption, transmission electron microscopy (TEM) and NH3 temperature-programmed desorption (NH3-TPD). The catalytic performances of hydrodesulfurization (HDS) were evaluated in a fixed-bed microreactor using dibenzothiophene (DBT) as a model compound. The results showed that the B-Ni2P/SBA-15 catalysts still retained mesoporous structure. The Ni2P phase was mainly active phases in all the catalysts. The proper addition of boron reduced the Ni2P active phases but increased the specific surface area of the catalysts. The amount of acid in B-Ni2P/SBA-15 also increased with addition of boron. When the reaction temperature was increased from 300 to 360 ℃, the HDS conversion of DBT over the catalyst clearly improved with an increase in the content of boron. The B-Ni2P/SBA-15 catalyst with a boron content of 1.40%(w) had the best catalytic activity. The mechanism of the HDS of DBT consisted of main direct desulfurization (DDS) over the B-Ni2P/SBA-15 catalysts.

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    1. [1]

      (1) Cheng,W.; Zhang, J. Y.;Wang, R. J.;Wang, Y. Q.; He, F. Acta Phys. -Chim. Sin. 1999, 15, 647. [程伟, 张继炎, 王日杰, 王亚权, 何菲. 物理化学学报, 1999, 15, 647.]

    2. [2]

      (2) Li, X. S.; Hou, Z. S.; Xin, Q.; Guo, X. X. Acta Phys. -Chim. Sin. 1993, 9, 63. [李新生, 侯震山, 辛勤, 郭燮贤. 物理化学学报, 1993, 9, 63.]

    3. [3]

      (3) Li, X.; Zhang, Y. L.;Wang, A. J.;Wang, Y.; Hu, Y. K. Catal. Commun. 2010, 11, 1129.

    4. [4]

      (4) Lee, Y. K.; Shu, Y. Y.; Oyama, S. T. Appl. Catal. A 2007, 322, 191.  

    5. [5]

      (5) Montesinos, C.; Zepeda, T.; Pawelec, B.; Lima, E.; Fierro, J. G.; Olivas, A.; Reyes, J. Appl. Catal. A 2008, 334, 330.  

    6. [6]

      (6) Trawczyáski, J. Appl. Catal. A 2000, 197, 289.  

    7. [7]

      (7) Lu, M. H.;Wang, A. J.; Li, X.; Duan, X. P.; Hu, Y. K. Acta Petro. Sin. (Petrol Proces Sec) 2006, 22, 33. [鲁墨弘, 王安杰, 李翔, 段新平, 胡永康. 石油学报(石油加工), 2006, 22, 33.]

    8. [8]

      (8) Abu, I.; Smith, K. Appl. Catal. A 2007, 328, 58.  

    9. [9]

      (9) Song, L.; Li,W.;Wang, G.; Zhang, M.; Tao, K. Cata1. Today 2007, 125, 137.  

    10. [10]

      (10) Lee, Y.; Oyama, S. J. Catal. 2006, 239, 376.  

    11. [11]

      (11) Sawhill, S.; Layman, K.; vanWyk, D.; Engelhard, M.;Wang, C.; Bussell, M. J. Catal. 2005, 231, 300.  

    12. [12]

      (12) Huang, X. F.; Ji, S. F.;Wu, P. Y.; Liu, Q. Q.; Liu, H.; Zhu, J. Q.; Li, C. Y. Acta Phys. -Chim. Sin. 2008, 24, 1773. [黄晓凡, 季生福, 吴平易, 刘倩倩, 刘辉, 朱吉钦, 李成岳. 物理化学学报, 2008, 24, 1773.]

    13. [13]

      (13) Usman, U.; Takaki, M.; Kubota, T.; Okamoto, Y. Appl. Catal. A. 2005, 286, 148.  

    14. [14]

      (14) Parks, G. L.; Pease, M. L.; Burns, A.W.; Layman, K. A.; Bussell, M. E.;Wang, X.; Hanson, J.; Rodriguez, J. J. Catal. 2007, 246, 277.  

    15. [15]

      (15) Rayo, P.; Rana, M.; Ramírez, J.; Ancheyta, J.; Elguezabal, A. Catal. Today 2008, 130, 283.  

    16. [16]

      (16) Ferdous, D.; Dalai, A. K.; Adjaye, J. Appl. Catal. A 2004, 260, 137.  

    17. [17]

      (17) Korányi, T.; Vít, Z.; Poduval, D.; Ryoo, R.; Kim, H. S.; Hensen, E. M. J. Catal. 2008, 253, 119.  

    18. [18]

      (18) Duan, X.; Teng, Y.;Wang, A.; Koganb, V. M.; Li, X.;Wang, Y. J. Catal. 2009, 261, 232.  

    19. [19]

      (19) Shang, H. Y.; Liu, C. G.; Chai, Y. M.; Xing, J. X. Acta Chim. Sin. 2004, 62, 888. [商红岩, 刘晨光, 柴永明, 邢金仙. 化学学报, 2004, 62, 888.]

    20. [20]

      (20) Liu, B. J.; Zheng, Y. Y.; Meng, Q. M.; Jiang, Y. T.; Sheng, S. S.; Yang,W. S.; Xiong, G. X. J. Mol. Catal. 2004, 18, 447. [刘百军, 郑宇印, 孟庆民, 蒋应田, 盛世善, 杨维慎, 熊国兴. 分子催化, 2004, 18, 447.]

    21. [21]

      (21) Moses, P.; Hinnemann, B.; Tops?e, H.; N?rskov, J. K. J. Catal. 2007, 248, 188.  

    22. [22]

      (22) Chen, T.;Wang, C. M.;Wang, I.; Tsai, T. C. J. Catal. 2010, 272, 28.  


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