Citation: ZHAO Peng-Fei, JI Sheng-Fu, WEI Ni, MA Qian, LIU Hui, LI Cheng-Yue. Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1737-1742. doi: 10.3866/PKU.WHXB20110728 shu

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 29 December 2010
Available Online: 1 June 2011
Fund Project: 国家基础研究重大项目计划(973) (2006CB202503)基金资助 (973) (2006CB202503)

The catalyst precursors of B-Ni₂P/SBA-15 were synthesized by co-impregnation using (NH₄)₂HPO₄ as the source of phosphorus, Ni(NO)₃ as the source of nickel and H₃BO₃ as the source of boron. The B-Ni₂P/SBA-15 catalysts with an initial P/Ni molar ratio of 0.8 and a boron content from 0.35% to 2.10%(w) were prepared by temperature-programmed reduction in a H₂ flow. The structure of the catalysts was characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscopy (TEM) and NH₃ temperature-programmed desorption (NH₃-TPD). The catalytic performances of hydrodesulfurization (HDS) were evaluated in a fixed-bed microreactor using dibenzothiophene (DBT) as a model compound. The results showed that the B-Ni₂P/SBA-15 catalysts still retained mesoporous structure. The Ni₂P phase was mainly active phases in all the catalysts. The proper addition of boron reduced the Ni₂P active phases but increased the specific surface area of the catalysts. The amount of acid in B-Ni₂P/SBA-15 also increased with addition of boron. When the reaction temperature was increased from 300 to 360 ℃, the HDS conversion of DBT over the catalyst clearly improved with an increase in the content of boron. The B-Ni₂P/SBA-15 catalyst with a boron content of 1.40%(w) had the best catalytic activity. The mechanism of the HDS of DBT consisted of main direct desulfurization (DDS) over the B-Ni₂P/SBA-15 catalysts.
- Hydrodesulfurization,
- SBA-15,
- Ni₂P,
- Dibenzothiophene,
- Boron
1. [1]
  
  (1) Cheng,W.; Zhang, J. Y.;Wang, R. J.;Wang, Y. Q.; He, F. Acta Phys. -Chim. Sin. 1999, 15, 647. [程伟, 张继炎, 王日杰, 王亚权, 何菲. 物理化学学报, 1999, 15, 647.]
2. [2]
  (2) Li, X. S.; Hou, Z. S.; Xin, Q.; Guo, X. X. Acta Phys. -Chim. Sin. 1993, 9, 63. [李新生, 侯震山, 辛勤, 郭燮贤. 物理化学学报, 1993, 9, 63.]
3. [3]
  (3) Li, X.; Zhang, Y. L.;Wang, A. J.;Wang, Y.; Hu, Y. K. Catal. Commun. 2010, 11, 1129.
4. [4]
  (4) Lee, Y. K.; Shu, Y. Y.; Oyama, S. T. Appl. Catal. A 2007, 322, 191.
5. [5]
  (5) Montesinos, C.; Zepeda, T.; Pawelec, B.; Lima, E.; Fierro, J. G.; Olivas, A.; Reyes, J. Appl. Catal. A 2008, 334, 330.
6. [6]
  (6) Trawczyáski, J. Appl. Catal. A 2000, 197, 289.
7. [7]
  (7) Lu, M. H.;Wang, A. J.; Li, X.; Duan, X. P.; Hu, Y. K. Acta Petro. Sin. (Petrol Proces Sec) 2006, 22, 33. [鲁墨弘, 王安杰, 李翔, 段新平, 胡永康. 石油学报(石油加工), 2006, 22, 33.]
8. [8]
  (8) Abu, I.; Smith, K. Appl. Catal. A 2007, 328, 58.
9. [9]
  (9) Song, L.; Li,W.;Wang, G.; Zhang, M.; Tao, K. Cata1. Today 2007, 125, 137.
10. [10]
  (10) Lee, Y.; Oyama, S. J. Catal. 2006, 239, 376.
11. [11]
  (11) Sawhill, S.; Layman, K.; vanWyk, D.; Engelhard, M.;Wang, C.; Bussell, M. J. Catal. 2005, 231, 300.
12. [12]
  (12) Huang, X. F.; Ji, S. F.;Wu, P. Y.; Liu, Q. Q.; Liu, H.; Zhu, J. Q.; Li, C. Y. Acta Phys. -Chim. Sin. 2008, 24, 1773. [黄晓凡, 季生福, 吴平易, 刘倩倩, 刘辉, 朱吉钦, 李成岳. 物理化学学报, 2008, 24, 1773.]
13. [13]
  (13) Usman, U.; Takaki, M.; Kubota, T.; Okamoto, Y. Appl. Catal. A. 2005, 286, 148.
14. [14]
  (14) Parks, G. L.; Pease, M. L.; Burns, A.W.; Layman, K. A.; Bussell, M. E.;Wang, X.; Hanson, J.; Rodriguez, J. J. Catal. 2007, 246, 277.
15. [15]
  (15) Rayo, P.; Rana, M.; Ramírez, J.; Ancheyta, J.; Elguezabal, A. Catal. Today 2008, 130, 283.
16. [16]
  (16) Ferdous, D.; Dalai, A. K.; Adjaye, J. Appl. Catal. A 2004, 260, 137.
17. [17]
  (17) Korányi, T.; Vít, Z.; Poduval, D.; Ryoo, R.; Kim, H. S.; Hensen, E. M. J. Catal. 2008, 253, 119.
18. [18]
  (18) Duan, X.; Teng, Y.;Wang, A.; Koganb, V. M.; Li, X.;Wang, Y. J. Catal. 2009, 261, 232.
19. [19]
  (19) Shang, H. Y.; Liu, C. G.; Chai, Y. M.; Xing, J. X. Acta Chim. Sin. 2004, 62, 888. [商红岩, 刘晨光, 柴永明, 邢金仙. 化学学报, 2004, 62, 888.]
20. [20]
  (20) Liu, B. J.; Zheng, Y. Y.; Meng, Q. M.; Jiang, Y. T.; Sheng, S. S.; Yang,W. S.; Xiong, G. X. J. Mol. Catal. 2004, 18, 447. [刘百军, 郑宇印, 孟庆民, 蒋应田, 盛世善, 杨维慎, 熊国兴. 分子催化, 2004, 18, 447.]
21. [21]
  (21) Moses, P.; Hinnemann, B.; Tops?e, H.; N?rskov, J. K. J. Catal. 2007, 248, 188.
22. [22]
  (22) Chen, T.;Wang, C. M.;Wang, I.; Tsai, T. C. J. Catal. 2010, 272, 28.
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
3. [3]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
4. [4]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
8. [8]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
9. [9]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
10. [10]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
11. [11]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
12. [12]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
13. [13]
  Bin Chen , Chaoyang Zheng , Dehuan Shi , Yi Huang , Renxia Deng , Yang Wei , Zheyuan Liu , Yan Yu , Shenghong Zhong . p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction. Chinese Journal of Structural Chemistry, 2025, 44(1): 100468-100468. doi: 10.1016/j.cjsc.2024.100468
14. [14]
  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
15. [15]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
16. [16]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
17. [17]
  Xian-Rui Meng , Qian Chen , Mei-Feng Wu , Qiang Wu , Su-Qin Wang , Li-Ping Jin , Fan Zhou , Ren-Li Ma , Jian-Ping Zou . Nano-flowers FeS/MoS2 composites as a peroxymonosulfate activator for efficient p-chlorophenol degradation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100543-100543. doi: 10.1016/j.cjsc.2025.100543
18. [18]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
19. [19]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
20. [20]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206

Get Citation

PDF

XML

Metrics

PDF Downloads(966)
Abstract views(2378)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni2P/SBA-15 Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts