Citation: CHEN Lang, RAO Mu-Min, LI Wei-Shan, XU Meng-Qing, LIAO You-Hao, TAN Chun-Lin, YI Jin. Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1689-1694. doi: 10.3866/PKU.WHXB20110712 shu

Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent

CHEN Lang ¹ ,
RAO Mu-Min ¹ ,
LI Wei-Shan ^1,2,3, ,
XU Meng-Qing ^1,2,3 ,
LIAO You-Hao ¹ ,
TAN Chun-Lin ^1,2,3 ,
YI Jin ¹

1.
1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006, P. R. China;
2. Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, South China Normal University, Guangzhou 510006, P. R. China;
3. Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (MOE), South China Normal University, Guangzhou 510006, P. R. China

Received Date: 18 January 2011
Available Online: 20 May 2011
Fund Project: 国家自然科学基金(20873046) (20873046)广东省自然科学基金(10351063101000001)资助项目 (10351063101000001)

Poly(acrylonitrile-methyl methacrylate-styrene) (PAMS) was synthesized by emulsion polymerization and a polyethylene (PE)-supported membrane was prepared using urea as foaming agent (PE-PAMS-U). The structure and performance of the PAMS copolymer, PE-PAMS-U membrane and corresponding gel polymer electrolyte (GPE) were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetry (TG), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and by a charge/discharge test. We found that the performance of the PE-PAMS-U based GPE could be improved when using urea as a foaming agent. With the use of urea the pore size of the membrane becomes uniform, the ionic conductivity of the GPE improves from 1.1×10^-3 to 2.15×10^-3 S·cm^-1 at room temperature and the interfacial resistance between the GPE and lithium is reduced from 480 to 250 Ω·cm². The GPE is stable up to 5.0 V (vs Li/Li⁺) at room temperature and the battery made using the Li/PE-supported GPE/LiCoO₂ shows a od rate and od cycle performance.
- Lithium ion battery,
- Gel polymer electrolyte,
- Poly((acrylonitrile-methyl methacrylate-styrene),
- Urea,
- Foaming agent
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