Citation: SHEN Shan-Shan, LU Wen-Cong, ZHANG Liang-Miao, YUE Bao-Hua, HAN Ling, ZHANG Hao. Fabrication of Mesoporous NiAl₂O₄ Nanorods and Their Catalytic Properties for Toluene Hydrocracking[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1743-1750. doi: 10.3866/PKU.WHXB20110711 shu

Fabrication of Mesoporous NiAl₂O₄ Nanorods and Their Catalytic Properties for Toluene Hydrocracking

1.
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China

Received Date: 23 February 2011
Available Online: 19 May 2011
Fund Project: 国家自然科学基金(20973108) (20973108) 上海教委(11ZZ83) (11ZZ83) 上海市重点学科建设 (J50101) (J50101)上海大学创新基金(A.10-0101-09-023)资助项目 (A.10-0101-09-023)

Mesoporous single-crystalline NiAl₂O₄ nanorods were successfully synthesized by a one-step hydrothermal method using a pore-forming agent (NH₄HCO₃). A series of controlled experiments were also carried out to better understand the formation mechanism of NiAl₂O₄ nanorods. The experimental results indicate that the reaction time, reactant concentration and the amount of NH₄HCO₃ play an important role in determining the morphology. The morphology, structure and composition of the nanorods were investigated using transmission electron microscopy, high resolution transmission electron microscopy, scanning electron microscopy and X-ray diffraction. The specific surface area and pore-size distribution of the obtained product was determined by nitrogen adsorption-desorption measurements. NiAl₂O₄ nanorods have a high Brunauer-Emmett-Teller surface area and od porosity properties. The catalytic performance of the NiAl₂O₄ nanorods during toluene hydrocracking was investigated using a fixed bed reactor. After the toluene catalytic reactions over 400 min at a water stream/carbon molar ratio (H₂O/C) of 1.0 with a reaction temperature of 700 ℃ the average conversion efficiency of toluene was about 86.5%. Compared to the NiAl₂O₄ nanoparticles prepared by alkaline precipitation, the mesoporous NiAl₂O₄ nanorods exhibited higher catalytic activity and stability during toluene hydrocracking. A possible formation mechanism for the mesoporous NiAl₂O₄ nanorods is proposed and discussed.
- Hydrothermal method,
- Single-crystalline NiAl₂O₄,
- NH₄HCO₃,
- Nickel catalyst,
- Characterization
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沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Mesoporous NiAl2O4 Nanorods and Their Catalytic Properties for Toluene Hydrocracking

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通讯作者: 陈斌, bchen63@163.com

Fabrication of Mesoporous NiAl₂O₄ Nanorods and Their Catalytic Properties for Toluene Hydrocracking