Citation: WU Mei-Fen, WEN Zhao-Yin, LIU Yu. Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1695-1700. doi: 10.3866/PKU.WHXB20110708 shu

Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode

1.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received Date: 18 February 2011
Available Online: 18 May 2011
Fund Project: 国家自然科学基金(50973127) (50973127) 国家重点基础研究发展计划项目(973) (2007CB209700) (973) (2007CB209700)上海市科委(08DZ2210900)资助 (08DZ2210900)

To get rid of impurities on a Li surface and avoid hydrogen gas generation during the preparation of a lithium pyrrolide film, tetrahydrofuran (THF) was used to pretreat the surface of a Li electrode. We found that THF pretreatment can obviously refresh the Li surface as well as improve the uniformity and density of the lithium pyrrolide film. The interface resistance effectively decreases and the interfacial stability improves. Additionally, the reversibility of the lithium deposition/dissolution process increases. All the ‘sponge-shaped’ lithium deposits are homogeneously distributed on the electrode surface and the lithium cycling efficiency is enhanced by THF pretreatment.
- Li metal,
- Tetrahydrofuran,
- Pyrrole,
- Passive film,
- Pretreatment
1. [1]
  
  (1) Scrosati, B.; Garche, J. J. Power Sources 2010, 195, 2419.
2. [2]
  (2) Hassoun, J.; Fernicola, A.; Navarra, M. A.; Panero, S.; Scrosati, B. J. Power Sources 2010, 195, 574.
3. [3]
  (3) Wang, L.; He, X. M.; Pu,W. H. Progress in Chemistry 2006, 18(5), 641. [王莉, 何向明, 蒲薇华. 化学进展, 2006, 18 (5), 641.]
4. [4]
  (4) Akridge, J. R.; Mikhaylik, Y. V.; White, N. Solid State Ionics 2004, 175, 243.
5. [5]
  (5) Mirzaeian, M.; Hall, P. J. Electrochim. Acta 2009, 54, 7444.
6. [6]
  (6) Padbury, R.; Zhang, X.W. J. Power Sources 2011, 196, 4436.
7. [7]
  (7) Lane, G. H.; Best, A. S.; MacFarlane, D. R.; Forsyth, M.; Hollenkamp, A. F. Electrochim. Acta 2010, 55 (6), 2210.
8. [8]
  (8) Zhuang, Q. C.;Wu, S. Chinese Journal of Power Sources 2004, 28 (2), 104. [庄全超, 武山. 电源技术, 2004, 28 (2), 104.]
9. [9]
  (9) Eineli, Y.; Aurbach, D. J. Power Sources 1995, 54, 281.
10. [10]
  (10) Ding, F.; Zhang, C. F.; Hu, X. G. Rare Metal Materials and Engineering, 2006, 35 (4), 585. [丁飞, 张翠芬, 胡信国. 稀有金属材料与工程, 2006, 35 (4), 585.]
11. [11]
  (11) Aurbach, D.; Zingrad, E.; fer, Y.; Teller, H. Solid State Ionics 2002, 148, 405.
12. [12]
  (12) Cohen, Y. S.; Cohen, Y.; Aurbach, D. J. Phys. Chem. B 2000, 104, 1228.
13. [13]
  (13) Koch, V. R.; Mass, F. Aprotic Solvent Electrolytes and Batteries Using Same. US Patent 4118550, 1978-10-3.
14. [14]
  (14) Abraham, K. M.; Foos J. S.; ldman, J. L. J. Electrochem. Soc. 1984, 131, 2197.
15. [15]
  (15) Wu, M. F.;Wen, Z. Y.; Liu, Y.; Huang, L. Z. Morphology and electrochemical behavior of Li metal behavior with pyrrole treatment for lithium secondary battery. In Solid State Ionics. Proceedings of the12th Asian Conference on Solid State Ionics- Fundamental Researches and Technological Applications, Wuhan, P. R. China, May 2-6, 2010, Chowdari, B. V. R.; Liu, H. X.; Chen,W.; Xu, Q.; Yu, Z. Y. Eds.;Wuhan University of Technology Press:Wuhan, c2010; pp 844-851.
16. [16]
  (16) Boukamp, B. A. Solid State Ionics 1986, 20 (1), 31.
17. [17]
  (17) Li, Q.; Sun, H.Y.; Takeda,Y.; Imanishi, N.;Yang, J.;Yamamoto, O. J. Power Sources 2001, 94 (2), 201.
18. [18]
  (18) Orsini, F.; Dolle, M.; Tarascon, J. M. Solid State Ionics 2000, 135, 213.
19. [19]
  (19) Aurbach, D. J. Power Sources 2000, 89 (2), 206.
20. [20]
  (20) Ding. F. Study on Lithium Metal Anode Material of High Specific Energy Lithium Secondary Battery. Ph. D. Dissertation, Harbin Institute of Technology, Harbin, 2006. [丁飞. 高比能量二次锂电池中金属锂负极材料的研究[D]. 哈尔滨: 哈尔滨工业大学, 2006.]
21. [21]
  (21) Cao, C. N.; Zhang, J. Q. An Introduction to Electrochemical Impedance. Science Press: Beijing, 2002; pp: 92-95. [曹楚南, 张鉴清. 电化学阻抗谱导论. 北京: 科学出版社, 2002: 92-95.]
22. [22]
  (22) Broussely, M.; Biensan, P.; Bonhomme, F.; Blanchard, P.; Herreyre, S.; Nechev, K.; Staniewicz, R. J. J. Power Sources 2005, 146 (1-2), 90.
23. [23]
  (23) Aurbach, D.; Einely, Y.; Zaban, A. J. Electrochem. Soc. 1994, 141 (1), L1.
24. [24]
  (24) Aurbach, D.;Weissman, I.; Schechter, A.; Cohen, H. Langmuir 1996, 12, 3991.
25. [25]
  (25) Zaban, A.; Aurbach, D. J. Electroanal. Chem. 1993, 348, 155.
26. [26]
  (26) Osaka, T.; Momma, T.; Matsumoto, Y.; Uchida, Y. J. Power Sources 1997, 68, 497.
1. [1]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
2. [2]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
3. [3]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
4. [4]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
5. [5]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
6. [6]
  Xiaofeng Xia , Jielian Zhu . Innovative Comprehensive Experimental Design: Synthesis of 6-Fluoro-N-benzoyl Tetrahydroquinoline. University Chemistry, 2024, 39(10): 344-352. doi: 10.12461/PKU.DXHX202405063
7. [7]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
8. [8]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
9. [9]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
10. [10]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
11. [11]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
14. [14]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
15. [15]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
16. [16]
  Zhaohu Li , Weidong Wang , Yuhao Liu , Mingzhe Han , Lingling Wei , Huan Jiao . Research on the Safety Management and Disposal of Chemical Laboratory Waste. University Chemistry, 2024, 39(10): 128-136. doi: 10.3866/PKU.DXHX202312090
17. [17]
  Lisen Sun , Yongmei Hao , Zhen Huang , Yongmei Liu . Experimental Teaching Design for Viscosity Measurement Serves the Optimization of Operating Conditions for Kitchen Waste Treatment Equipment. University Chemistry, 2024, 39(2): 52-56. doi: 10.3866/PKU.DXHX202307063
18. [18]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
19. [19]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
20. [20]
  Limin Shao , Na Li . A Unified Equation Derived from the Charge Balance Equation for Constructing Acid-Base Titration Curve and Calculating Endpoint Error. University Chemistry, 2024, 39(11): 365-373. doi: 10.3866/PKU.DXHX202401086

Get Citation

PDF

XML

Metrics

PDF Downloads(1081)
Abstract views(2737)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142