Citation: JIN Jing, NG Yuan-Yuan, WU Han-Qing, LI Lei, NIU Shu-Yun. Crystal Structure and Surface Photoelectric Property of Mn(II) Coordination Complexes[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1587-1594. doi: 10.3866/PKU.WHXB20110705 shu

Crystal Structure and Surface Photoelectric Property of Mn(II) Coordination Complexes

1.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China

Received Date: 3 March 2011
Available Online: 16 May 2011
Fund Project: 国家自然科学基金(20571037) (20571037)辽宁省创新团队项目(2007T092)资助 (2007T092)

Three Mn(II) complexes [Mn(SO₄)(H₂O)₃]_n (1), [Mn2.5(HPO₄)(PO₄)(H₂O)₂]_n (2), [Mn(phen)₂(H₂O)₂]?(C₄H₄O₄)?4H₂O (3) (phen=1,10-phenanthroline) were synthesized by a hydrothermal method and characterized by infrared spectrum (IR), ultraviolet-visible spectrum (UV-Vis), electron paramagnetic resonance spectrum (EPR), single crystal X-ray diffraction and surface photovoltage spectrum (SPS). The structural analyses indicate that complex 1 is a 2D coordination polymer and hydrogen bonds link the polymer to a 3D infinite structure. Complex 2 is a 3D coordination polymer. Complex 3 is a mononuclear complex and diverse hydrogen bonds connect the complex to the 3D supramolecule. SPS results indicate that the three complexes exhibit obvious surface photovoltage responses between 300-800 nm, which reveals that they possess a definite photoelectric conversion property. The structure of the complex, its dimensions and the coordination environment of the central metal affect obviously SPS: the intensity of the surface photovoltage (SPV) response bands become larger with increasing of dimensions and regularity of structure; differences in the species of direct coordination atoms and the strength of the crystal field around the central metal ions lead to the change of number and position of the response bands. Additionally, the association between SPS and UV-Vis were discussed.
- Mn(II) complex,
- Synthesis,
- Crystal structure,
- Hydrogen bond,
- Photoelectric property
1. [1]
  
  (1) Khanmohammadi, H.; Amani, S.; Abnosi, M. H.; Khavasi, H. R. Spectrochim Acta Part A 2010, 77 (2), 342.
2. [2]
  (2) Kaizer, J.; Baráth, G.; Speier, G.; Réglier, M.; Giorgi, M. Inorg. Chem. Commun. 2007, 10 (3), 292.
3. [3]
  (3) Maji, T. K.; Sain, S.; Mostafa, G.; Lu, T. H.; Ribas, J.; Monfort, M.; Chaudhuri, N. R. Inorg. Chem. 2003, 42 (3), 709.
4. [4]
  (4) Chattopadhyay, S.; Geiger, R. A.; Yin, G. C.; Busch, D. H.; Jackson, T. A. Inorg. Chem. 2010, 49 (16), 7530.
5. [5]
  (5) Izzet, G.; Ishow, E.; Delaire, J.; Afonso, C.; Tabet, J. C.; Proust, A. Inorg. Chem. 2009, 48 (24), 11865.
6. [6]
  (6) Feng, J. L.; Zhang, J. G.; Zhang, T. L.; Cui, Y. Acta Phys. -Chim. Sin. 2010, 26 (9), 2410. [冯金玲, 张建国, 张同来, 崔燕. 物理化学学报, 2010, 26 (9), 2410.]
7. [7]
  (7) Marinho, M. V.; Yoshida, M. I.; Krambrock, K.; Oliveira, L. F. C. D.; Diniz, R.; Machado, F. C. J. Mol. Struct. 2009, 923(1-3), 60.
8. [8]
  (8) Morsali, A.; Monfared, H. H.; Morsali, A. Inorg. Chim. Acta 2009, 362 (10), 3427.
9. [9]
  (9) Ruiz-García, R.; Pardo, E.; Mu?oz, M. C.; Cano, J. Inorg. Chim. Acta 2007, 360 (1), 221.
10. [10]
  (10) Zhang, L. P.; Ma, J. F.; Yang, J.; Pang, Y. Y.; Ma , J. C. Inorg. Chem. 2010, 49 (4), 1535.
11. [11]
  (11) Xu, H. Q.; Liu, X. N.;Wang, Y. Q.;Wang, H. L.; Sun, Y. M. Acta Phys. -Chim. Sin. 2009, 25 (5), 840. [徐海青, 刘秀宁, 王育乔, 王华林, 孙岳明. 物理化学学报, 2009, 25 (5), 840.]
12. [12]
  (12) Weng, R.; Ding, H. M.;Wu, X. D.; Xu, L. H.; Chen, Z. Acta Phys. -Chim. Sin. 2001, 17 (3), 248. [翁瑞, 丁红梅, 吴晓东, 徐鲁华, 陈震. 物理化学学报, 2001, 17 (3), 248.]
13. [13]
  (13) Mautner, F. A.; Egger, A.; Sodin, B.; her, M. A. S.; Abu-Youssef, M. A. M.; Massoud, A.; Escuer, A.; Vicente, R. J. Mol. Struct. 2010, 969 (1-3), 192.
14. [14]
  (14) Bhargavi, G.; Rajasekharan, M. V.; Tuchagues, J. P. Inorg. Chim. Acta 2009, 362 (9), 3247.
15. [15]
  (15) Ghosh, K.; Tyagi, N.; Kumar, P.; Singh, U. P.; el, N. J. Inorg. Biochem. 2010, 104 (1), 9.
16. [16]
  (16) Kosone, T.; Kanadani, C.; Saito, T.; Kitazawa, T. Polyhedron 2009, 28 (9-10), 1930.
17. [17]
  (17) Sun, L. P.; Niu, S. Y.; Jin, J.; Zhang, L. Eur. J. Inorg. Chem. 2007, 2007 (24), 3845.
18. [18]
  (18) Zhang, L.; Niu, S. Y.; Jin, J.; Yang, G. D.; Ye, L. Inorg. Chim. Acta 2009, 362 (5), 1448.
19. [19]
  (19) Lin, Y. H.;Wang, D. J.; Zhao, Q. D.; Yang, M.; Zhang, Q. L. J. Phys. Chem. B 2004, 108 (10), 3202.
20. [20]
  (20) Qi, M. H.; Liu, G. F. J. Phys. Chem. B 2003, 107 (31), 7640.
21. [21]
  (21) Shi, F. Z.; Jin, J.; Li, L.; Xing, Y. H.; Niu, S. Y. Acta Phys. -Chim. Sin. 2009, 25 (10), 2011. [史忠丰, 金晶, 李雷, 邢永恒, 牛淑云. 物理化学学报, 2009, 25 (10), 2011.]
22. [22]
  (22) Zhang, L.; Niu, S. Y.; Jin, J.; Sun, L. P.; Shi, Z. F.; Li, L. Acta Phys. -Chim. Sin. 2009, 25 (6), 1161. [张丽, 牛淑云, 金晶, 孙丽萍, 史忠丰, 李雷. 物理化学学报, 2009, 25 (6), 1161.]
23. [23]
  (23) Lenzmann, F.; Krueger, J.; Burnside, S.; Brooks, K.; Grältzel, M.; Gal, D.; Rülhle, S.; Cahen. D. J. Phys. Chem. B 2001, 105(27), 6347.
24. [24]
  (24) Lin, Y. H.;Wang, D. J.; Zhao, Q. D.; Yang, M.; Zhang. Q. L. J. Phys. Chem. B 2004, 108 (10), 3202.
25. [25]
  (25) Xie, T. F.;Wang, D. J.; Zhu, L. J.;Wang, C.; Li, T. J.; Zhou, X. Q.;Wang, M. J. Phys. Chem. B 2000, 104 (34), 8177.
26. [26]
  (26) Devereux, M.; McCann M.; Leon, V.; Geraghty, M.; McKee, V.; Wikaira, J. Polyhedron 2000, 19 (10), 1205.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
15. [15]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
16. [16]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
17. [17]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
18. [18]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation

PDF

XML

Metrics

PDF Downloads(1125)
Abstract views(3349)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142