Citation: FANG Fang, LI Yong-Tao, SONG Yun, ZHA Jun, ZHAO Bin, SUN Da-Lin. LiMn(BH₄)₃/2LiCl Composite Synthesized by Reactive Ball-Milling and Its Dehydrogenation Properties[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1537-1542. doi: 10.3866/PKU.WHXB20110617 shu

LiMn(BH₄)₃/2LiCl Composite Synthesized by Reactive Ball-Milling and Its Dehydrogenation Properties

1.
Department of Materials Science, Fudan University, Shanghai 200433, P. R. China

Received Date: 12 January 2011
Available Online: 29 April 2011
Fund Project: 国家自然科学基金(51001028) (51001028) 上海市自然科学基金(10ZR1404300) (10ZR1404300)

A LiMn(BH₄)₃/2LiCl composite was prepared by reactive ball-milling a mixture of LiBH₄ and MnCl₂, and its dehydrogenation properties were investigated. The results indicate that the LiMn(BH₄)₃/2LiCl composite consists of crystalline LiCl and amorphous LiMn(BH₄)₃, and decomposes at 135-190 °C with an activation energy of 114.0 kJ·mol^-1, resulting in an emission of 7.0% (w) gas. The released gases contain 96.0% H₂ and 4.0% B₂H₆ (mole fraction, x), which is the reason for why the mass loss of the LiMn(BH₄)₃/2LiCl composite is larger than that of theoretical hydrogen capacity of 6.3% (w). Moreover, the influence of various Ti-containing dopants on the decomposition of the LiMn(BH₄)₃/2LiCl composite was studied. We found that among TiF₃, TiC, TiN, and TiO₂, only TiF₃ achieved a reduction in decomposition temperature. Compared with the undoped LiMn(BH₄)₃/2LiCl composite, the onset decomposition temperature and the activation energy of the TiF₃-doped composite are reduced to 125 °C and to 104.0 kJ·mol^-1, respectively. These are attributed to the formation of Ti(BH₄)₃ in some local regions of the TiF₃-doped composite by the partial substitution of Ti for Li in LiMn(BH₄)₃.
- Borohydride,
- Reactive ball-milling,
- LiMn(BH₄)₃,
- Dehydrogenation property,
- Catalysis
1. [1]
  
  (1) Bogdanovic, B.; Eberle, U.; Felderhoff, M.; Schuth, F. Scripta Mater. 2007, 56, 813.
2. [2]
  (2) Schlapbach, L.; Zuttel, A. Natrue 2001, 414, 353.
3. [3]
  (3) Schuth, F.; Bogdanovic, B.; Felderhoff, M. Chem. Commun. 2004, 2249.
4. [4]
  (4) Crabtree, G.W.; Dresselhaus, M. S.; Buchanan, M. V. Phys. Today 2004, 57, 39.
5. [5]
  (5) Xiao, X. Z.; Chen, L. X.; Fan, X. L.; Ge, H.W.; Li, S. Q.; Ying, Y.;Wang, X. H.; Chen, C. P. Acta Phys. -Chim. Sin. 2008, 24, 423.
6. [6]
  [肖学章, 陈立新, 范修林, 葛红卫, 李寿权, 应窕, 王新华, 陈长聘. 物理化学学报, 2008, 24, 423.]
7. [7]
  (6) Xiao, X. Z.; Chen, L. X.;Wang, X. H.; Li, S. Q.; Chen, C. P. Acta Phys. -Chim. Sin. 2006, 22, 1511.
8. [8]
  [肖学章, 陈立新, 王新华, 李寿权, 陈长聘. 物理化学学报, 2006, 22, 1511.]
9. [9]
  (7) Fang, F.; Zheng, S. Y.; Chen, G. R.; Sang, G.; He, B.;Wei, S. Q.; Sun, D. L. Acta Mater. 2009, 57, 1959.
10. [10]
  (8) Graetz, J.; Reilly, J. J.; Johnson, J.; Ignatov, A. Y.; Tyson, T. A. Appl. Phys. Lett. 2004, 85, 500. (9) Zheng, S. Y.; Fang, F.; Zhou, G. Y.; Chen, G. R.; Ouyang, L. Z.; Zhu, M.; Sun, D. L. Chem. Mater. 2008, 20, 3954.
11. [11]
  (10) Gao, J.; Adelhelm, P.; Verkuijlen, M. H.W.; Rongeat, C.; Herrich, M.; van Bentum, P. J. M.; Gutfleisch, O.; Kentgens, A. P. M.; de Jong, K. P.; de Jongh, P. E. J. Phys. Chem. C 2010, 114, 4675.
12. [12]
  (11) Lodziana, Z.; Zuttel, A.; Zielinski, P. J. Phys.-Condens. Mat. 2008, 20, 465210.
13. [13]
  (12) Fang, Z. Z.; Ma, L. P.; Kang, X. D.;Wang, P. J.;Wang, P.; Cheng, H. M. Appl. Phys. Lett. 2009, 94, 044104.
14. [14]
  (13) Cahen, S.; Eymery, J. B.; Janot, R.; Tarascon, J. M. J. Power Sources 2009, 189, 902.
15. [15]
  (14) Zhang, Y. S.; Majzoub, E.; Ozolins, V.;Wolverton, C. Phys. Rev. B 2010, 82, 174107.
16. [16]
  (15) Dunbar, A. C.; zum, J. E.; Girolami, G. S. J. Organomet. Chem. 2010, 695, 2804.
17. [17]
  (16) Cerny, R.; Chul Kim, K.; Penin, N.; D′Anna, V.; Hagemann, H.; Sholl, D. S. J. Phys. Chem. C 2010, 114, 19127.
18. [18]
  (17) Lee, J. Y.; Lee, Y. S.; Suh, J. Y.; Shim, J. H.; Cho, Y.W. J. Alloy. Compd. 2010, 506, 721.
19. [19]
  (18) Nakamori, Y.; Miwa, K.; Ninomiya, A. Li, H.W.; Ohba, N.; Towata, S.; Zuttel, A.; Orimo, S. Phys. Rev. B. 2006, 74, 045126.
20. [20]
  (19) Nakamori, Y.; Li, H.W.; Miwa, K.; Towata, S.; Orimo, S. Mater. Trans. 2006, 47, 1898.
21. [21]
  (20) Nakamori, Y.; Li, H.W.; Kikuchi, K.; Aoki, M.; Miwa, K.; Towata, S.; Orimo, S. J. Alloy. Compd. 2007, 296-300, 446.
22. [22]
  (21) Choudhury, P.; Srinivasan, S. S.; Bhethanabotla, V. R.; swami, Y.; McGrath, K.; Stefanakos, E. K. Int. J. Hydrog.
23. [23]
  Energy 2009, 34, 6325.
24. [24]
  (22) Varin, R. A.; Zbroniec L. Int. J. Hydrog. Energy 2010, 35, 3588.
25. [25]
  (23) Guo, Y. H.; Yu, X. B.; Gao, L.; Xia, G. L.; Guo, Z. P.; Liu, H. K. Energy Environ. Sci. 2010, 3, 465
26. [26]
  (24) Kissinger, H. E. Anal. Chem. 1957, 29, 1702.
27. [27]
  (25) Kumar, N.; Yang, Y.; Noh,W.; Girolami, G. S.; Abelson, J. R. Chem. Mater. 2007, 19, 3802.
1. [1]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
2. [2]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
3. [3]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
4. [4]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
5. [5]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
8. [8]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
9. [9]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
10. [10]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
11. [11]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
12. [12]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
13. [13]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
14. [14]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
15. [15]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
16. [16]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
17. [17]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
18. [18]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
19. [19]
  Zhiwen HU , Ping LI , Yulong YANG , Weixia DONG , Qifu BAO . Morphology effects on the piezocatalytic performance of BaTiO₃. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 339-348. doi: 10.11862/CJIC.20240172
20. [20]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

Get Citation

PDF

XML

Metrics

PDF Downloads(1054)
Abstract views(2858)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

LiMn(BH4)3/2LiCl Composite Synthesized by Reactive Ball-Milling and Its Dehydrogenation Properties

Metrics

通讯作者: 陈斌, bchen63@163.com

LiMn(BH₄)₃/2LiCl Composite Synthesized by Reactive Ball-Milling and Its Dehydrogenation Properties