Citation: YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1122-1127. doi: 10.3866/PKU.WHXB20110433 shu

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization

1.
1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. Key Laboratory of Shanghai Colleges and Universities for Electric Power Corrosion Control and Applied Electrochemistry, Department of Energy Source and Environment Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R. China

Received Date: 7 December 2010
Available Online: 17 March 2011
Fund Project: 国家自然科学基金(50571085, 20773100, 21003089) (50571085, 20773100, 21003089)国家高技术研究发展专项(2009AA03Z327)资助项目 (2009AA03Z327)

Nano TiO₂ films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH₂)₃CH₃)₄ as a precursor. The properties of the TiO₂ films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO₂ films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO₂ films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO₂ prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.
- Hydrothermal crystallization,
- Anatase TiO₂,
- Corrosion and protection
1. [1]
  
  (1) Bartók, M.; Molnár, Á. The Chemistry of Double-Bonded Functional Groups (Suppl. A3), Patai, S. Ed.; Wiley: New York, 1997; p 843.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev.-Sci. Eng. 1998, 40, 81.
3. [3]
  (3) Ponec, V. Appl. Catal. A 1997, 149, 27.
4. [4]
  (4) Hirschl, R.; Delbecq, F.; Sautet, P.; Hafner, J. J. Catal. 2003, 217, 354.
5. [5]
  (5) Claus, P.; Brückner, A.; Mohr, C.; Hofmeister, H. J. Am. Chem. Soc. 2000, 122, 11430.
6. [6]
  (6) Loffreda, D.; Delbecq, F.; Vigné, F.; Sautet, P. J. Am. Chem. Soc. 2006, 128, 1316.
7. [7]
  (7) Milone, C.; In glia, R.; Schipilliti, L.; Crisafulli, C.; Neri, G.; Galvagno, S. J. Catal. 2005, 236, 80.
8. [8]
  (8) Milone, C.; Crisafulli, C.; In glia, R.; Schipilliti, L.; Galvagno, S. Catal. Today 2007, 122, 341.
9. [9]
  (9) Yang, Q. Y.; Zhu, Y.; Tian, L.; Pei, Y.; Qiao, M. H.; Fan, K. N. Acta Phys. -Chim. Sin. 2009, 25, 1853. [杨秋芸, 朱渊, 田莉, 裴燕, 乔明华, 范康年. 物理化学学报, 2009, 25, 1853.]
10. [10]
  (10) Baillie, J. E.; Hutching, G. J. Chem. Commun. 1999, No. 21, 2151.
11. [11]
  (11) Okumura, M.; Akita, T.; Haruta, M. Catal. Today 2002, 74, 265.
12. [12]
  (12) Schimpf, S.; Lucas, M.; Mohr, C.; Rodemerck, U.; Brückner, A.; Radnik, J.; Hofmeister, H.; Claus, P. Catal. Today 2002, 72, 63.
13. [13]
  (13) Pei, Y.; Guo, P. J.; Zhu, L. J.; Yan, S. R.; Qiao, M. H.; Fan, K. N. Stud. Surf. Sci. Catal. 2007, 170, 1174.
14. [14]
  (14) Yang, Q. Y.; Zhu, Y.; Tian, L.; Xie, S. H.; Pei, Y.; Li, H.; Li, H. X.; Qiao, M. H.; Fan, K. N. Appl. Catal. A 2009, 369, 67.
15. [15]
  (15) Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
16. [16]
  (16) Zhang, L. X.; Yu, C. C.; Zhao, W. R.; Hua, Z. L.; Chen, H. R.; Li, L.; Shi, J. L. J. Non-Cryst. Solids 2007, 353, 4055.
17. [17]
  (17) Chastain, J. andbook of X-ray Photoelectron Spectroscopy; Perkin Elmer Corporation: Eden Prairie, 1992; p 182.
18. [18]
  (18) Zanella, R.; Louis, C.; Giorgio, S.; Touroude, R. J. Catal. 2004, 223, 328.
19. [19]
  (19) Bailie, J. E.; Abdullah, H. A.; Anderson, J. A.; Rochester, C. H.; Richardson, N. V.; Hodge, N.; Zhang, J. G.; Burrows, A.; Kiely, C. J.; Hutchings, G. J. Phys. Chem. Chem. Phys. 2001, 3, 4113.
20. [20]
  (20) Mohr, C.; Hofmeister, H.; Radnik, J.; Claus, P. J. Am. Chem. Soc. 2003, 125, 1905.
21. [21]
  (21) Delbecq, F.; Sautet, P. J. Catal. 1995, 152, 217.
1. [1]
  Shuyong Zhang , Shu'e Song . Ideological and Political Case Design of Experiment of Corrosion and Protection Linking with National Major Projects. University Chemistry, 2024, 39(2): 57-60. doi: 10.3866/PKU.DXHX202304078
2. [2]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
3. [3]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
4. [4]
  Yiting Huo , Xin Zhou , Feifan Zhao , Chenbin Ai , Zhen Wu , Zhidong Chang , Bicheng Zhu . Boosting photocatalytic CO₂ methanation through TiO₂/CdS S-scheme heterojunction and fs-TAS mechanism study. Acta Physico-Chimica Sinica, 2025, 41(11): 100148-0. doi: 10.1016/j.actphy.2025.100148
5. [5]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
6. [6]
  Ning CHEN , Jingle CHEN , Hongyuan ZHU , Huali CHEN , Liguang WU , Ting WANG . Mechanism and performance regulation of Co/Zr-doped mesoporous TiO₂ catalysts in activating sodium persulfate for tetracycline degradation. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 507-518. doi: 10.11862/CJIC.20250275
7. [7]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
8. [8]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-0. doi: 10.3866/PKU.WHXB202309045
9. [9]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
10. [10]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
11. [11]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
12. [12]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
13. [13]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
14. [14]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
15. [15]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098
16. [16]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
17. [17]
  Yang Yang , Yan-Xin Chen , Ao-Sheng She , Hao-Yan Shi , Wen Chen , Wei Wang , Hai-Long Wang , Ke-Xian Li , Yi-Hu Pu , Wei-Hua Yang , Xiu-Mei Lin , Can-Zhong Lu . Nickel phosphide modified TiO2 nanotube arrays for efficient PEC water splitting H2 generation. Chinese Journal of Structural Chemistry, 2025, 44(7): 100623-100623. doi: 10.1016/j.cjsc.2025.100623
18. [18]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074
19. [19]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
20. [20]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096

Get Citation

PDF

XML

Metrics

PDF Downloads(1453)
Abstract views(2598)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization

Metrics

通讯作者: 陈斌, bchen63@163.com

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization