Citation: BAI Qing-Long, ZHANG Chun-Hua, CHENG Chuan-Hui, LI Wan-Cheng, SHEN Ren-Sheng, DU Guo-Tong. Photoluminescence and Electroluminescence of the Novel Soluble Zinc Phthalocyanine[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1195-1200. doi: 10.3866/PKU.WHXB20110425 shu

Photoluminescence and Electroluminescence of the Novel Soluble Zinc Phthalocyanine

1.
1. School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
2. College of Chemistry and Chemical Engineering, Inner Mongglia University for Nationalities, Tongliao 028043, Inner Mongglia, P. R. China;
3. State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130021, P. R. China

Received Date: 2 November 2010
Available Online: 11 March 2011
Fund Project: 国家自然科学基金(60807009) (60807009) 中央高校基本科研业务费专项资金和高等学校博士学科点专项科研基金(200801411038)资助项目 (200801411038)

α(β)-tetra-(methoxy-phenoxy)-zinc phthalocyanine are synthesized by employing 3(4)- nitrobenzene-1,2-dicarbonitrile as precursors. They are characterized by spectrum methods and elemental analysis. The UV-Vis spectrum, photoluminescence spectra of spin-coated film and solid pellet are compared. The electroluminescent devices are fabricated by using spin coating. The results indicate that the fluorescence of solid phthalocyanine has a red-shift of more than 145 nm compared to that in solution. The fluorescences are broader in solid state than that in solution. The fluorescence of β-substituted phthalcyanines has a more red-shift than α-substituted phthalcyanines. The electroluminescent spectra around 856 and 862 nm are consisted with the photoluminescence spectra of spin-coated film. The shorter inter-molecule space leads to the large red-shift of the fluorescence.
- Soluble phthalocyanine,
- Synthesis,
- Photoluminescence,
- Electroluminescence,
- Red-shift
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