Citation: SHAN Zhi-Chao, LIU Si-Yu, LI Cai-Jin, ZHU Long-Feng, MENG Xiang-Ju, XIAO Feng-Shou. High-Temperature Synthesis of Zeolite Y[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 959-964. doi: 10.3866/PKU.WHXB20110417 shu

High-Temperature Synthesis of Zeolite Y

1.
1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Institute of Catalysis, Zhejiang University, Hangzhou, 310028, P. R. China

Received Date: 25 October 2010
Available Online: 8 March 2011
Fund Project: 国家自然科学基金(20973079)资助项目 (20973079)

We hydrothermally synthesized sheet-like crystals of zeolite Y at high temperature (140 °C) using methyltriethoxysilane (MTS) as an additivity. Compared with the zeolite Y synthesized at 100 °C, the zeolite Y synthesized at high temperature has a high Si/Al ratio, a large crystalline width/thickness ratio and has od adsorption for organic volatile compounds. Characterization by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ²⁹Si nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) spectroscopy, elemental analysis and water contact angle measurements suggests that the zeolite Y synthesized at high temperature contains methyl groups, which can be responsible for the improvement in sample hydrophobicity and adsorption capacity.
- Zeolite Y,
- High-temperature,
- Sheet-like morphology,
- Adsorption,
- Organosilane
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