Citation: NING Shen, SHEN Jing, LI Xing-Long, XU Yong, LI Quan-Xin. Characterization and Anion Emission Characteristics of the Microporous Crystal Cs-C12A7[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 983-989. doi: 10.3866/PKU.WHXB20110410 shu

Characterization and Anion Emission Characteristics of the Microporous Crystal Cs-C12A7

1.
Laboratory of Biomass Clean Energy, Department of Chemical Physics, University of Science & Technology of China, Hefei 230026, P. R. China

Received Date: 26 November 2010
Available Online: 2 March 2011
Fund Project: 国家自然科学基金(50772107) (50772107) 国家重点基础研究发展规划(973)(2007CB210²⁰6) (973)(2007CB210²⁰6)国家高技术研究发展计划(863)(2009AA05Z435)资助项目 (863)(2009AA05Z435)

Cesium-12CaO·7Al₂O₃ (Cs-C12A7) was fabricated by adding CsI to the C12A7 surface using incipient wetness impregnation. The X-ray diffraction (XRD) structure determined for the Cs-C12A7 material is the same as that of the 12CaO·7Al₂O₃ (C12A7) crystal, which belongs to the I43d] space group. The concentrations of O^- and O₂^- in Cs-C12A7 were about (1.3±0.3)×10²⁰ cm^-3 and (1.2±0.2)×10²⁰ cm^-3, respectively, according to a simulation of the measured electron paramagnetic resonance (EPR) spectrum. This is similar to the data obtained for fresh C12A7 ([O^-]=(1.4±0.3)×10²⁰ cm^-3 and [O₂^-]=(1.4±0.3)×10²⁰ cm^-3). The CsI particles from the C12A7 surface were observed using field emission scanning electron microscope (FESEM) and conventional transmission electron microscopy (TEM). The emission features of Cs-C12A7, including the emission distribution, field effect and apparent activation energy were investigated in detail and compared with those of C12A7. The advanced emission behavior was attributed to a reduction in the apparent activation energy.
- Atomic oxygen anion,
- Cs-C12A7,
- Emission characteristics,
- Storage characteristics,
- Apparent activation energy
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