Citation: YAO Zhen-Dong, WEI Wei, WANG Jiu-Lin, YANG Jun, NULI Yan-Na. Review of Sulfur-Based Cathodes for High Performance Lithium Rechargeable Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1005-1016. doi: 10.3866/PKU.WHXB20110345 shu

Review of Sulfur-Based Cathodes for High Performance Lithium Rechargeable Batteries

1.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 5 November 2010
Available Online: 28 February 2011
Fund Project: 国家自然科学基金(50902095) (50902095) 上海市青年科技启明星计划(07QA14034) (07QA14034)国家重点基础研究发展规划(973) (2007CB209700)资助项目 (973) (2007CB209700)

The preparation, characteristics and electrochemical performances of the sulfur-based cathode materials in lithium/sulfur batteries are reviewed in this paper. The elemental sulfur cathode material is briefly introduced. The structural designs, preparation processes, reaction mechanisms, and charge/discharge properties of organic sulfide, sulfur-porous carbon and sulfur-polymer composites as cathode materials are systematically discussed and problems associated with these materials are also analyzed. In addition, the research and application of lithium sulfides as cathode materials are also outlined. Finally, the further development of sulfur-based cathode materials and the commercialization of lithium/sulfur batteries are discussed.
- Lithium-sulfur rechargeable battery,
- Cathode,
- Sulfur-based composite material,
- Cycle performance
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沈阳化工大学材料科学与工程学院沈阳 110142