Citation:
MA Yan-Hui, ZHAO Hui-Ling, TANG Sheng-Jie, HU Jun, LIU Hong-Lai. Synthesis of Micro/Mesoporous Composites and Their Application as CO2 Adsorbents[J]. Acta Physico-Chimica Sinica,
;2011, 27(03): 689-696.
doi:
10.3866/PKU.WHXB20110335
-
We synthesized a series of micro/mesoporous composites of S-β-MCM41(c), P-β-MCM41(c), P-ZSM-MCM41(c), P-ZSM-C through a two-step crystallization process. During this process, the microporous zeolite precursor solution (S) or the zeolite powder (P) was first synthesized and treated with NaOH solution with different concentration (c), and then the mesopores were induced by hexadecyltrimethyl- ammoniumbromide (CTAB) as a soft template or mesoporous carbon as a hard template. The effects of the type of inorganic precursor, the base concentration, and the type of mesoporous template on the structure and property of the micro/mesoporous composites were investigated. The results of X-ray diffraction (XRD), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherms showed that the products contained micropores and mesopores, simultaneously. The CO2 adsorption capacities of these micro/mesoporous composites were obviously improved compared to the pure microporous or mesoporous materials. Among them, P-ZSM-MCM41(2) had the highest CO2 adsorption capacity of 1.51 mmol·g-1, which was almost twice that of the original ZSM-5.
-
-
-
[1]
(1) IPCC Special Report on Carbon dioxide Capture and Storage. http://arch.rivm.nl/env/int/ipcc/pages_media/SRCCS-final/IPCCSpecialReportonCarbondioxideCaptureandStorage.htm.
-
[2]
(2) Chou, C. T.; Chen, C. Y. Sep. Purif. Technol. 2004, 39, 51.
-
[3]
(3) Chue, K. T.; Kim, J. N.; Yoo, Y. J.; Cho, S. H. Ind. Eng. Chem. Res. 1995, 34, 591.
-
[4]
(4) Pakseresht, S.; Kazemeini, M.; Akbarnejad, M. M. Sep. Purif. Technol. 2002, 28, 53.
-
[5]
(5) Siriwardane, R. V.; Shen, M. S.; Fisher, E. P.; Poston, J. A. Energy Fuels 2001, 15, 279.
-
[6]
(6) Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O′Keeffe, M.; Yaghi, O. M. Science 2008, 319, 939.
-
[7]
(7) He, Y.; Seaton, N. A. Langmuir 2006, 22, 1150.
-
[8]
(8) Liu, X.; Li, J.; Zhou, L.; Huang, D.; Zhou, Y. Chem. Phys. Lett. 2005, 415, 198.
-
[9]
(9) Proke?ova, P.; Mintova, S.; Cejka, J.; Bein, T. Microporous Mesoporous Mat. 2003, 64, 165.
-
[10]
(10) Proke?ova, P.; Mintova, S.; Cejka, J.; Bein, T. Mater. Sci. Eng. C 2003, 23, 1001.
-
[11]
(11) Karlsson, A.; Stocker, M.; Schmidt, R. Microporous Mesoporous Mat. 1999, 27, 18l.
-
[12]
(12) Poladi, R. H. P. R.; Landry, C. C. J. Solid State Chem. 2002, 167, 363.
-
[13]
(13) Liu, Y.; Zhang, W. Z.; Pinnavaia, T. J. J. Am. Chem. Soc. 2000, l22, 8791.
-
[14]
(14) Han, W. S.; Sun, Y. Chem. Mater. 2002, l4, 1144.
-
[15]
(15) Zhang, Z. Z.; Xiao, F. S. J. Am, Chem, Soc. 200l, 123, 5014.
-
[16]
(16) Shen, B. J.; Huang, H. Y.; Li, H. L. Preparation Method of High Silicon Aluminium Ratio small Crystal NaY Molecular sieve. CN Patent 1393403.A, 2003.
-
[17]
[申宝剑, 黄海燕, 李海丽. 一种中微孔复合分子筛组合物的分步晶化合成方法: 中国, CN 1393403.A
-
[18]
[P]. 2003.]
-
[19]
(17) Li, G.; Kan, Q. B.; Wu, T. H. Acta Chem. Sin. 2002, 60, 759.
-
[20]
[李 工, 阚秋斌, 吴通好, 化学学报, 2002, 60, 759.]
-
[21]
(18) Guo, W. P.; Huang, L. M.; Chen, H. Y. J. Chem. Chin. Univ. 1999, 20, 356.
-
[22]
[郭万平, 黄立民, 陈海鹰. 高等学校化学学报, 1999, 20, 356.]
-
[23]
(19) Zhang, H.; Wu, D.; Sun, Y. H. J. Fuel Chem. Technol. 2001, 29 (Suppl.1), 28.
-
[24]
[张 晔, 吴 东, 孙予罕. 燃料化学学报, 2001, 29(增刊), 28.]
-
[25]
(20) Li, F. X.; Wu, L.; Dou, T. J. Fuel Chem. Technol. 1998, 26, 102.
-
[26]
[李福祥, 吴 岚, 窦 涛. 燃料化学学报, 1998, 26, 102.]
-
[27]
(21) Huang, H. Y.; Shen, B. J.; Xu, C. M. Acta Chim. Sin. 2002, 60, 1350.
-
[28]
[黄海燕, 申宝剑, 徐春明. 化学学报, 2002, 60, 1350.]
-
[29]
(22) Kim, S.; Shah, J.; Pinnavaia, T. J. Chem. Mater. 2003, 15, 1664.
-
[30]
(23) Yang, Z.; Xia, Y.; Mokaya, R. Adv. Mater. 2004, 16, 727.
-
[31]
(24) Zhuo, S.; Huang, Y.; Hu, J.; Liu, H.; Hu, Y.; Jiang, J. J. Phys. Chem. C 2008, 112, 11295.
-
[1]
-
-
-
[1]
Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
-
[2]
Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
-
[3]
Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
-
[4]
Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
-
[5]
Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO2 capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
-
[6]
Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
-
[7]
Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
-
[8]
Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
-
[9]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[10]
Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C3N4纳米片及其高效光催化产H2O2. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
-
[11]
Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
-
[12]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[13]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[14]
Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
-
[15]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[16]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[17]
Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
-
[18]
Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
-
[19]
Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
-
[20]
Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
-
[1]
Metrics
- PDF Downloads(1721)
- Abstract views(2705)
- HTML views(3)