Citation: ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long. Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 705-710. doi: 10.3866/PKU.WHXB20110311 shu

Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke

1.
1. Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Technology Center, China Tobacco of Zhejiang Industrial Company, Hangzhou 310008, P. R. China

Received Date: 13 October 2010
Available Online: 27 January 2011
Fund Project: 国家重点基础研究重大项目计划(973)(2010CB732300) (973)(2010CB732300)上海市自然科学基金(09ZR1408200)资助 (09ZR1408200)

Pd-Cu/activated carbon catalysts were prepared by wetness impregnation and their performance in the room-temperature catalytic oxidation of the pulse reaction of carbon monoxide were investigated using simulated cigarette smoke gas consisting of 4.4 CO-4.2 H₂O-19.2 O₂-72.2 He (volume fraction, %). The effect of different activated carbon supports on catalytic performance was investigated in detail. The results show that at room temperature the order of catalytic performance for CO oxidation is: the catalyst supported on coconut activated carbon (CAC)2+ and Pd⁰ are also present on the surfaces of the CAC and WAC catalysts but only Pd²⁺ is present on the surface of the SAC catalysts, which results in better catalytic activity for SAC than that of the CAC and WAC catalysts. When the ternary composite filter was prepared by inserting the catalyst between the cigarette filter and the acetate filter rod, the smoking tests showed that the amount of CO in the main cigarette smoke decreased noticeably. The SAC catalyst reduced CO by 25.4% when the amount of Pd in the catalyst increased to 3.4% (w).
- Cigarette smoke,
- Carbon monoxide,
- Room-temperature catalytic oxidation,
- Activated carbon
1. [1]
  
  (1) Chen, M. S.; odman, D. W. Science 2004, 306, 252.
2. [2]
  (2) Campbell, C. T. Science 2004, 306, 234.
3. [3]
  (3) Shelef, M.; McCabe, R. W. Catal. Today 2000, 62, 35.
4. [4]
  (4) Twigg, M. V. Appl. Catal. B 2007, 70, 2.
5. [5]
  (5) Xie, X.; Li, Y.; Liu, Z. Q.; Haruta, M.; Shen, W. Nature 2009, 458, 746.
6. [6]
  (6) Qiao, B.; Liu, L.; Zhang, J.; Deng, Y. J. Catal. 2009, 261, 241.
7. [7]
  (7) Li, S.; Liu, G.; Lian, H.; Jia, M.; Zhao, G.; Jiang, D.; Zhang, W. Catal. Commun. 2008, 9, 1045.
8. [8]
  (8) Antonio, G. C.; Gabriela, D.; Rodolfo, Z.; Humberto, R.; Patricia, S.; José, M. S. J. Phys. Chem. C 2009, 113, 9710.
9. [9]
  (9) Dyakonov, A. J. Appl. Catal. B 2003, 45, 257.
10. [10]
  (10) Zhang, Y. Q.; Gu, Z. T.; Zhuang, L.; Wang, L. Y. Cu-Pd Modified Activated Carbon Fiber Composite Filter. CN Patent 2803014, 2005-04-14.
11. [11]
  [张玉清, 顾中铸, 庄磊, 王力友. 铜钯基改性活性炭纤维复合过滤嘴. 中国, CN2803014
12. [12]
  [P]. 2005-04-14]
13. [13]
  (11) Zhang, Y. Q.; Zhuang, L.; Gu, Z. T. Synthesis of Modified Activated Carbon Fiber for Cigarette Filtration and Abatement of Hazardous Substance. CN Patent 1692848, 2005-06-20.
14. [14]
  [清, 庄磊, 顾中铸. 用于卷烟过滤降害的改性活性炭纤其制备方法. 中国, CN1692848
15. [15]
  [P]. 2005-06-20]
16. [16]
  (12) Park, E. D.; Lee, J. S. J. Catal. 2000, 193, 5.
17. [17]
  (13) Gurrath, M.; Kuretzky, T.; Boehm, H. P.; Okhlopkova, L. B.; Lisitsyn, A. S.; Likholobov, V. A. Carbon 2000, 38, 1241.
18. [18]
  (14) Okhlopkova, L. B.; Lisitsyn, A. S.; Likholobov, V. A.; Gurrath, M.; Boehm, H. P. Appl. Catal. A 2000, 204, 229.
19. [19]
  (15) Park, E. D.; Lee, J. S. J. Catal. 1998, 180, 123.
20. [20]
  (16) Yamamoto, Y.; Matsuzaki, T.; Ohdan, K.; Okamoto, Y. J. Catal. 1996, 161, 577.
21. [21]
  (17) Izatt, R. M.; Eatough, D.; Christensen, J. J. J. Chem. Soc. 1967, 1301.
22. [22]
  (18) Wu, J. C. S.; Chang, T. Y. Catal. Today 1998, 44, 111.
23. [23]
  (19) Park, E. D.; Choi, S. H.; Lee, J. S. J. Phys. Chem. B 2000, 104, 5586.
24. [24]
  (20) Deevi, S.; Ettireddy, P. R. Catalysts to Reduce Carbon Monoxide Such As in the Mainstream Smoke of a Cigarett. WO. Pat. Appl. PCT/IB2007/001775, 2007.
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