Citation: ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun. Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 455-460. doi: 10.3866/PKU.WHXB20110228 shu

Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior

1.
1. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
2. Institute of Chemical Industry of Forest Products, Nanjing 210042, P. R. China

Received Date: 20 September 2010
Available Online: 5 January 2011
Fund Project: 国家重点基础研究发展计划(973) (2007CB209703) (973) (2007CB209703)江苏省生物质能源与材料重点实验室(2010M001)资助项目 (2010M001)

Porous carbons were prepared by the carbonization of water soluble chitosan and they were then used to synthesize porous C/NiO composites. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and nitrogen adsorption-desorption experinents were used to characterize the structure and morphology of the products. The results showed that the mesopore-rich composites consisted of NiO crystallites and porous carbon. The electrochemical properties of the porous C/NiO composites were studied by cyclic voltammetry (CV) and galvanostatic charge/discharge measurements. We found that compared with porous carbon, the composites showed superior electrochemical capacitive performance. When the mass ratio of nickel to carbon was 2:20, the composite had a large specific capacitance of 355 F·g^-1 at a current density of 0.1 A·g^-1 and excellent cyclability with a capacity retention of about 99% after 1500 cycles.
- Supercapacitor,
- Chitosan,
- Porous carbon,
- Nickel oxide
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沈阳化工大学材料科学与工程学院沈阳 110142