Citation: ZHAO Hui-Ling, XU Sheng, ZHOU Jian-Hai, HU Jun, LIU Hong-Lai. One-Step Synthesis of Metal-Doped Mesoporous MCM-41 Materials and Their Application in Esterification Catalysis[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 499-504. doi: 10.3866/PKU.WHXB20110227 shu

One-Step Synthesis of Metal-Doped Mesoporous MCM-41 Materials and Their Application in Esterification Catalysis

1.
Laboratory for Advanced Materials, Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 10 September 2010
Available Online: 5 January 2011
Fund Project: 国家自然科学基金(20776045, 20736002) (20776045, 20736002)长江学者创新团队(IRT0721)资助项目 (IRT0721)

Metals (Fe, Ti, Zr) were doped into mesoporous MCM-41 by a one-step method using cetyltriethylammonium bromide (CTAB) micelles with micellar solubilized metallocenes as templates. X- ray diffraction (XRD) and N₂ adsorption-desorption isotherms show that after metallocene doping, M- MCM-41(T) materials still preserved the ordered hexa nal structure and high BET surface area. Inductively coupled plasma atomic emission spectrometry (ICP-AES) indicated that the mass fractions of the metals in the corresponding samples are: 1.71% Fe in Fe-MCM-41(400), 0.95% Ti in Ti-MCM-41(550) and 0.81% Zr in Zr-MCM-41(550). All the M-MCM-41(T) materials showed a particular high catalysis effect for the esterification of acetic acid and n-butanol. The TOF of Fe-MCM-41(400) and Zr-MCM-41(550) were 55643 g·h^-1·g^-1 and 125320 g·h^-1·g^-1, respectively, which is much higher than that of the corresponding pure metallocenes.
- Metallocene,
- M-MCM-41,
- One-step impregnation,
- Esterification,
- Catalysis effect
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