Citation: ZHANG Qi-Bo, HUA Yi-Xin. Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 149-155. doi: 10.3866/PKU.WHXB20110126 shu

Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning

ZHANG Qi-Bo ,
HUA Yi-Xin

1.
Key Laboratory of Ionic Liquids Metallurgy, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, P. R. China

Received Date: 30 September 2010
Available Online: 8 December 2010
Fund Project: 国家自然科学基金(50864009, 50904031) (50864009, 50904031)高等学校博士学科点专项科研基金(20070674001)资助项目 (20070674001)

The effect of the ionic liquid additive 1-butyl-3-methylimidazolium hydrogen sulfate ([BMIM] HSO₄) on the kinetics of oxygen evolution during zinc electrowinning from an acidic sulfate solution was investigated. We used potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and X-ray diffraction for this study. Potentiodynamic polarization curves and the corresponding kinetic parameter analysis show that [BMIM]HSO₄ has a catalytic effect on oxygen evolution by stimulating the reaction rate constant. Impedance data reveal that [BMIM]HSO₄ can markedly reduce the oxygen evolution charge transfer resistance. The addition of 5 mg·L^-1 [BMIM]HSO₄ obviously decreased the resistance value by at least 50% over the studied potential range from 1.85 to 2.10 V. In addition, the results of the impedance measurements also suggest an inhibition effect of [BMIM]HSO₄ on the secondary reactions and this is due to the adsorption of the additive on the anode surface, which decreased the amount of active sites for anion adsorption. All electrochemical results were corroborated with a morphological and orientation analysis of the anodic surface after 120 h of anodic polarization. The addition of [BMIM]HSO₄ inhibited the generation of the intermediate product β-PbO₂ and it promoted the generation of larger, loose, and porous α-PbO₂, which benefited the oxygen evolution reaction.
- Electrochemical impedance spectroscopy,
- Zinc electrowinning,
- Oxygen evolution,
- Ionic liquid additive,
- Surface morphology
1. [1]
  
  1 Petrova, M.; Noncheva, Z.; Dobrev, T.; Rashkov, S.; Kounchev, N.; Petrov, D.; Vlaev, S.; Mihnev, V.; Zarev, S.; Georgieva, L.; Buttinelli, D. Hydrometallurgy, 1996, 40: 293
2. [2]
  2 Ivanov, I.; Stefanov, Y.; Noncheva, Z.; Petrova, M.; Dobrev, T.; Mirkova, L.; Vermeersch, R.; Demaerel, J. P. Hydrometallurgy, 2000, 57: 109
3. [3]
  3 Felder, A.; Prengaman, R. D. Journal of the Minerals, Metals and Material Society, 2006, 58: 28
4. [4]
  4 Jiang, L. X.; Zhong, S. P.; Lai, Y. Q.; Lü, X. J.; Hong, B.; Peng, H. J.; Zhou, X. Y.; Li, J.; Liu, Y. X. Acta Phys. -Chim. Sin., 2010, 26: 2369
5. [5]
  [蒋良兴, 衷水平, 赖延清, 吕晓军, 洪波, 彭红建, 周向阳, 李劼, 刘业翔. 物理化学学报, 2010, 26: 2369]
6. [6]
  5 Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lü, X. J.; Peng, H. J.; Liu, Y. X. Hydrometallurgy, 2010, 102: 73
7. [7]
  6 Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lü, X. J.; Peng, H. J.; Liu, Y. X. Hydrometallurgy, 2010, 102: 81
8. [8]
  7 Pavlov, D.; Rogachev, T. Electrochim. Acta, 1986, 31: 241
9. [9]
  8 Rashkov, S.; Dobrev, T.; Noncheva, Z.; Stefanov, Y.; Rashkova, B.; Petrova, M. Hydrometallurgy, 1999, 52: 223
10. [10]
  9 Lupi, C.; Pilone, D. Hydrometallurgy, 1997, 44: 347
11. [11]
  10 Siegmund, A.; Prengaman, R. D.; Dutrizac, J. E. Lead-Zinc 2000
12. [12]
  [C].//Dutrizac, J. E.Warrendale. PA: TMS, 2000: 589-597
13. [13]
  11 Newnham, R. H. J. Appl. Electrochem., 1992, 22: 116
14. [14]
  12 Zhong, S. P.; Lai, Y. Q.; Jiang, L. X.; Tian, Z. L.; Li, J.; Liu, Y. X. Chin. J. Process Eng., 2008, 8: 289
15. [15]
  [衷水平, 赖延清, 蒋良兴, 田忠良, 李劫, 刘业翔. 过程工程学报, 2008, 8: 289]
16. [16]
  13 Lai, Y. Q.; Zhong, S. P.; Jiang, L. X.; Lü, X. J.; Chen, P. R.; Li, J.; Liu, Y. X. J. Cent. South Uuiv. Tech., 2009, 16: 236
17. [17]
  14 Petrova, M.; Stefanov, Y.; Noncheva, Z.; Dobrev, T.; Rashkov, S. British Corrosion Journal, 1999, 34: 198
18. [18]
  15 Pavlov, D. Electrochim. Acta, 1978, 23: 845
19. [19]
  16 Pavlov, D.; Dinev, Z. J. Electrochem. Soc., 1980, 127: 855
20. [20]
  17 Yamamoto, Y.; Fumino, K.; Ueda, T.; Nambu, M. Electrochim. Acta, 1992, 37: 199
21. [21]
  18 Ruetchi, P.; Cahan, B. D. J. Electrochem. Soc., 1957, 104: 406
22. [22]
  19 Burbank, J. J. Electrochem. Soc., 1959, 106: 369
23. [23]
  20 Paunovic, M.; Schlesinger, M. Fundamental of electrochemical deposition. 2nd ed. New York: JohnWilley & Sons Inc. Publication, 2006: 177-198
24. [24]
  21 Saba, A. E.; Elsherief, A. E. Hydrometallurgy, 2000, 54: 91
25. [25]
  22 Afifi, S. E.; Ebraid, A. R. Journal of the Minerals, 1992, 1: 32
26. [26]
  23 Chapman, T.W.; Yen, S. C. Anode depolarisation in electrowinning
27. [27]
  [C]. AIME Meeting, Las Vegas, No., 1980
28. [28]
  24 2 Zhang, Q. B.; Hua, Y. X. J. Appl. Electrochem., 2009, 39: 261
29. [29]
  25 Zhang, Q. B.; Hua, Y. X.;Wang, Y. T.; Lu, H. J.; Zhang, X. Y. Hydrometallurgy, 2009, 98: 291
30. [30]
  26 Whitehead, J. A.; Lawrance, G. A.; McCluskey, A. Aust. J. Chem., 2004, 57: 151
31. [31]
  27 Rerolle, C.;Wiart, R. Electrochim. Acta, 1995, 40: 939
32. [32]
  28 Cachet, C.; Rerolle, C.;Wiart, R. Electrochim. Acta, 1996, 41: 83
33. [33]
  29 Cachet, C.; Pape-Rerolle, C. L. E.;Wiart, R. J. Appl. Electrochem., 1999, 29: 813
34. [34]
  30 Berube, L. P.; Piron, D. J. Electrochem. Soc., 1987, 134: 562
35. [35]
  31 Katz, E. R.; Stucki, S. J. Electroanal. Chem., 1987, 228: 407
36. [36]
  32 Ruetschi, P.; Cahan, B. D. J. Electrochem. Soc., 1958, 105: 369
37. [37]
  33 Lappe, F. J. Phys. Chem. Solid., 1962, 23: 1563
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning

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通讯作者: 陈斌, bchen63@163.com

Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning