Citation: ZHANG Qi-Bo, HUA Yi-Xin. Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 149-155. doi: 10.3866/PKU.WHXB20110126 shu

Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning

ZHANG Qi-Bo ,
HUA Yi-Xin

1.
Key Laboratory of Ionic Liquids Metallurgy, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, P. R. China

Received Date: 30 September 2010
Available Online: 8 December 2010
Fund Project: 国家自然科学基金(50864009, 50904031) (50864009, 50904031)高等学校博士学科点专项科研基金(20070674001)资助项目 (20070674001)

The effect of the ionic liquid additive 1-butyl-3-methylimidazolium hydrogen sulfate ([BMIM] HSO₄) on the kinetics of oxygen evolution during zinc electrowinning from an acidic sulfate solution was investigated. We used potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and X-ray diffraction for this study. Potentiodynamic polarization curves and the corresponding kinetic parameter analysis show that [BMIM]HSO₄ has a catalytic effect on oxygen evolution by stimulating the reaction rate constant. Impedance data reveal that [BMIM]HSO₄ can markedly reduce the oxygen evolution charge transfer resistance. The addition of 5 mg·L^-1 [BMIM]HSO₄ obviously decreased the resistance value by at least 50% over the studied potential range from 1.85 to 2.10 V. In addition, the results of the impedance measurements also suggest an inhibition effect of [BMIM]HSO₄ on the secondary reactions and this is due to the adsorption of the additive on the anode surface, which decreased the amount of active sites for anion adsorption. All electrochemical results were corroborated with a morphological and orientation analysis of the anodic surface after 120 h of anodic polarization. The addition of [BMIM]HSO₄ inhibited the generation of the intermediate product β-PbO₂ and it promoted the generation of larger, loose, and porous α-PbO₂, which benefited the oxygen evolution reaction.
- Electrochemical impedance spectroscopy,
- Zinc electrowinning,
- Oxygen evolution,
- Ionic liquid additive,
- Surface morphology
1. [1]
  
  1 Petrova, M.; Noncheva, Z.; Dobrev, T.; Rashkov, S.; Kounchev, N.; Petrov, D.; Vlaev, S.; Mihnev, V.; Zarev, S.; Georgieva, L.; Buttinelli, D. Hydrometallurgy, 1996, 40: 293
2. [2]
  2 Ivanov, I.; Stefanov, Y.; Noncheva, Z.; Petrova, M.; Dobrev, T.; Mirkova, L.; Vermeersch, R.; Demaerel, J. P. Hydrometallurgy, 2000, 57: 109
3. [3]
  3 Felder, A.; Prengaman, R. D. Journal of the Minerals, Metals and Material Society, 2006, 58: 28
4. [4]
  4 Jiang, L. X.; Zhong, S. P.; Lai, Y. Q.; Lü, X. J.; Hong, B.; Peng, H. J.; Zhou, X. Y.; Li, J.; Liu, Y. X. Acta Phys. -Chim. Sin., 2010, 26: 2369
5. [5]
  [蒋良兴, 衷水平, 赖延清, 吕晓军, 洪波, 彭红建, 周向阳, 李劼, 刘业翔. 物理化学学报, 2010, 26: 2369]
6. [6]
  5 Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lü, X. J.; Peng, H. J.; Liu, Y. X. Hydrometallurgy, 2010, 102: 73
7. [7]
  6 Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lü, X. J.; Peng, H. J.; Liu, Y. X. Hydrometallurgy, 2010, 102: 81
8. [8]
  7 Pavlov, D.; Rogachev, T. Electrochim. Acta, 1986, 31: 241
9. [9]
  8 Rashkov, S.; Dobrev, T.; Noncheva, Z.; Stefanov, Y.; Rashkova, B.; Petrova, M. Hydrometallurgy, 1999, 52: 223
10. [10]
  9 Lupi, C.; Pilone, D. Hydrometallurgy, 1997, 44: 347
11. [11]
  10 Siegmund, A.; Prengaman, R. D.; Dutrizac, J. E. Lead-Zinc 2000
12. [12]
  [C].//Dutrizac, J. E.Warrendale. PA: TMS, 2000: 589-597
13. [13]
  11 Newnham, R. H. J. Appl. Electrochem., 1992, 22: 116
14. [14]
  12 Zhong, S. P.; Lai, Y. Q.; Jiang, L. X.; Tian, Z. L.; Li, J.; Liu, Y. X. Chin. J. Process Eng., 2008, 8: 289
15. [15]
  [衷水平, 赖延清, 蒋良兴, 田忠良, 李劫, 刘业翔. 过程工程学报, 2008, 8: 289]
16. [16]
  13 Lai, Y. Q.; Zhong, S. P.; Jiang, L. X.; Lü, X. J.; Chen, P. R.; Li, J.; Liu, Y. X. J. Cent. South Uuiv. Tech., 2009, 16: 236
17. [17]
  14 Petrova, M.; Stefanov, Y.; Noncheva, Z.; Dobrev, T.; Rashkov, S. British Corrosion Journal, 1999, 34: 198
18. [18]
  15 Pavlov, D. Electrochim. Acta, 1978, 23: 845
19. [19]
  16 Pavlov, D.; Dinev, Z. J. Electrochem. Soc., 1980, 127: 855
20. [20]
  17 Yamamoto, Y.; Fumino, K.; Ueda, T.; Nambu, M. Electrochim. Acta, 1992, 37: 199
21. [21]
  18 Ruetchi, P.; Cahan, B. D. J. Electrochem. Soc., 1957, 104: 406
22. [22]
  19 Burbank, J. J. Electrochem. Soc., 1959, 106: 369
23. [23]
  20 Paunovic, M.; Schlesinger, M. Fundamental of electrochemical deposition. 2nd ed. New York: JohnWilley & Sons Inc. Publication, 2006: 177-198
24. [24]
  21 Saba, A. E.; Elsherief, A. E. Hydrometallurgy, 2000, 54: 91
25. [25]
  22 Afifi, S. E.; Ebraid, A. R. Journal of the Minerals, 1992, 1: 32
26. [26]
  23 Chapman, T.W.; Yen, S. C. Anode depolarisation in electrowinning
27. [27]
  [C]. AIME Meeting, Las Vegas, No., 1980
28. [28]
  24 2 Zhang, Q. B.; Hua, Y. X. J. Appl. Electrochem., 2009, 39: 261
29. [29]
  25 Zhang, Q. B.; Hua, Y. X.;Wang, Y. T.; Lu, H. J.; Zhang, X. Y. Hydrometallurgy, 2009, 98: 291
30. [30]
  26 Whitehead, J. A.; Lawrance, G. A.; McCluskey, A. Aust. J. Chem., 2004, 57: 151
31. [31]
  27 Rerolle, C.;Wiart, R. Electrochim. Acta, 1995, 40: 939
32. [32]
  28 Cachet, C.; Rerolle, C.;Wiart, R. Electrochim. Acta, 1996, 41: 83
33. [33]
  29 Cachet, C.; Pape-Rerolle, C. L. E.;Wiart, R. J. Appl. Electrochem., 1999, 29: 813
34. [34]
  30 Berube, L. P.; Piron, D. J. Electrochem. Soc., 1987, 134: 562
35. [35]
  31 Katz, E. R.; Stucki, S. J. Electroanal. Chem., 1987, 228: 407
36. [36]
  32 Ruetschi, P.; Cahan, B. D. J. Electrochem. Soc., 1958, 105: 369
37. [37]
  33 Lappe, F. J. Phys. Chem. Solid., 1962, 23: 1563
1. [1]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
2. [2]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
3. [3]
  Haiying Wang , Andrew C.-H. Sue . How to Visually Identify Homochiral Crystals. University Chemistry, 2024, 39(3): 78-85. doi: 10.3866/PKU.DXHX202309004
4. [4]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
5. [5]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
6. [6]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
7. [7]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
8. [8]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
9. [9]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
10. [10]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
13. [13]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
14. [14]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
15. [15]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
16. [16]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
19. [19]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
20. [20]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009

Get Citation

PDF

XML

Metrics

PDF Downloads(1387)
Abstract views(3190)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of the Ionic Liquid Additive-[BMIM]HSO₄ on the Kinetics of Oxygen Evolution during Zinc Electrowinning