Citation: LU Xue-Bin, GUO Zhao-Hui, HUANG Rong, CHEN Ming-An. Preparation of a (3-Mercaptopropyl)triethoxylsilane Film on Copper and Its Corrosion Protective Performance[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 108-112. doi: 10.3866/PKU.WHXB20110121 shu

Preparation of a (3-Mercaptopropyl)triethoxylsilane Film on Copper and Its Corrosion Protective Performance

1.
School of Materials Science and Engineering, Central South University, Changsha 410083, P. R. China

Received Date: 24 June 2010
Available Online: 6 December 2010

(3-Mercaptopropyl)triethoxysilane (MPTES) was hydrolyzed in acid or basic ethanol-water solution. Fourier transform infrared (FTIR) spectroscopy was used to characterize the structures of MPTES solutions and MPTES films that formed on copper. The corrosion protective performance of the MPTES films was evaluated by polarization curves and electrochemical impedance spectroscopy (EIS). The results showed that MPTES was hydrolyzed to a certain extent with the formation of Si―OH groups in an acid silane solution and the degree of hydrolysis increased during the aging process of the solution at room temperature. However, a small amount of MPTES was hydrolyzed in the basic silane solution and a large number of SiOCH₂CH₃ groups were found in it. More Si ―O― Si bonds were formed in the film obtained from the acid silane solution compared to the film formed in the basic silane solution. The polarization curves showed that the MPTES films could decrease the corrosion current density of the copper electrodes; the protection efficiencies of the films were 90.3% (for the acid film) and 79.2% (for the basic film). EIS plots indicated that the basic film lost its protective capability after 24 h of immersion in 3.5% (w) NaCl solution while the acid film showed increasing impedance.
- Copper,
- Silane,
- Film,
- Corrosion,
- Fourier tansform infrared spectroscopy
1. [1]
  
  1 Li, C. Heat Treat. Met., 2000, 8: 38
2. [2]
  [李灿. 金属热处理, 2000, 8: 38]
3. [3]
  2 Hu, J. M.; Liu, L.; Zhang, J. T.; Zhang, J. Q.; Cao, C. N. Acta etall. Sin., 2004, 40: 1189
4. [4]
  [胡吉明, 刘倞, 张金涛, 张鉴清, 曹楚南. 金属学报, 2004, 40: 1189]
5. [5]
  3 Li, S. M.;Wang, Y. G.; Liu, J. H.;Wei,W. Acta Phys. -Chim. Sin., 2007, 23: 1631
6. [6]
  [李松梅, 王勇干, 刘建华, 韦巍. 物理化学学报, 2007, 23: 1631]
7. [7]
  4 Li, Y. S.; Lu,W. J.;Wang, Y.; Tran, T. Spectrochim. Acta A, 2009, 73: 922
8. [8]
  5 Zucchi, F.; Frignani, A.; Grassi, V.; Balbo, A.; Trabanelli, G. Mater. Chem. Phys., 2008, 110: 263
9. [9]
  6 Chen, M. A.; Yang, X.; Zhang, X. M.; Li, H. Z.; Lu, X. B.; Liu, C. R. Chin. J. Nonferrous Met., 2008, 18: 24
10. [10]
  [陈明安, 杨汐, 张新明, 李慧中, 路学斌, 刘超仁. 中国有色金属学报, 2008, 18: 24]
11. [11]
  7 Ferreira, M. G. S.; Duarte, R. G.; Montemor, M. F.; Simões, A. M. P. Electrochim. Acta, 2004, 49: 2927
12. [12]
  8 Wu, H. J.; Lu, J. T. Acta Phys. -Chim. Sin., 2009, 25: 1743 [吴海江, 卢锦堂. 物理化学学报, 2009, 25: 1743]
13. [13]
  9 Peng, T. L.; Man, R. L. Journal of Rare Earths, 2009, 27: 159
14. [14]
  10 Huang, L.; Lin, K. F.; Yang, F. Z.; Xu, S. K.; Zhou, S. M. Electrochemistry, 2005, 11: 188
15. [15]
  [黄令, 林克发, 杨防祖, 许书楷, 周绍民. 电化学, 2005, 11: 188]
16. [16]
  11 Zucchi, F.; Grassi, V.; Frignani, A.; Trabanelli, G.; Monticelli, C. Mater. Chem. Phys., 2007, 103: 340
17. [17]
  12 Liu, L.; Hu, J. M.; Zhang, J. Q.; Cao, C. N. J. Chin. Soc. Corros. Prot., 2006, 26: 59
18. [18]
  [刘倞, 胡吉明, 张鉴清, 曹楚南. 中国腐蚀与防护学报, 2006, 26: 59]
19. [19]
  13 Van Ooij,W. J.; Zhu, D. Q.; Stacy, M.; Seth,A.; Mugada,T.; Gandhi, J.; Puomi, P. Tsinghua Science and Technology, 2005, 10: 639
20. [20]
  14 Osterholtz, F. D.; Pohl, E. R. J. Adhesion Sci. Technol., 1992, 6: 127
21. [21]
  15 Cabral, A.; Duarte, R. G.; Montemor, M. F.; Zheludkevich, M. L.; Ferreira, M. G. S. Corros. Sci., 2005, 47: 869
22. [22]
  16 Laibinis, P. E.; Bain, C. D.; Whitesides, G. M. J. Phys. Chem., 1991, 95: 7017
23. [23]
  17 Zucchi, F.; Grassi, V.; Frignani, A.; Trabanelli, G. Corrosion Sci., 2004, 46: 2853
24. [24]
  18 Zucchi, F.; Frignani, A.; Grassi, V.; Trabanelli, G.; DalColle, M. Corrosion Sci., 2007, 49: 1570
25. [25]
  19 Sinapi, F.; Lejeune, I.; Delhalle, J.; Mekhalif, Z. Electrochim. Acta, 2007, 52: 5182
26. [26]
  20 Sinapi, F.; Julien, S.; Auguste, D.; Hevesi, L.; Delhalle, J.; ekhalif, Z. Electrochim. Acta, 2008, 53: 4228
27. [27]
  21 Chen, M. A.; Xie, X.; Qi, H. Y.; Zang, X. M.; Li, H. Z.; Yang, X. Acta Phys. -Chim. Sin., 2006, 22: 1025
28. [28]
  [陈明安, 谢玄, 戚海英, 张新明, 李慧中, 杨汐. 物理化学学报, 2006, 22: 1025]
29. [29]
  22 Zhu, D. Q.;Van Ooij,W. J. J. Adhesion Sci. Technol., 2002, 16: 1235
30. [30]
  23 Chen, M. A.; Xie, X.; Zhang, X. M. Prog. Org. Coat., 2009, 66: 40
31. [31]
  24 Wang, C. T. Study of self-assembled films on copper surface for orrosion inhibition
32. [32]
  [D]. Jinan: Shandong University, 2003 王春涛. 铜表面组装缓蚀功能有序分子膜的研究
33. [33]
  [D]. 济南: 刘东大学, 2003]
34. [34]
  25 Quan, Z. L.; Chen, S. H.; Li, Y.; Cui, X. G. Corrosion Sci., 2002, 44: 703
35. [35]
  26 Cao, C. N. Principles of electrochemistry of corrosion. 3rd ed. eijing: Chemical Industry Press, 2008: 175-186
36. [36]
  [曹楚南. 腐蚀电化学原理. 第三版. 北京: 化学工业出版社, 2008: 175-186]
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