Citation: CHEN Hua-Rong, CHANG Ran-Ran, LI Li, YUAN Wen-Hui. High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 241-247. doi: 10.3866/PKU.WHXB20110119 shu

High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface

1.
1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China;
2. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 8 September 2010
Available Online: 2 December 2010
Fund Project: 国家自然科学基金(20976057)资助项目 (20976057)

Positively charged organic-functionalized α-Al₂O₃ ceramic hollow fiber was obtained by dip-coating the substrate with a 3-aminopropyl-(diethoxy)methylsilane (ADMS) solution. Negatively charged NaA zeolite particles were deposited on the substrate surface and used as seed for further secondary growth by the electrostatic adsorption of a positively charged organic-functionalized substrate and NaA zeolite particles. The NaA zeolite membrane was synthesized on a porous α-Al₂O₃ ceramic hollow fiber support by the microwave heating-secondary growth method. The as-synthesized NaA zeolite membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), zeta potential, and gas permeation tests. The differences in morphology, structure, and gas permeability between the NaA zeolite and the ADMS-modified substrate supported NaA zeolite membrane were determined. XRD results show that only NaA zeolite is present on the support. The zeta potential results indicate that opposite charges exist between the NaA zeolite seed or precursor and the organic-functionalized substrate surface, which confirms the electrostatic adsorption between them. SEM images show that a smooth and dense membrane (5 μm thick) is obtained and the particles are twinborn by od intergrowth on the ADMS-modified substrate supported NaA zeolite membrane surface. Gas permeation tests with H₂, O₂, N₂, and C₃H₈ at different temperatures show that the permeability of H₂ on the ADMS-modified substrate supported NaA zeolite membrane at 35 °C is 3.6×10^-7 mol·m^-2·s^-1·Pa^-1, which is lower than that (4.0×10^-7 mol·m^-2·s^-1·Pa^-1) of the NaA zeolite membrane. The ideal permselectivity of H₂/C₃H₈ is 11.25, which is far higher than that (5.06) of the NaA zeolite membrane.
- Hollow fiber,
- Organic-functionalization,
- NaA zeolite membrane,
- Microwave heating,
- Hydrogen separation
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High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al2O3 Ceramic Hollow Fiber Surface

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通讯作者: 陈斌, bchen63@163.com

High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface