Citation: WANG Bin, DU Min, ZHANG Jing. Inhibition Performance of an Imidazoline Derivative as a Gas-Liquid Two-Phase Inhibitor for Q235 Steel against CO₂ Corrosion[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 120-126. doi: 10.3866/PKU.WHXB20110117 shu

Inhibition Performance of an Imidazoline Derivative as a Gas-Liquid Two-Phase Inhibitor for Q235 Steel against CO₂ Corrosion

1.
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education,College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, Shandong Province, P. R. China

Received Date: 20 September 2010
Available Online: 1 December 2010
Fund Project: 国家自然科学基金(40806030)资助项目 (40806030)

We investigated the inhibition performance of a new imidazoline derivative inhibitor, TAI, which can be used as a gas-liquid two-phase inhibitor against CO₂ corrosion by weight-loss method, electrochemical impedance spectroscopy (EIS), Fourier-transform infrared (FT-IR) spectroscopy, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). Results revealed that the thioureido imidazoline inhibitor was an effective inhibitor against CO₂ corrosion in gas and liquid two phases. Surface analysis by AFM showed that damage to the metallic surface was considerably reduced in the presence of the TAI inhibitor. A bigger adhesive force between the AFM probe and the steel surface was detected owing to hydrophobic interaction from the inhibitors in the two phases. The long range-repulsive force between the AFM probe and the steel surface increased in gas phase but decreased in liquid phase by the screening effect of surface charges. XPS and FT-IR spectroscopy proved that the adsorption films on the metal surfaces with protective properties of TAI and acid hydrolysis products of the TAI (amides) were present in liquid phase and in gas phase, respectively. The above results further confirmed the hydrolysis mechanism of imidazoline derivatives in acid solution.
- CO₂ corrosion,
- Imidazoline derivative,
- Acid hydrolysis,
- Fourier transform infrared spectroscopy,
- Atomic force microscopy,
- X-ray photoelectron spectroscopy
1. [1]
  
  1. Nesic, S.; Pots, B. F. M.; Postlethwaite, J.; Thevenot, N. J. Corr.Sci. Eng., 1996, 1: 3
2. [2]
  2. Lopez, D. A.; Schreiner,W. H.; De Sanchez, S. R.; Simison, S. N.Appl. Surf. Sci., 2004, 236: 77
3. [3]
  3. Zhang, X. Y.;Wang, F. P.; He, Y. F.; Du, Y. L. Corrosion Sci.,2001, 43: 1418
4. [4]
  4. Nesic, S.; Nordsveen, M.; Maxwell, N.; Vrhovac, M. Corrosion Sci., 2001, 43: 1373
5. [5]
  5. Amri, J.; Gulbrandsen, E.; Nogueira, R. P. Electrochem. Commun., 2008, 10: 200
6. [6]
  6. Durnie,W. H.; Kinsella, B. J.; De Marco, R.; Jefferson, A. J. Appl. Electrochem., 2001, 31: 1221
7. [7]
  7. Liu, X.; Okafor, P. C.; Zheng, Y. G. Corrosion Sci., 2009, 51: 744
8. [8]
  8. Liu, F. G.; Du, M.; Zhang, J.; Qiu, M. Acta Phys. -Chim. Sin., 2008, 24: 138.
9. [9]
  [刘福国, 杜敏, 张静, 仇萌. 物理化学学报, 2008, 24: 138. ]
10. [10]
  9. Song, F. M.; Kirk, D.W.; Graydon, J.W.; Cormack, D. E. Corrosion, 2004, 60: 736
11. [11]
  10. Ramachandran, S.; Jovancicevic, V. Corrosion, 1999, 55: 259
12. [12]
  11. Edwards, A.; Osborne, C.;Webster, S.; Klenerman, D.; Joseph, M.; Ostovar, P.; Doyle, M. Corrosion Sci., 1994, 36: 315
13. [13]
  12. Jovancicevic, V.; Ramachandran, S.; Prince, P. Corrosion, 1999, 55: 449
14. [14]
  13. Tan, Y. J.; Bailey, S.; Kinsella, B. Corrosion Sci.,1996, 38: 1545
15. [15]
  14. Durnie,W.; De Marco, R.; Jefferson, A.; Kinsella, B. J. Electrochem. Soc., 1999, 146: 1751
16. [16]
  15. Popova, A.; Christor, M.; Raicheva, S.; Sokolova, E. Corrosion Sci., 2004, 46: 1333
17. [17]
  16. Okafor, P. C.; Zheng, Y. G. Corrosion Sci.,2009, 51: 850
18. [18]
  17. ASTM E 200-01, Standard practice for preparation, standardization and storage of standard and reagent solutions for chemical analysis, ASTM book of standards. Vol. 15.02.West Conshohocken, PA, 2001
19. [19]
  18. ASTM G 01-03, Standard practice for preparing, cleaning and evaluating corrosion test specimens, ASTM book of standards. Vol.3.02.West Conshohocken, PA, 2003
20. [20]
  19. ASTM G 31-72, Standard practice for laboratory immersion corrosion testing of metals, ASTM Book of Standards. Vol.3.02. West Conshohocken, PA, 2004
21. [21]
  20. Liu, F. G.; Du, M.; Zhang, J.; Qiu, M. Corrosion Sci., 2009, 51: 102
22. [22]
  21. Lopez, D. A.; Simison, S. N.; De Sanchez, S. R. Corrosion Sci.,2005, 47: 735
23. [23]
  22. Khaled, K. F.; Hackerman, N. Electrochim. Acta, 2003, 48: 2715
24. [24]
  23. Moretti, G.; Guidi, F.; Grion, G. Corrosion Sci., 2004, 46: 387
25. [25]
  24. McCafferty, E.; Hackerman, N. J. Electrochem. Soc., 1972, 119:146
26. [26]
  25. Muralidharan, S.; Phani, K. L. N.; Pitchumani, S.; Ravichandran, S.; Lyer, S. V. K. J. Electrochem. Soc., 1995, 142: 1478
27. [27]
  26. Limatibul, S.;Watson, J.W. J. Org. Chem., 1971, 36: 3803
28. [28]
  27. Reese, S. R.; Fox, M. A. J. Phys. Chem. B, 1998, 102: 9820
29. [29]
  28. Jakubowicz, A.; Jia, H.;Wallace, R. M.; Gnade, B. E. Langmuir,2005, 21: 950
30. [30]
  29. Liu, X. Y.; Chen, S. H.; Ma, H. Y.; Liu, G. Z.; Shen, L. X. Appl.Surf. Sci., 2006, 253: 814
31. [31]
  30. Wang, D. X.; Li, S. Y.; Yu, Y. Corrosion Sci., 1999, 41: 735
32. [32]
  31. Olivares-Xometl, O.; Likhanova, N. V.; Dominguez-Aguilar, M.A.; Hallen, J. M.; Zamudio, L. S.; Arce, E. Appl. Surf. Sci., 2006,252: 2139
33. [33]
  32. Weisenhorn, A. L.; Hansma, P. K. Appl. Phys. Lett., 1989, 54:2651
34. [34]
  33. Ai, J. Z.; Guo, X. P.; Qu, J. E.; Chen, Z. Y.; Zheng, J. S. Colloid Surf. A-Physicochem. Eng. Asp., 2006, 281: 147
35. [35]
  34. Tsao, Y. H.; Evans, D. F.;Wennerstrom, H. Science, 1993, 262:547
36. [36]
  35. Liu, X. Y.; Chen, S. H.; Zhai, H. Y.; Shen, L. X.; Zhou, J. J.;Wu,L. Electrochem. Commun., 2007, 9: 813
37. [37]
  36. Auger and X-ray photoelectron spectroscopy, Vol.1.//Practical surface analysis. 2nd ed. Briggs, D.; Seah, M. P. Eds. Chichester, England: JohnWiley & Sons, 1990
38. [38]
  37. Moulder, F.; Stickle,W. F.; Sobol, P. E.; Bomben, K. D. Handbook of X-ray photoelectron spectroscopy. Chaitain, J. Ed. Minnesota, USA: Perkin-Elmer Corp., 1992
39. [39]
  38. NIST X-Ray photoelectron spectroscopy database, NIST standard reference database 20. Vol.1. Gaithersburg, USA, 1989
40. [40]
  39. Sastri, V. S.; Elboujdaini, M.; Roma, J. R.; Perumareddi, J. R. Corrosion, 1996, 52: 447
41. [41]
  40. Zhang, D. Q.; Gao, L. X.; Zhou, G. D. J. Appl. Electrochem., 2003, 33: 361
42. [42]
  41. Zhang, D. Q.; Gao, L. X.; Zhou, G. D. Surf. Coat. Technol., 2010, 204: 1646
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Inhibition Performance of an Imidazoline Derivative as a Gas-Liquid Two-Phase Inhibitor for Q235 Steel against CO2 Corrosion

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通讯作者: 陈斌, bchen63@163.com

Inhibition Performance of an Imidazoline Derivative as a Gas-Liquid Two-Phase Inhibitor for Q235 Steel against CO₂ Corrosion