Citation: YE Qing, ZHAO Jian-Sheng, LI Dong-Hui, ZHAO Jun, CHENG Shui-Yuan, KANG Tian-Fang. Au/SnO₂ and M-Au (M=Pt, Pd)/SnO₂ Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 169-176. doi: 10.3866/PKU.WHXB20110108 shu

Au/SnO₂ and M-Au (M=Pt, Pd)/SnO₂ Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO

1.
Department of Environmental Science, College of Environmental and Energy Engineering, Beijing University of Technology,Beijing 100124, P. R. China

Received Date: 10 August 2010
Available Online: 23 November 2010
Fund Project: 国家自然科学基金项目(20777005) (20777005) 北京市自然科学基金项目(8082008) (8082008) 北京市组织部优秀人才基金项目(20071D0501500210) (20071D0501500210)北京工业大学人才强教深化计划项目(PHR201007105)资助 (PHR201007105)

Au/SnO₂ catalysts were prepared by deposition-precipitation (DP), co-precipitation (CP) and typical wet impregnation methods (IM). M(M=Pt, Pd)-promoted Au/SnO₂ catalysts were prepared by the DP method. The samples were characterized by X-ray diffraction (XRD), Brunaner-Emmett-Teller (BET) adsorption, transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) techniques. The results showed that compared with CP and IM, the DP method led to a fairly uniform dispersion of ld nanoparticles with diameters less than 5 nm and larger specific surfaces for the Au/ SnO₂ catalyst. The Au in Au/SnO₂-DP was metallic (Au⁰) while in Au/SnO₂-CP and Au/SnO₂-IM the Au consisted of a mixture of Au⁰ and Au³⁺. The oxidation of carbon monoxide over the Au/SnO₂-DP and Mpromoted Au/SnO₂-DP catalysts were investigated. We observed that the Pd- or Pt-doping of Au/SnO₂-DP resulted in a significant increase in performance. We conclude that the different activities of the Au/SnO₂ catalysts that were prepared using different preparation methods may be attributed to the size of the Au particles and the states of ld. A remarkable improvement in catalytic activity because of Pd or Pt doping was associated with strong interactions between Pd or Pt and Au.
- Au/SnO₂,
- Low-temperature catalytic oxidation of CO,
- Preparation method,
- Au binary catalyst
1. [1]
  
  1. Gardner, S. D.; Hoflund, G. B.; Schryer, D. R.; Schryer, J.; Upchurch, B. T.; Kielin, E. J. Langmuir., 1991, 7: 2135
2. [2]
  2. Li, Q. X.; Zhou, X. J.; Li, J. G.; Xu, Q. J. Acta Phys. -Chim. Sin.,2010, 26: 1488.
3. [3]
  [李巧霞, 周小金, 李金光, 徐群杰. 物理化学学报, 2010, 26: 1488]
4. [4]
  3. Liu, Y. J.; Zhang, J. J.; Li, N.; Lin, B. X. Acta Phys. -Chim. Sin., 1999, 15: 97.
5. [5]
  [刘英骏, 张继军, 李能, 林炳雄. 物理化学学报 1999, 15: 97]
6. [6]
  4. Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett., 1987. , 2: 405
7. [7]
  5. Zhang, X.; Shi, H.; Xu, B. Q. Catal. Today, 2007, 122: 330
8. [8]
  6. Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. J. Catal., 1989, 115: 301
9. [9]
  7. Haruta, M.; Tsubota, S.; Kobayashi, T.; Kageyama, H.; Genet, M. J.; Delmon, B. J. Catal.,1993, 144: 175
10. [10]
  8. Santhosh, P. N.; Potde, H. S.; Date, S. K. J. Mater. Res., 1997, 12: 326
11. [11]
  9. Kung, M. C.; Park, P.W.; Kim, D.W.; Kung, H. H. J. Catal., 1999, 181: 1
12. [12]
  10. Chang, C. K.; Chen, Y. J.; Yeh, C. T. Appl. Catal. A, 1998, 174: 13
13. [13]
  11. Buffat, P.; Borel J.P. Phys. Rev. A, 1976, 13: 2287
14. [14]
  12. Haruta, M. Catal. Today, 1997, 36: 153
15. [15]
  13. Ivanova, S.; Petit, C.; Pitchon, V. Appl. Catal. A, 2004, 267: 191
16. [16]
  14. Tsubota, S.; Cunningham, D. A. H.; Bando, Y. ; Haruta, M. Stud. Surf. Sci. Catal., 1995, 91: 227
17. [17]
  15. Bollinger, M. A.; Vannice, M. A. Appl. Catal. B, 1996, 8: 417
18. [18]
  16. Wagner, C. D.; Moulder, J. F.; Davis, L. E.; Riggs,W. M. Handbook of X-ray photoelectron spectroscopy. Minnesota:Perkin-Elmer, 1979
19. [19]
  17. Lin, J. N.; Chen, J. H.; Hsiao, C. Y.; Kang, Y. M.;Wan, B. Z. Appl. Catal. B, 2002, 36: 19
20. [20]
  18. Soares, J. M. C.; Morrall, P.; Crossley, A.; Harris, P.; Bowker, M. J. Catal., 2003, 219: 17
21. [21]
  19. Visco, A. M.; Neri, F.; Neri, G.; Donato, A.; Milone, C.; Galvagno, S. Phys. Chem. Chem. Phys., 1999, 1: 2869
22. [22]
  20. Radnik, J.; Mohr, C.; Claus, P. Phys. Chem. Chem. Phys., 2003, 5: 172
23. [23]
  21. Arrii, S.; Morfin, F.; Renouprez, A. J.; Rousset, J. L. J. Am. Chem.Soc., 2004, 126: 1199
24. [24]
  22. Nascente, P. A. P.; de Castro, S. G. C.; Landers, R.; Kleiman, G. G. Phys. Rev. B, 1991. 43:4659
25. [25]
  23. Yi, C.W.; Luo, K.;Wei, T.; odman, D.W. J. Phys. Chem. B, 2005, 109:18535
26. [26]
  24. Li, C. Y.; Shen, Y. N.; Hu, R. S., Transactions of Nonferrous Metals Society of China, 2007: s1107.
27. [27]
  [李常艳, 沈岳年, 胡瑞生中国有色金属学会会刊, 2007, 17: s1107]
28. [28]
  25. Li, J. L.;Wang H. L. Environ. Sci. Tech., 1995, 70. (3) :10.
29. [29]
  [李金林, 王海龙. 环境科学与技术, 1995, 70. (3):10]
30. [30]
  26. Grutsch, P. A.; Zeller, M. V.; Fehlner, T. P. Inorg. Chem., 1973, 12: 1431
31. [31]
  27. Bond, G. C.; Thompson, D. T. Catal. Rev. Sci. Eng., 1999, 41: 319
32. [32]
  28. Schubert, M. M. S.; Hackenberg, A. C.; van Veen, M.; Muhler, V. Plzak, R. J. Behm. J. Catal., 2001, 197: 113.
33. [33]
  29. Grisel, R. J. H.; Nieuwenhuys, B. E. Catal. Today, 2001, 64: 69.
34. [34]
  30. Henao, J. D.; Caputo, T.; Yang, J. H.; Kung, M. C.; Kung, H. H. J. Phys. Chem. B, 2006, 110: 8689
35. [35]
  31. Venezia, A. M.; La Parola, V.; Nicoli, V.; Deganello, G. J. Catal., 2002, 212: 56
36. [36]
  32. Kochubey, D. I.; Pavlova, S. N.; Nov rodov, B. N.; Kryukova, G. N.; Sadykov, V.A. J. Catal., 1996, 161: 500
37. [37]
  33. Nutt, M. O.; Heck, K. N.; Alvarez, P.;Wong, M. S. Appl. Catal. B, 2006, 69: 115
38. [38]
  34. Edwards, J. K.; Solsona, B. E.; Landon, P.; Carley, A. F.; Herzing, A.; Kiely, C. J.; Hutchings, G. J. J. Catal., 2005, 236: 69
39. [39]
  35. Enache, D. I.; Edwards, J. K.; Landon, P.; Solsona, B. E.; Carley,A. F.; Herzing, A. A.;Watanabe, M.; Kiely, C. J.; Knight, D.W.; Hutchings, G. J. Science, 2006, 311: 362
40. [40]
  36. Comotti, M.; Li,W. C.; Spliethoff, B.; Schuth, F. J. Am. Chem. Soc., 2006, 128: 917
41. [41]
  37. Liu, H. C.; Kozlov, A. I.; Kozlova, A. P.; Shido, T.; Akasura, K.; Iwasawa, Y. J. Catal., 1999, 18x5: 252
42. [42]
  38. Gangal, N. D.; Gupta, N. M.; Iyer, R. M. J. Catal., 1990, 126. :13
1. [1]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
2. [2]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-0. doi: 10.3866/PKU.WHXB202407021
3. [3]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
10. [10]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
11. [11]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
14. [14]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
19. [19]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
20. [20]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174

Get Citation

PDF

XML

Metrics

PDF Downloads(1432)
Abstract views(2834)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Au/SnO2 and M-Au (M=Pt, Pd)/SnO2 Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO

Metrics

通讯作者: 陈斌, bchen63@163.com

Au/SnO₂ and M-Au (M=Pt, Pd)/SnO₂ Bimetallic Catalysts for the Low-Temperature Catalytic Oxidation of CO