Citation: WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai. Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3317-3321. doi: 10.3866/PKU.WHXB20101226 shu

Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor

1.
College of Physics Science & Technology, Hebei University, Baoding 071002, Hebei Province, P. R China

Received Date: 2 August 2010
Available Online: 10 November 2010
Fund Project: 国家自然科学基金(50902042) (50902042) 河北省自然科学基金(E2009000209, E2010000283) (E2009000209, E2010000283) 河北省教育厅基金(2009313) (2009313)发光与光信息技术教育部重点实验室研究基金(2010LOI12)资助项目 (2010LOI12)

We synthesized a kind of green phosphor, NaBaPOM₄:Tb³⁺, by the high temperature solid-state method, and investigated its luminescent characteristics. NaBaPO₄:Tb³⁺ has several emission peaks, and these are located at 437, 490, 543, 587, and 624 nm, which correspond to the ⁵D₃→⁷D₄ and ⁵D₄→⁷F_{J=6. 5, 4, 3} transitions of Tb³⁺, respectively. The main peak is at 543 nm. The excitation spectrum (monitored at an emission wavelength of 543 nm) consists of several bands, and the main peak is located at 380 nm. The effect of amount of Tb³⁺ doping content, the compensators (Li⁺, Na⁺, K⁺, or Cl^-), and the sensitizer activator Ce³⁺ on the emission intensity of the NaBaPOM₄:Tb³⁺ phosphor were also studied. The results show that the emission intensity can be controlled by the above factors, and the intensity can be enhanced by selecting the prime optimum conditions.
- Luminescent characteristics,
- NaBaPOM₄：Tb³⁺,
- Green phosphor
1. [1]
  
  1. Nakamura, S.; Fasol, G. The blue laser diode. Berlin: Springer-Verlag, 1997: 1
2. [2]
  2. Setlur, A. A.; Heward,W. J.; Gao, Y.; Srivastava, A. M.; Chandran, R. G.; Shankar, A. V. Chem. Mater., 2006, 18(14): 3314
3. [3]
  3. Li, P. L.; Yang, Z. P.;Wang, Z. J.; Xiong, Z. J.; Guo, Q. L. Acta Phys.-Chim. Sin., 2008, 24(1): 179
4. [4]
  [李盼来, 杨志平, 王志军, 熊志军, 郭庆林. 物理化学学报, 2008, 24(1): 179]
5. [5]
  4. Kuo, C. H.; Sheu, J. K.; Chang, S. J.; Su, Y. K.;Wu, L.W.; Tsai, J. M.; Liu, C. H.;Wu, R. K. Jpn. J. Appl. Phys., 2003, 42(4B): 2284
6. [6]
  5. Du, H.; Sun, J.; Xia, Z.; Sun, J. Appl. Phys. B, 2009, 96: 459
7. [7]
  6. Zhang, J. C.;Wang, Y. H.; Zhang, Z. Y.; Xie, P.; Li, H. H.; Jiang, Y. P. Chin. Phys. Lett., 2008, 25(4): 1453
8. [8]
  7. Liao, J. S.; Liu, B.; Lai, H. S. J. Lumin., 2009, 129: 668
9. [9]
  8. Li, P. L.; Pang, L. B.;Wang, Z. J.; Yang, Z. P.; Guo, Q. L.; Li, X. J. Alloy. Compd., 2009, 478: 813
10. [10]
  9. Tang, Y. S.; Hu, S. F.; Lin, C. C.; Bagkar, N. C.; Liu, R. S. Appl. Phys. Lett., 2007, 90: 151108-1
11. [11]
  10. Wu, Z. C.; Liu, J.; ng, M. L.; Su, Q. J. Electrochem. Soc., 2009, 156(3): H153
12. [12]
  11. Liao, J. S.; Qiu, B.;Wen, H. R.; Chen, J, L.; You,W. X. Mater. Res. Bull., 2009, 44: 1863
13. [13]
  12. Meng, Q. Y.; Chen, B. J.; Xu,W.; Zhao, X. X.; Yang, Y. M.; Di, W. H.;Wang, X. J. Spectroscopy and Spectral Analysis, 2009, 29 (1): 151
14. [14]
  [孟庆裕, 陈宝玖, 许武, 赵晓霞, 杨艳民, 狄卫华, 王晓君. 光谱学与光谱分析, 2009, 29(1): 151]
15. [15]
  13. Chen, Y.;Wang, J.; Zhang, X. G.; Zhang, G. G.; ng, M. L.; Su, Q. Sensors and Actuators B: Chemical, 2010, 148: 259
16. [16]
  14. Lu ,J.; Huang, Y. L.; Tao, Y.; Seo, H. J. J. Alloy. Compd., 2010, 500: 134
17. [17]
  15. Sun, L. D.; Qian, C.; Liao, C. S.;Wang, X. L.; Yan, C. H. Solid State Commun., 2001, 119: 393
18. [18]
  16. Li, X.; Yang, Z. P.; Guan, L.; Guo, J. X.;Wang, Y.; Guo, Q. L. J. Alloy. Compd., 2009, 478: 684
19. [19]
  17. Turos-Matysiak, R.; Gryk,W.; Grinberg, M.; Lin, Y. S.; Liu, R. S. Radiation Measurements, 2007, 42: 755
20. [20]
  18. Liu, X. R.;Wang, X. J.;Wang, Z. K. Phys. Rev. B, 1989, 39: 10633
1. [1]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
2. [2]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
3. [3]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
4. [4]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
5. [5]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
6. [6]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
7. [7]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
8. [8]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
9. [9]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
10. [10]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
11. [11]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
12. [12]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
13. [13]
  Borong Yu , Huijiao Zhang , Xinyu Zhang , Xiaoying Li , Shuming Chen , Zhangang Han . The Blue Elf in the Dark: Gradient Science Popularization Experiments on Chemiluminescence. University Chemistry, 2024, 39(9): 295-303. doi: 10.12461/PKU.DXHX202403107
14. [14]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
15. [15]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
16. [16]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
17. [17]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
18. [18]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
19. [19]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
20. [20]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718

Get Citation

PDF

XML

Metrics

PDF Downloads(1125)
Abstract views(2377)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescent Characteristics of the NaBaPOM4:Tb3+ Green Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor