Citation: YANG Xiao-Long, XIA Chun-Gu, TANG Li-Ping, XIONG Xu-Mao, MU Xin-Yuan, HU Bin. Effect of Alumina Support and Barium Oxide on the Structure and Catalytic Activity of Ruthenium Catalysts for Ammonia Synthesis[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3263-3272. doi: 10.3866/PKU.WHXB20101223 shu

Effect of Alumina Support and Barium Oxide on the Structure and Catalytic Activity of Ruthenium Catalysts for Ammonia Synthesis

1.
1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 1 September 2010
Available Online: 8 November 2010
Fund Project: 国家杰出青年科学基金(20625308)资助项目 (20625308)

A series of Ba-Ru/Al₂O₃ catalysts were prepared by the impregnation method using industrial alumina (Al₂O₃-1) and synthesized alumina (Al₂O₃-2) as supports. The catalysts were characterized by X-ray diffraction, N2 adsorption-desorption, X-ray fluorescence spectroscopy, transmission electron microscopy, H₂ temperature-programmed reduction, NH₃ temperature-programmed desorption, and X-ray photoelectron spectroscopy. The effect of Al₂O₃ and the BaO promoter on the phase structure, texture properties, morphology, surface properties, and catalytic activity in ammonia synthesis were investigated. The results indicate that the physical and chemical properties of Al₂O₃ have a strong impact on the structure and activity of the ruthenium catalysts. The BaO promoter has a strong impact on the ruthenium catalyst in two ways: first, the amount of BaO added leads to a difference in the interaction between BaO and γ-Al₂O₃, which further influences the specific area and the porous structure of the catalysts; second, the addition of BaO influences the reduction process and the surface acidity and alkaline properties of the ruthenium catalysts. A proper amount of BaO promotes the activity and the optimal amount of BaO depends on the properties of the supports.
- Ammonia synthesis,
- γ-Al₂O₃,
- Support,
- Ruthenium,
- Reduce,
- Acidity
1. [1]
  
  1. Liang, C. H.; Wei, Z. B.; Xin, Q.; Li, C. Appl. Catal. A., 2001, 208: 193
2. [2]
  2. Yang, X. L.; Hu, B.; Xia, C. G.; Xiong, X. M.; Mu, X. Y. Ind. Catal., 2010, 18: 5
3. [3]
  [杨晓龙, 胡斌, 夏春谷, 熊绪茂, 慕新元. 工业催化, 2010, 18: 5]
4. [4]
  3. You, Z. X.; Inazu, K.; Aika, K.; Baba, T. J. Catal., 2007, 251: 321
5. [5]
  4. Zhang, X. B.; Li, X. N.; Huo, C.; Cen, Y. Q.; Zhu, Y. F.; Liu, H. Z. Chin. J. Catal., 2002, 23: 207
6. [6]
  [张新波, 李小年, 霍超, 岑亚青, 祝一峰, 刘化章. 催化学报, 2002, 23: 207]
7. [7]
  5. Szmigiel, D.; Raróg-Pilecka, W.; MiSkiewicz, E.; Gliński, M.; Kielak, M.; Kaszkur, Z.; Kowalczyk, Z. Appl. Catal. A, 2004, 273: 105
8. [8]
  6. Xu, Q. C.; Lin, J. D.; Fu, X. Z.; Liao, D. W. Catal. Commun., 2008, 9: 1214
9. [9]
  7. Ni, J.;Wang, R.; Lin, J. X.;Wei, K. M. Acta Phys. -Chim. Sin., 2009, 25(3): 519
10. [10]
  [倪军, 王榕, 林建新, 魏可镁. 物理化学学报, 2009, 25(3): 519]
11. [11]
  8. Luo, X. J.;Wang, R.; Ni, J.; Lin, J. X.; Lin, B. Y.; Xu, X. M.;Wei, K. M. Catal. Lett., 2009, 133: 382
12. [12]
  9. Larichev, Y. V.; Moroz, B. L.; Zaikovskii, V. L.; Yunusov, S. M.; Kalyuzhnaya, E. S.; Shur, V. B.; Bukhtiyarov, V. I. J. Phys. Chem. C, 2007, 111: 9427
13. [13]
  10. Miyazaki, A.; Balint, I.; Aika, K.; Nakano, Y. J. Catal., 2001, 204: 364
14. [14]
  11. Kadowaki, Y.; Aika, K. J. Catal., 1996, 161: 178
15. [15]
  12. Siporin, S. E.; Davis, R. J. J. Catal., 2004, 225: 359
16. [16]
  13. Wang, R.;Wei, K. M.; Lin, J. X.; Yu, X. J.; Mao, S. L. Ind. Catal., 2005, 13: 31
17. [17]
  [王榕, 魏可镁, 林建新, 俞秀金, 毛树禄. 工业催化, 2005, 13: 31]
18. [18]
  14. Mao, S. L.; Wang, R.; Yu, X. J.; Lin, J. X.;Wei, K. M. Chin. Rare Earth, 2004, 25: 18
19. [19]
  [毛树禄, 王榕, 俞秀金, 林建新, 魏可镁. 稀土, 2004, 25: 18]
20. [20]
  15. Fu,W. J. The Preparation and Study of the Ruthenium Catalysts for Ammonia Synthesis
21. [21]
  [D]. Fuzhou: Fuzhou University, 2003
22. [22]
  [傅武俊. 钌催化剂的制备及氨合成催化性能的研究
23. [23]
  [D]. 福州: 福州大学, 2003]
24. [24]
  16. Liu, H. Z. Ammoina synthesis catalysis: practice and theory. Beijing: Chemical Industry Press, 2007: 309, 293
25. [25]
  [刘化章. 氨合成催化剂实践与理论. 北京: 化学工业出版社, 2007: 309, 293]
26. [26]
  17. Okal, J. Catal. Commun. 2010, 11: 508
27. [27]
  18. Huo, C.; Yan, G.; Zheng, Y. F.; Yu, F.W.; Liu, H. Z. Chin. J. Catal., 2007, 28: 484
28. [28]
  [霍超, 晏刚, 郑遗凡, 于凤文, 刘化章. 催化学报, 2007, 28: 484]
29. [29]
  19. Sharma, L. D.; Kumar, M.; Saxena, A. K.; Chand, M.; Gupta, J. K. J. Mol. Catal. A, 2002, 185: 135
30. [30]
  20. Li,Y.; Yang, Q. H.; Yang, J.; Li, C. Microporous Mesopor Mat., 2006, 91: 85
31. [31]
  21. Yuan, Z. Y.;Wang, J. Z.; Zhang, Z. L.; Chen, T. H.; Li, H. X. Microporous Mesoporous Mat., 2001, 43: 227
32. [32]
  22. Groen, J. C.; Pérez-Ramírez, J. Appl. Catal. A, 2004, 268: 121
33. [33]
  23. Jacobsen, C. J. H.; Dahl, S.; Hansen, P. L.; Törnqvist, E.; Jensen, L.; Topsφe, H.; Prip, D. V.; Mφenshaug, P. B.; Chorkendorff, I. J. Mol. Catal. A, 2000, 163: 19
34. [34]
  24. Seetharamulu, P.; Siva Kumar, V.; Padmasri, A. H.; David Raju, B.; Rama Rao, K. S. J. Mol. Catal. A, 2007, 263: 253
35. [35]
  25. Seetharamulu, P.; Hari Prasad Reddy, K.; Padmasri, A. H.; Rama Rao, K. S.; David Raju, B. Catal. Today, 2009, 141: 94
36. [36]
  26. Huo, C.; Xia, Q. H.; Luo, Y.; Yang, X. Z.; Liu, H. Z. Chin. J. Catal., 2009, 30: 537
37. [37]
  [霍超, 夏庆华, 骆燕, 杨霞珍, 刘化章. 催化学报, 2009, 30: 537-542]
38. [38]
  27. Hanse, T.W.;Wagner, J. B.; Hansen, P. L.; Dahl, S.; Topsφe, H.; Jacobsen, C. J. H. Science, 2001, 294: 1508
39. [39]
  28. Dahl, S.; Logadottir, A.; Jacobsen, C. J. H.; Nφrskov, J. K. Appl. Catal. A, 2001, 222: 19
40. [40]
  29. Zhao, Y. Ind. Catal., 2002, 10: 54
41. [41]
  [赵琰, 工业催化, 2002, 10: 54]
42. [42]
  30. Walker, G. S.; Pyke, D. R.;Werrett, C. R.;Williams, E.; Bhattacharya, A. K. Appl. Surf. Sci., 1999, 147: 228
43. [43]
  31. Somorjai, G. A. Science, 1978, 201: 489
44. [44]
  32. Nagai, M.; Koizumi, K.; Omi, S. Catal. Today, 1997, 35: 393
45. [45]
  33. Elmasides, C.; Kondarides, D. I., Grünert,W.; Verykios, X. E. J. Phys. Chem. B, 1999, 103: 5227
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