Citation: ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke. 5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3175-3180. doi: 10.3866/PKU.WHXB20101141 shu

5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides

1.
1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
2. School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, Anhui Province, P. R. China

Received Date: 6 July 2010
Available Online: 20 October 2010
Fund Project: 国家重点基础研究发展计划项目(973)(2007CB209703) (973)(2007CB209703)国家自然科学基金(20633040, 20873064)资助 (20633040, 20873064)

Co-Ni layered double hydroxides (Co_xNi_1-x LDHs) were successfully synthesized by a 5- sulfosalicylic acid (SSA)-assisted hydrothermal process. Structural and morphological characterizations were performed using powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The results reveal that different morphologies of Co_xNi_1-x LDHs could be obtained by tuning the Co/Ni molar ratio. The Co_xNi_1-x LDHs exhibit petal-like nanospheres that are composed of nanoflakes at a Co molar fraction of 0.24. The LDH of this structure has a specific capacitance of 1735 F·g^-1 at a current density of 1 A·g^-1 as determined by cyclic voltammetry and galvanostatic charge-discharge.
- Supercapacitor,
- Layered double hydroxide,
- 5-Sulfosalicylic acid,
- Hydrothermal method
1. [1]
  
  1. Conway, B. E. J. Electrochem. Soc., 1991, 138: 1539
2. [2]
  2. Miller, J. R. Electrochim. Acta, 2006, 52: 1703
3. [3]
  3. Jiang, Q.; Qu, M. Z.; Zhang, B. L.;Yu, Z. L. J. Inorg. Mater., 2002, 17(4): 649
4. [4]
  [江奇, 瞿美臻, 张伯兰, 于作龙. 无机材料学报, 2002, 17(4): 649]
5. [5]
  4. Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Adv. Mater., 2010, 22: E28
6. [6]
  5. Wohlfahrt-Mehrens, M.; Schenk, J.;Wilde, P. M.; Abdelmula, E.; Axmann, P.; Garche, J. J. Power Sources, 2002, 105: 182
7. [7]
  6. Liu, X. M.; Zhang, X. G. Chin. J. Appl. Chem., 2003, 20(6): 524
8. [8]
  [刘献明, 张校刚. 应用化学, 2003, 20(6): 524]
9. [9]
  7. Wang, Y.; Yang,W. S.; Zhang, S. C.; Evans, D. G.; Duan, X. J. Electrochem. Soc., 2005, 152: A2130
10. [10]
  8. Zolfaghari, A.; Ataherian, F.; Ghaemi, M.; Gholami, A. Electrochim. Acta, 2007, 52: 2806
11. [11]
  9. Cao, H. Q.; Zheng, H.; Liu, K. Y.;Warner, J. H. ChemPhysChem, 2009, 11: 489
12. [12]
  10. Wang, H.; Fan, G. L.; Zheng, C.; Xiang X.; Li, F. Ind. Eng. Chem. Res., 2010, 49: 2759
13. [13]
  11. Xiao, T.; Tang, Y.W.; Jia, Z. Y.; Li, D.W.; Hu, X. Y.; Li, B. H.; Luo, L. J. Nanotechnology, 2009, 20: 475603
14. [14]
  12. Marzotto, A.; Clemente, D. A.; Gerola, T.; Valle, G. Polyhedron, 2001, 20: 1079
15. [15]
  13. Kushi, Y.; Hosoo, T.; Kuroya, H. J. Chem. Soc. D, 1970: 397
16. [16]
  14. Hu, Z. A.; Xie, Y. L.;Wang, Y. X.;Wu, H. Y.; Yang, Y. Y.; Zhang, Z. Y. Electrochim. Acta, 2009, 54: 2737
17. [17]
  15. Zhang, L. Y.; Lin, Y. J.; Tuo, Z. J.; Evans, D. G.; Li, D. Q. J. Solid State Chem., 2007, 180: 1230
18. [18]
  16. Yin,W. Y.; Chen, X.; Cao, M. H.; Hu, C.W.;Wei, B. Q. J. Phys. Chem. C, 2009, 113: 15897
19. [19]
  17. Xing, Y.; Li, D. Q.; Ren, L. L.; Evans, D. G.; Duan, X. Acta Chim. Sin., 2003, 61(2): 267
20. [20]
  [邢颖, 李殿卿, 任玲玲, Evans D. G., 段雪. 化学学报, 2003, 61(2): 267]
21. [21]
  18. Perez-Ramirez, J.; Mul, G.; Kapteijn, F.; Moulijn, J. A. J. Mater. Chem., 2001, 11: 821
22. [22]
  19. Villegas, J. C.; Giraldo, O. H.; Laubernds K.; Suib, S. L. Inorg. Chem., 2003, 42: 5621
23. [23]
  20. Murakami, Y.; Takagi, M. Bull. Chem. Soc. Jpn., 1964, 37: 268
24. [24]
  21. Mentasti, E.; Secco, F.; Venturini, M. Inorg. Chem., 1980, 19: 3528
25. [25]
  22. Wang, H. L.; Gao, Q. M.; Hu, J. J. Power Sources, 2010, 195: 3017
26. [26]
  23. Zhang, X. G.; Liu, X. M.; Bao, S. J.;Wang, Y. G. Chin. J. Inorg. Chem., 2004, 20(1): 94
27. [27]
  [张校刚, 刘献明, 包淑娟, 王永刚. 无机化学学报, 2004, 20(1): 94]
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