Citation: ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke. 5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3175-3180. doi: 10.3866/PKU.WHXB20101141 shu

5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides

1.
1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
2. School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, Anhui Province, P. R. China

Received Date: 6 July 2010
Available Online: 20 October 2010
Fund Project: 国家重点基础研究发展计划项目(973)(2007CB209703) (973)(2007CB209703)国家自然科学基金(20633040, 20873064)资助 (20633040, 20873064)

Co-Ni layered double hydroxides (Co_xNi_1-x LDHs) were successfully synthesized by a 5- sulfosalicylic acid (SSA)-assisted hydrothermal process. Structural and morphological characterizations were performed using powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The results reveal that different morphologies of Co_xNi_1-x LDHs could be obtained by tuning the Co/Ni molar ratio. The Co_xNi_1-x LDHs exhibit petal-like nanospheres that are composed of nanoflakes at a Co molar fraction of 0.24. The LDH of this structure has a specific capacitance of 1735 F·g^-1 at a current density of 1 A·g^-1 as determined by cyclic voltammetry and galvanostatic charge-discharge.
- Supercapacitor,
- Layered double hydroxide,
- 5-Sulfosalicylic acid,
- Hydrothermal method
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