Citation: SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao. Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3023-3029. doi: 10.3866/PKU.WHXB20101109 shu

Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16

1.
Institute of Industrial Ecology and Environment, Zhejiang University, Hangzhou 310028, P. R. China

Received Date: 27 June 2010
Available Online: 15 September 2010
Fund Project: 国家自然科学基金(20976159)资助项目 (20976159)

Novel CO₂ adsorbents for CO₂ removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesoporous silica using a post-synthetic impregnation method. The properties of the mesoporous materials before and after surface modification were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), and N₂ adsorption-desorption. We confirmed that TEPA was loaded onto the surface of the channels in the mesoporous materials. The surface area, pore size, and pore volume of TEPA-loaded SBA-16 decreased with an increase in TEPA loading while its fundamental pore structure was unchanged. The dynamic adsorption of CO₂ onto TEPA-loaded SBA-16 as well as its regeneration property was studied in a packed column. The total adsorption capacity and breakthrough capacity increased when the amount of loaded TEPA increased from 10% to 30% (w). The sample impregnated with 30% TEPA showed the highest breakthrough capacity and total adsorption capacity of about 0.625 and 0.973 mmol·g^-1 at 60℃, respectively. From 60℃ to 80℃, the CO₂ dynamic adsorption behavior of TEPA-loaded SBA-16 was stable. The total adsorption capacity of CO₂ on TEPA-loaded SBA-16 dropped slightly (6.45%) after 20 adsorption-desorption regeneration cycles. Their CO₂ adsorption behavior was also investigated using the deactivation model, which showed an excellent predictive capability for the breakthrough curves.
- SBA-16,
- Dynamic,
- Breakthrough curve,
- Deactivation model,
- CO₂ adsorption
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16

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通讯作者: 陈斌, bchen63@163.com

Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16