Citation: WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei. Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 2915-2919. doi: 10.3866/PKU.WHXB20101028 shu

Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)

1.
1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. The Translational Medicine R &DCenter, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, Guangdong Province, P. R. China

Received Date: 14 May 2010
Available Online: 17 September 2010
Fund Project: 国家自然科学基金(20976197) (20976197)高等学校博士学科点专项科研基金(20090162120013)资助项目 (20090162120013)

The thermal decomposition kinetics of the novel terpolymer, poly(propylene carbonate maleate) (PPCMA), was investigated using thermogravimetric (TG) analysis at different heating rates. A new computational method called nonlinear approximation (NLA) is introduced in this work. The Flynn-Wall-Ozawa (FWO), Tang, Kissinger-Akahira- Sunose (KAS), and NLA methods were used to calculate the apparent activation energy (Ea). The results show that the NLA method is ideal for Ea calculations because of its simpler and more appropriate analysis process. It does, however, give slightly higher average relative errors for Ea compared to the other typical model-free methods. Calculations using the solid-state reaction model-fitting method indicated that the thermal decomposition process was composed of multiple mechanisms. For the whole decomposition process, the values of Ea were between 70 and 135 kJ·mol^-1, and the pre-exponential factor (A) varied from5.24×10⁴ to 9.89×10⁷ min^-1. The differences in Ea also explain the differences in decomposition temperature between poly(propylene carbonate) (PPC) and PPCMA.
- Polycarbonate,
- Carbon dioxide,
- Thermal decomposition kinetics
1. [1]
  
  1. Santer, B. D.; Taylor, K. E.;Wigley, T. M. L.; Johns, T. C.; Jones, P. D.; Karoly, D. J.; Mitchell, J. F. B.; Oort, A. H.; Penner, J. E.; Ramaswamy, V.; Schwarzkopf, M. D. Nature, 1996, 382: 39
2. [2]
  2. Meehl, G. A.; Washington,W. M. Nature, 1996, 382: 56
3. [3]
  3. Broecker,W. S. Science, 1997, 278: 1582
4. [4]
  4. Kacholia, K.; Reck, R. A. Climatic Change, 1997, 35: 53
5. [5]
  5. Beckman, E. J. Science, 1999, 283: 946
6. [6]
  6. Inoue, S.; Koinuma, H.; Tsuruta, T. J. Polym. Sci. Polym. Lett., 1969, 7: 287
7. [7]
  7. Darensbourg, D. J.; Mattew, W. H. Macromolecules, 1995, 28: 7577
8. [8]
  8. Zhang, N. Y.; Chen, L. B.; Yang, S. Y.; Yu, A. F.; He, S. J. Acta Polym. Sin., 2000: 741
9. [9]
  9. Plesse, C.; Vidal, F.; Randriamahazaka, H.; Teyssi佴, D.; Chevrot, C. Polymer, 2005, 46: 7771
10. [10]
  10. Jiang, G. H.; Wang, L.; Yu, H. J.; Dong, X. C.; Chen, C. Polymer, 2006, 47: 12
11. [11]
  11. Jiang, G. H.; Wang, L.; Chen, T.; Yu, H. J.; Dong, X. C.; Chen, C. Polymer, 2005, 46: 9501
12. [12]
  12. Lu, L. B.; Huang, K. L. J. Polym. Sci. Pol. Chem., 2005, 43: 2468
13. [13]
  13. Liu, Y. F.; Huang, K. L.; Peng, D. M.; Wu, H. Polymer, 2006, 47: 8453
14. [14]
  14. Flynn, J. H.;Wall, L. A. J. Res. Nat. Bur. Stand. Sect. A, 1966, 70: 487
15. [15]
  15. Ozawa, T. B. Chem. Soc. Jpn., 1965, 38: 1881
16. [16]
  16. Kissinger, H. E. Anal. Chem., 1957, 29: 1702
17. [17]
  17. Akahira, T.; Sunose, T. Res. Rep. Chiba. Inst. Technol., 1971, 16: 22
18. [18]
  18. Tang, W. J.; Liu, Y. W.; Zhang, H.;Wang, C. X. Thermochim. Acta, 2003, 408: 39
19. [19]
  19. Tang, W. J.; Chen, D. H.; Wang, C. X. AICHE J., 2006, 52: 2211
20. [20]
  20. Quan, Z.; Min, J.; Zhou, Q.; Xie, D.; Liu, J.; Wang, S.; Zhao, X.; Wang, F. Macromol. Symp., 2003, 195: 281
21. [21]
  21. Vyazovkin, S. J. Comput. Chem., 2001, 22: 178
22. [22]
  22. Senum, G. I.; Yang, R. T. J. Therm. Anal. Calorim., 1977, 11: 445
23. [23]
  23. Vyazovkin, S. Thermochim. Acta, 2000, 355: 155
24. [24]
  24. Opfermann, J. R.; Hammersheim, H. J. Thermochim. Acta, 2003, 397: 1
25. [25]
  25. Sahin, O.; Tas, E.; Dolas, H. J. Therm. Anal. Calorim., 2007, 89: 123
26. [26]
  26. Liu, B. Y.; Zhao, X. J.; Wang, X. H.;Wang, F. S. J. Appl. Polym. Sci., 2003, 90: 947
27. [27]
  27. Vyazovkin, S.; Sbirrazzuoli, N. Macromol. Rapid. Commun., 2006, 27: 1515
28. [28]
  28. Coats, A. W.; Redfern, J. P. J. Polym. Sci. Polym. Lett., 1965, 3: 917
29. [29]
  29. Coats, A. W.; Redfern, J. P. Nature, 1964, 201: 68
30. [30]
  30. Jankovic', B.; Adnad-evic', B.; Jovanovic', J. Thermochim. Acta, 2007, 452: 106
1. [1]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
2. [2]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
3. [3]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
4. [4]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
5. [5]
  Hailian Cheng , Shuaiqiang Jia , Chunjun Chen , Haihong Wu , Buxing Han . Electrocatalytic CO₂ Conversion: A Key to Unlocking a Low-Carbon Future. University Chemistry, 2026, 41(2): 1-13. doi: 10.12461/PKU.DXHX202502023
6. [6]
  Jiayin Hu , Yafei Guo , Long Li , Tianlong Deng . Teaching Innovation of Salt-Water System Phase Diagrams under the “Dual Carbon” Background: Introducing the Pressurized CO₂ Carbonization Phase Equilibria. University Chemistry, 2025, 40(11): 31-36. doi: 10.12461/PKU.DXHX202412031
7. [7]
  Zixuan Zhao , Miao Fan . “Carbon” with No “Ester”: A Boundless Journey of CO₂ Transformation. University Chemistry, 2025, 40(7): 213-217. doi: 10.12461/PKU.DXHX202409040
8. [8]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . 非均相催化CO₂与烃类协同催化转化的最新进展. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-0. doi: 10.1016/j.actphy.2025.100073
9. [9]
  Xiaomin Kang , Chuanbao Jiao . Application of Metal-Organic Frameworks in CO₂ Catalytic Conversion: Promoting “Double Carbon” Actions for a Beautiful China. University Chemistry, 2026, 41(2): 208-217. doi: 10.12461/PKU.DXHX202503011
10. [10]
  Chen Lin , Huanjun Xu . ‘Thank-You Letter’ from CO₂: Development of Technology Has Changed My Image. University Chemistry, 2026, 41(2): 238-241. doi: 10.12461/PKU.DXHX202502048
11. [11]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
12. [12]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006
13. [13]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
14. [14]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
15. [15]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
16. [16]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
17. [17]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
18. [18]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
19. [19]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
20. [20]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213

Get Citation

PDF

XML

Metrics

PDF Downloads(1360)
Abstract views(3965)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142