Citation: LONG Jun-Ying, MA Lan, HE De-Hua. 1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2719-2725. doi: 10.3866/PKU.WHXB20101022 shu

1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts

LONG Jun-Ying ¹ ,
MA Lan ^1,2 ,
HE De-Hua ^1,

1.
1. Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
2. Institute of Chemical Defence, Beijing 102205, P. R. China

Received Date: 26 April 2010
Available Online: 27 September 2010
Fund Project: 国家自然科学基金(20921001)资助项目 (20921001)

Co-B catalysts supported on ZrO₂ (prepared by alcogel nitrogen thermo-treatment method), carbon nanotubes (CNTs), and mesoporous SBA-15 as supports were prepared by chemical reduction method and characterized by X-ray diffraction (XRD), nitrogen physisorption, transmission electron microscopy (TEM), inductively coupled plasma -atomic emission spectrometry (ICP-AES) and X-ray photoelectron spectroscopy (XPS). Hydroformylation of 1-octene was used as a probe reaction to investigate the catalytic performance and stability of the catalysts in recycles. The as-prepared Co-B catalysts showed amorphous characteristics and the support structures were unchanged. The reaction results reveal that the catalytic activities of Co-B/CNTs, Co-B/ZrO₂ and Co-B/SBA-15 in the hydroformylation of 1-octene were comparatively high. However, the catalytic activities decreased upon recycling. Nevertheless, the Co-B/ CNTs and Co-B/SBA-15 were relatively stable compared with Co-B/ZrO₂.
- Amorphous Co-B catalyst,
- Support,
- Hydroformylation,
- Catalytic property
1. [1]
  
  1. Cornils, B.; Rasch, M.; Otto, R. Angew. Chem. Int. Edit., 1994, 33: 2144
2. [2]
  2. Chapuis, C.; Jacoby, D. Appl. Catal. A, 2001, 221: 93
3. [3]
  3. Botteghi, C.; Paganelli, S.; Moratti, F. J. Mol. Catal. A-Chem., 2003, 200: 147
4. [4]
  4. Russell, M. J. H. PlatinumMet. Rev., 1988, 32(4): 179
5. [5]
  5. Ungvary, F. C. Chem. Rev., 1997, 167: 233
6. [6]
  6. Klingler, R. J.; Chen, M. J.; Rathke, J. W.; Kramarz, K. W. Organometallics, 2007, 26(2): 352
7. [7]
  7. Dieguez, M.; Pamies, O.; Claver, C. Tetrahedron: Asymmetry, 2004, 15(14): 2113
8. [8]
  8. Lin, Q.; Jiang, W. D.; Fu, H. Y.; Chen, H.; Li, X. J. Appl. Catal. A, 2007, 328(1): 83
9. [9]
  9. Fu, H. Y.; Li, M.; Chen, H.; Ji, X. J. Mol. Catal. A-Chem., 2006, 259(1-2): 156
10. [10]
  10. Zhou,W.; He, D. H. Green Chem., 2009, 11: 1146
11. [11]
  11. Zhou,W.; He, D. H. Catal. Lett., 2009, 127: 437
12. [12]
  12. Fierro, J. L. G.; Merchan, M. D.; Rojas, S.; Terreros, P. J. Mol. Catal. A-Chem., 2001, 166(2): 255
13. [13]
  13. Kainulainen, T. A.; Nieme, M. K.; Krause, A. O. I. J. Mol. Catal. A-Chem., 1997, 122: 39
14. [14]
  14. Kainulainen, T. A.; Niemela, M. K.; Krause, A. O. I. J. Mol. Catal. A-Chem., 1999, 140: 173
15. [15]
  15. Zhang, H.; Qiu, J.; Liang, C.; Li, Z.; Wang, X.; Wang, Y.; Feng, Z.; Lin, C. Catal. Lett., 2005, 101: 211
16. [16]
  16. Wang, M. H.; Li, H. X.; Deng, J. F. Chin. J. Catal., 1999, 20: 548 [王明辉,李和兴, 邓景发. 催化学报, 1999, 20: 548]
17. [17]
  17. Li, H.; Xu, Y.; Yang, H. X.; Zhang, F.; Li, H. X. J. Mol. Catal. A- Chem., 2009, 307: 105
18. [18]
  18. Li, H.; Zhao, Q. F.; Li, H. X. J. Mol. Catal. A-Chem., 2008, 285: 29
19. [19]
  19. Lü, Z. G.; Guo, Z. M. Chem. Ind. Eng. Prog., 1998, 21(8): 552 [吕志果,郭振美. 化工进展, 1998, 21(8): 552]
20. [20]
  20. Nitta, Y.; Imanaka, T.; Teranishi, S. Bull. Chem. Soc. Jpn., 1980, 53: 3154
21. [21]
  21. Chen, Y. Z.;Wu, K. J. Appl. Catal., 1991, 78: 185
22. [22]
  22. Pei, Y.; Guo, P. J.; Qiao, M. H.; Li, H. X.; Wei, S. Q.; He, H. Y.; Fan, K. N. J. Catal., 2007, 248: 303
23. [23]
  23. Ma, L.; Peng, Q. R.; He, D. H. Catal. Lett., 2009, 130: 137
24. [24]
  24. Li, H. X.; Wang, W. J.; Li, H.; Deng, J. F. J. Catal., 2000, 194: 211
25. [25]
  25. Chen, X. Y.; Wang, S.; Zhuang, J. H.; Qiao, M. H.; Fan, K. N.; He, H. Y. J. Catal., 2004, 227: 419
26. [26]
  26. Zhang, Q.; Zhao, M. Q.; Liu, Y.; Cao, A. Y.; Qian, W. Z.; Lu, Y. F.;Wei, F. Chinese Science Bulletin, 2009, 54: 1794 [张强, 赵梦强,刘毅, 曹安源,骞伟中,卢云峰,魏飞. 科学通报, 2009, 54: 1794]
27. [27]
  27. Xu, B. Q.; Wei, J. M.; Yu, Y. J. Phys. Chem. B, 2003, 107: 5203
28. [28]
  28. Zhao, D. Y.; Feng, J. L.; Huo, Q. S.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science, 1998, 279: 548
29. [29]
  29. Ocampo, A. L.; Miranda, H. M.; Morgado, J.; Montoya, J. A.; Sebastian, P. J. J. Power Sources, 2006, 160(2): 915
30. [30]
  30. Wang, Y.; Noguchi, M.; Takahashi, Y.; Ohtsuka, Y. Catal. Today, 2001, 68: 3
31. [31]
  31. Wonterghem, J. V.; Morup, S. C.; Koch, J. W.; Charles, S.W.; Wells, S. Nature, 1986, 322: 622
32. [32]
  32. Dillon, A. C.; Jones, K. M.; Bekkedahl, T. A. Nature, 1997, 386: 377
33. [33]
  33. Manuela, V.; Fabrizio, C. Chem. Phys. Lett., 2003, 371: 476
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
7. [7]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
8. [8]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
9. [9]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
12. [12]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
13. [13]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
14. [14]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
15. [15]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
17. [17]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
18. [18]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
19. [19]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
20. [20]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

Get Citation

PDF

XML

Metrics

PDF Downloads(1050)
Abstract views(2520)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142