Citation: ZHOU Yan-Li, ZHI Jin-Fang, ZHANG Xiang-Fei, XU Mao-Tian. Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2405-2409. doi: 10.3866/PKU.WHXB20100841 shu

Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials

1.
1. Department of Chemistry, Shangqiu Normal University, Shangqiu 476000, Henan Province, P. R. China;
2. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 18 April 2010
Available Online: 2 July 2010
Fund Project: 国家自然科学基金(20775047) (20775047)河南省科技厅国际合作项目基金(084300510075) (084300510075)商丘师范学院青年基金(009QN08)资助 (009QN08)

The electrochemical properties of three carbon-based electrodes including boron-doped nanocrystalline diamond (BDND), boron-doped microcrystalline diamond (BDMD), and glassy carbon (GC) were compared. We used scanning electron microscopy to characterize the two diamond electrodes and the grain sizes of the BDMD and BDND films were 1-5 μm and 20-100 nm, respectively. The phase composition was characterized by Raman spectroscopy and high-quality BDMD and BDND films were formed by hot-filament chemical vapor deposition. Cyclic votammograms for 0.5 mol·L^-1 H₂SO₄ showed that the potential windows for the BDND and BDMD electrodes were 3.3 and 3.0 V, respectively. The potential windows were much wider than that of the GC electrode (2.5 V). The cyclic voltammograms and Nyquist plots of the impedance measurements for [Fe(CN)₆]³-/[Fe(CN)₆]⁴- show peak to peak separations (ΔE_p) of 73, 92, and 112 mV and electron transfer resistances (R_et) of (98依5), (260依19), and (400依25) Ωfor the BDND, BDMD, and GC electrodes, respectively. We also investigated the oxidation of 0.1 mmol·L-1 bisphenol A (BPA) on the three carbon-based electrodes. The above-mentioned electrochemical results reveal that the two diamond electrodes have wider potential windows, better reversibility, faster electron transfer, and higher stability than the GC electrode. Additionally, the BDND electrode shows better electrochemical properties than the BDMD electrode.
- Electrochemical property,
- Boron-doped nanocrystalline diamond,
- Boron-doped microcrystalline diamond,
- Glassy carbon,
- Electrode
1. [1]
  
  1. McCreery, R. L. Chem. Rev., 2008, 108: 2646
2. [2]
  2. Wang, Y. R.; Hu, P.; Liang, Q. L.; Luo, G. A.; Wang, Y. M. Chin. J. Anal. Chem., 2008, 36: 1011 [王月荣,胡坪, 梁琼麟, 罗国安,王义明. 分析化学, 2008, 36: 1011]
3. [3]
  3. Chen, P. H.; Fryling, M. A.; McCreery, R. L. Anal. Chem., 1995, 67: 3115
4. [4]
  4. Wang, J.; Musameh, M.; Mo, J. W. Anal. Chem., 2006, 78: 7044
5. [5]
  5. Hermans, A.; Seipel, A. T.; Miller, C. E.; Wightman, R. M. Langmuir, 2006, 22: 1964
6. [6]
  6. L俟, Y. F.; Yin, Y. J.; Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin., 2007, 23: 5 [吕亚芬, 印亚静,吴萍,蔡称心.物理化学学报, 2007, 23: 5]
7. [7]
  7. Zhang, B.; Adams, K. L.; Luber, S. J.; Eves, D. J.; Heien, M.; Ewing, A. G. Anal. Chem., 2008, 80: 1394
8. [8]
  8. Zhi, J. F.; Tian, R. H. Prog. Chem., 2005, 17: 55 [只金芳, 田如海.化学进展, 2005, 17: 55]
9. [9]
  9. Granger, M. C.; Witek, M.; Xu, J.;Wang, J.; Hupert, M.; Hanks, A.; Koppang, M. D.; Butler, J. E.; Lucazeau, G.; Mermoux, M.; Strojek, J. W.; Swain, G. M. Anal. Chem., 2000, 72: 3793
10. [10]
  10. Tatsuma, T.; Mori, H.; Fujishima, A. Anal. Chem., 2000, 72: 2919
11. [11]
  11. Compton, R. G.; Foord, J. S.; Marken, F. Electroanalysis, 2003, 15: 1349
12. [12]
  12. Swain, G. M.; Ramesham, R. Anal. Chem., 1993, 65: 345
13. [13]
  13. Zhou, Y. L.; Zhi, J. F.; Zou, Y. S.; Zhang,W. J.; Lee, S. T. Anal. Chem., 2008, 80: 4141
14. [14]
  14. Wilson, N. R.; Clewes, S. L.; Newton, M. E.; Unwin, P. R.; MacPherson, J. V. J. Phys. Chem. B, 2006, 110: 5639
15. [15]
  15. Barnard, A. S.; Sternberg, M. J. Phys. Chem. B, 2006, 110: 19307
16. [16]
  16. Zhang, Y.; Yoshihara, S.; Shirakashi, T.; Kyomen, T. Diamond Relat. Mater., 2005, 14: 213
17. [17]
  17. Fischer, A. E.; Show, Y.; Swain, G. M. Anal. Chem., 2004, 76: 2553
18. [18]
  18. Duo, I.; Fujishima, A.; Comninellis, C. Electrochem. Commun., 2003, 5: 695
19. [19]
  19. Bennett, J. A.;Wang, J.; Show, Y.; Swain, G. M. J. Electrochem. Soc., 2004, 151: E306
20. [20]
  20. Show, Y.; Witek, M. A.; Sonthalia, P.; Swain, G. M. Chem. Mater., 2003, 15: 879
21. [21]
  21. Prawer, S.; Nugent, K. W.; Jamieson, D. N.; Orwa, J. O.; Bursill, L. A.; Peng, J. L. Chem. Phys. Lett., 2000, 332: 93
22. [22]
  22. Chen, Q.; Gruen, D. M.; Krauss, A. R.; Corrigan, T. D.;Witek, M.; Swain, G. M. J. Electrochem. Soc., 2001, 148: E44
23. [23]
  23. Niwa, O.; Jia, J.; Sato, Y.; Kato, D.; Kurita, R.; Maruyama, K.; Suzuki, K.; Hirono, S. J. Am. Chem. Soc., 2006, 128: 7144
24. [24]
  24. Jia, J.; Kato, D.; Kurita, R.; Sato, Y.; Maruyama, K.; Suzuki, K.; Hirono, S.; Ando, T.; Niwa, O. Anal. Chem., 2007, 79: 98
25. [25]
  25. Yin, H.; Zhou, Y.; Ai, S. J. Electroanal. Chem., 2009, 626: 80
26. [26]
  26. D'Antuono, A.; Dall'Orto, V. C.; Lo Balbo, A.; Sobral, S.; Rezzano, I. J. Agric. Food Chem., 2001, 49: 1098
1. [1]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
4. [4]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
5. [5]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
6. [6]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
9. [9]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
10. [10]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
11. [11]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
14. [14]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
15. [15]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
16. [16]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
17. [17]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
18. [18]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
19. [19]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
20. [20]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

Get Citation

PDF

XML

Metrics

PDF Downloads(1384)
Abstract views(3195)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142