Citation: LIU Shu-Ping, YUE Ming-Bo, WANG Yi-Meng. One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2224-2228. doi: 10.3866/PKU.WHXB20100806 shu

One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062, P. R. China

Received Date: 7 January 2010
Available Online: 9 June 2010
Fund Project: 国家自然科学基金(20873042, 20890122)资助项目 (20873042, 20890122)

The addition of sodium phosphate monobasic (NaH₂PO₄) to a synthetic mixture allows a one-step synthesis of mesoporous Beta zeolite. Aggregation of the nanosized Beta zeolites allows the filtration difficulties to be overcome while the intercrystalline mesopores reduce the diffusion limitation and thus enhance the catalytic activity. The obtained Beta zeolite samples were characterized by X-ray diffraction, scanning electron microscopy, N₂ adsorption-desorption, and temperature-programmed desorption of ammonia. The amount of phosphate strongly influenced the mesopore volume of the Beta zeolites. When the molar ratio of NaH₂PO₄/SiO₂ was 0.1, the sample had od textural and acidic properties and exhibited the best catalytic activity for the alkylation of phenol with tert-butanol.
- Hydrothermal synthesis,
- Beta zeolite,
- Mesoporous,
- Alkylation,
- Phosphate
1. [1]
  
  [1]. Corma, A.; mez, V.; Martinez, A. Appl. Catal. A, 1994, 119: 83
2. [2]
  [2]. Yang, B. L.; Lu, S. Q.; Wu, J.; Wang, H. J. Chin. J. Catal., 2007, 28(1):73. [杨伯伦, 路士庆, 吴江, 王华军. 催化学报, 2007, 28(1): 73]
3. [3]
  [3]. Li, Q.; Dou, T.; Huo, Q.; Xu, Q. H.; ng, Y. J.; Pan, H. F. Acta Phys. -Chim. Sin., 2008, 24:1192. [李强, 窦涛, 霍全, 徐庆虎, 巩雁军, 潘惠芳. 物理化学学报, 2008, 24: 1192]
4. [4]
  [4]. van der Pol, A. J. H. P.; Verduyn, A. J.; van Hooff, J. H. C. Appl. Catal. A, 1992, 92: 113
5. [5]
  [5]. Shiralkar, V. P.; Joshi, P. N.; Eapen, M. J.; Rao, B. S. Zeolites, 1991, 11: 511
6. [6]
  [6]. Yamamura, M.; Chaki, K.; Wakatsuki, T.; Okado, H. Zeolites, 1994, 14: 643
7. [7]
  [7]. Valtchev, V. Chem. Mater., 2002, 14: 956
8. [8]
  [8]. Naydenov, V.; Tosheva, L.; Sterte, J. Chem. Mater., 2002, 14: 4881
9. [9]
  [9]. Rhodes, K. H.; Davis, S. A.; Caruso, F.; Zhang, B.; Mann, S. Chem. Mater., 2000, 12: 2832
10. [10]
  [10]. Dong, A.; Wang, Y.; Tang, Y.; Zhang, Y.; Ren, N.; Gao, Z. Adv. Mater., 2002, 14: 1506
11. [11]
  [11]. Wang, Y.; Caruso, F. Adv. Funct. Mater., 2004, 14: 1012
12. [12]
  [12]. Wang, X. D.; Yang, W. L.; Tang, Y.; Wang, Y. J.; Fu, S. K.; Gao, Z. Chem. Commun., 2000: 2161
13. [13]
  [13]. Tao, Y. S.; Kanoh, H.; Abrams, L.; Kaneko, K. Chem. Rev., 2006, 106: 896
14. [14]
  [14]. Perez-Ramirez, J.; Christensen, C. H.; Egeblad, K.; Christensen, C. H.; Groene, J. C. Chem. Soc. Rev., 2008, 37: 2530
15. [15]
  [15]. Egeblad, K.; Christensen, C. H.; Kustova, M.; Christensen, C. H. Chem. Mater., 2008, 20: 946
16. [16]
  [16]. Groen, J. C.; Abello, S.; Villaescusa, L. A.; Perez-Ramirez, J. Microporous Mesoporous Mat., 2008, 114: 93
17. [17]
  [17]. Majano, G.; Mintova, S.; Ovsitser, O.; Mihailova, B.; Bein, T. Microporous Mesoporous Mat., 2005, 80: 227
18. [18]
  [18]. Aguado, J.; Serrano, D. P.; Rodriguez, J. M. Microporous Mesoporous Mat., 2008, 115: 504
19. [19]
  [19]. Kuechl, D. E.; Benin, A. I.; Knight, L. M.; Abrevaya, H.; Wilson, S. T.; Sinkler, W.; Mezza, T. M.; Willis, R. R. Microporous Mesoporous Mat., 2010, 127: 104
20. [20]
  [20]. Choi, M.; Na, K.; Ryoo, R. Chem. Commun., 2009: 2845
21. [21]
  [21]. Na, K.; Choi, M.; Ryoo, R. J. Mater. Chem., 2009, 19: 6713
22. [22]
  [22]. Zhu, G.; Qiu, S.; Gao, F.; Li, D.; Li, Y. F.; Wang, R. W.; Gao, B.; Li, B. S.; Guo, Y. H.; Xu, R. R.; Liu, Z.; Terasaki, O. J. Mater. Chem., 2001, 11: 1687
23. [23]
  [23]. Kang, Y.; Shan, W.; Wu, J.; Zhang, Y.; Wang, X.; Yang, W.; Tang, Y. Chem. Mater., 2006, 18: 1861
24. [24]
  [24]. Song, J. W.; Ren, L. M.; Yin, C. Y.; Ji, Y. Y.; Wu, Z. F.; Li, J. X.; Xiao, F. S. J. Phys. Chem. C, 2008, 112: 8609
25. [25]
  [25]. Zhu, H.; Liu, Z.; Kong, D.; Wang, Y.; Xie, Z. J. J. Phys. Chem. C, 2008, 112: 17257
26. [26]
  [26]. Chen, R.; ng, Y. J.; Li, Q.; Dou, T.; Zhao, Z.; Xu, Q. H. Acta Phys. -Chim. Sin., 2009, 25(3):539. [陈然, 巩雁军, 李强, 窦涛, 赵震, 徐庆虎. 物理化学学报, 2009, 25(3): 539]
27. [27]
  [27]. Kumar, R.; Bhaumik, A.; Ganaphthy, S. Nature, 1996, 381: 298
28. [28]
  [28]. Kumar, R.; Mukhrjee, P.; Pandey, R. K.; Rajmohanan, P.; Bhaumik, A. Microporous Mesoporous Mat., 1998, 22: 23
29. [29]
  [29]. Fang, Y.; Hu, H.; Chen, G. Chem. Mater., 2008, 20: 1670
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