Citation: YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying. Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2087-2095. doi: 10.3866/PKU.WHXB20100639
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The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our work. The mechanisms are interpreted based on the analysis of calcium carbonate crystallization in the presence of biomacromolecules, synthetic polymers, or mixtures of the polymer and surfactants. This paper provides not only the methods for the crystallization of calcium carbonate consisting of different resultant morphologies, polymorphs, and sizes, but also a theoretical guide for industrial production.
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Keywords:
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Water soluble polymer
, - Calcium carbonate,
- Crystallization,
- Polymorph,
- Morphology
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[1]
[1] Stupp, S. I.; Braun, P. V. Science, 1997, 277: 1242
-
[2]
[2] Naka, K.; Chujo, Y. Chem. Mater., 2001, 13: 3245
-
[3]
[3] Cõlfen, H. Curr. Opin. Colloid Interface Sci., 2003, 8: 23
-
[4]
[4] Politi, Y.; Arad, T.; Klein, E.; Weiner, S.; Addadi, L. Science, 2004, 306: 1161
-
[5]
[5] Xu, A. W.; Ma, Y.; Cõlfen, H. J. Mater. Chem., 2007, 17: 415
-
[6]
[6] Porter, S. M. Science, 2007, 316: 1302
-
[7]
[7] Stanley, S. M. Chem. Rev., 2008, 108: 4483
-
[8]
[8] Wang, L.; Nancollas, G. H. Chem. Rev., 2008, 108: 4628
-
[9]
[9] Ouyang, J. M. The modulation and application of matrix in biomimetic mineralization. Beijing: Chemical Industry Press, 2006: 1-45 [欧阳健明. 生物矿化的基质调控及其仿生应用. 北京: 化学工业出版社, 2006: 1-45]
-
[10]
[10] Mount, A. S.; Wheeler, A. P.; Paradkar, R. P.; Snider, D. Science, 2004, 304: 297
-
[11]
[11] Sugawara, A.; Kato, T. Chem. Commun., 2000: 487
-
[12]
[12] Cheng, B.; Lei, M.; Yu, J.; Zhao, X. Mater. Lett., 2004, 58: 1565
-
[13]
[13] Cui, F. Z. Biomineralization. Beijing. Tsinghua University Press, 2007: 90-156 [崔福斋. 生物矿化. 北京: 清华大学出版社, 2007: 90-156]
-
[14]
[14] Lochhead, M. J.; Letellier, S. R.; Vogel, V. J. Phys. Chem. B, 1997, 101: 10821
-
[15]
[15] Wei, H. Controlled mineralization of calcium carbonate by organic additives [D]. Beijing: Institute of Chemistry, Chinese Academy of Sciences, 2005 [魏 浩. 有机质对碳酸钙矿化过程机理研究 [D]. 北京: 中国科学院化学研究所, 2005]
-
[16]
[16] Wolf, S. E.; Loges, N.; Mathiasch, B.; Panth?觟fer, M.; Mey, I.; Janshoff, A.; Tremel, W. Angew. Chem. Int. Edit., 2007, 46: 5618
-
[17]
[17] Heuer, A.; Fink, D.; Laraia, V.; Arias, J.; Calvert, P.; Kendall, K.; Messing, G.; Blackwell, J.; Rieke, P.; Thompson, D. Science, 1992, 255: 1098
-
[18]
[18] Mann, S. J. Mater. Chem., 1995, 5: 935
-
[19]
[19] Mann, S.; Heywood, B. R.; Rajam, S.; Birchall, J. D. Nature, 1988, 334: 692
-
[20]
[20] Arias, J. L.; Fernàndez, M. S. Chem. Rev., 2008, 108: 4475
-
[21]
[21] Evans, J. S. Chem. Rev., 2008, 108: 4455
-
[22]
[22] Dickerson, M. B.; Sandhage, K. H.; Naik, R. R. Chem. Rev., 2008, 108: 4935
-
[23]
[23] Cusack, M.; Freer, A. Chem. Rev., 2008, 108: 4433
-
[24]
[24] Sommerdijk, N. A. J. M.; With, G. D. Chem. Rev., 2008, 108: 4499
-
[25]
[25] Cai, G. B.; Wan, Y.; Yu, S. H. Chin. J. Inorg. Chem., 2008, 24: 673 [蔡国斌, 万 勇, 俞书宏. 无机化学学报, 2008, 24: 673]
-
[26]
[26] Sun, Z. Y.; Huang, J. B. Acta Phys. -Chim. Sin., 2006, 22: 172 [孙振亚, 黄江波. 物理化学学报, 2006, 22: 172]
-
[27]
[27] Gómez-Morales, J.; Hernández-Hernández, A.; Sazaki, G.; García- Ruiz, J. M. Cryst. Growth Des., 2010, 10: 963
-
[28]
[28] Tohse, H.; Saruwatari, K.; Kogure, T.; Nagasawa, H.; Takagi, Y. Cryst. Growth Des., 2009, 9: 4897
-
[29]
[29] Yao, Y.; Dong, W.; Zhu, S.; Yu, X.; Yan, D. Langmuir, 2009, 25: 13238
-
[30]
[30] Politi, Y.; Batchelor, D. R.; Zaslansky, P.; Chmelka, B. F.; Weaver, J. C.; Sagi, I.; Weiner, S.; Addadi, L. Chem. Mater., 2010, 22: 161
-
[31]
[31] You, C.; Zhang, Q.; Jiao, Q.; Fu, Z. Cryst. Growth Des., 2009, 9: 4720
-
[32]
[32] Yamanaka, S.; Ito, N.; Shimosaka, A.; Shirakawa, Y.; Hidaka, J. Cryst. Growth Des., 2009, 9: 3245
-
[33]
[33] Hou, W.; Feng, Q. J. Cryst. Growth, 2005, 282: 214
-
[34]
[34] Zhang, Z.; Gao, D.; Zhao, H.; Xie, C.; Guan, G.; Wang, D.; Yu, S. H. J. Phys. Chem. B, 2006, 110: 8613
-
[35]
[35] Orme, C. A.; Noy, A.; Wierzbicki, A.; McBride, M. T.; Grantham, M.; Teng, H. H.; Dove, P. M.; DeYoreo, J. J. Nature, 2001, 411: 775
-
[36]
[36] Mao, Z.; Huang, J. J. Solid State Chem., 2007, 180: 453
-
[37]
[37] Maas, M.; Rehage, H.; Nebel, H.; Epple, M. Colloid. Polym. Sci., 2007, 285: 1301
-
[38]
[38] Loste, E.; Wilson, R. M.; Seshadri, R.; Meldrum, F. C. J. Cryst. Growth, 2003, 254: 206
-
[39]
[39] Zhu, L.; Zhao, Q.; Zheng, X.; Xie, Y. J. Solid State Chem., 2006, 179: 1247
-
[40]
[40] Katsifaras, A.; Spanos, N. J. Gryst. Growth, 1999, 204: 183
-
[41]
[41] Ajikumar, P. K.; Wong, L. G.; Subramanyam, G.; Lakshminarayanan, R.; Valiyaveettil, S. Cryst. Growth Des., 2005, 5: 1129
-
[42]
[42] Nishino, Y.; Oaki, Y.; Imai, H. Cryst. Growth Des., 2009, 9: 223
-
[43]
[43] Vavouraki, A. I.; Putnis, C. V.; Putnis, A.; Koutsoukos, P. G. Chem. Geol., 2008, 253: 243
-
[44]
[44] Nebel, H.; Epple, M. Z. Anorg. Allg. Chem., 2008, 634: 1439
-
[45]
[45] Yan, R. X. Water-soluble macromolecules. Beijing: Chemical Industry Press, 1998: 1-41 [严瑞. 水溶性大分子. 北京: 化学工业出版社, 1998: 1-41]
-
[46]
[46] Yang, X.; Xu, G.; Chen, Y.; Wang, F.; Mao, H.; Sui, W.; Bai, Y.; ng, H. J. Cryst. Growth, 2009, 311: 4558
-
[47]
[47] Huang, Y.; Shen, Q.; Sui, W.; Guo, M.; Zhao, Y.; Wang, D.; Xu, D. Colloid. Polym. Sci., 2007, 285: 641
-
[48]
[48] Liang, P.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wei, H.; Lieberwirth, I.; Huang, Y.; Wang, D.; Xu, D. Langmuir, 2004, 20: 10444
-
[49]
[49] Li, X.; Shen, Q.; Su, Y.; Tian, F.; Zhao, Y.; Wang, D. Cryst. Growth Des., 2009, 9: 3470
-
[50]
[50] Liang, P.; Zhao, Y.; Shen, Q.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 261: 571
-
[51]
[51] Wei, H.; Shen, Q.; Wang, H.; Gao, Y.; Zhao, Y.; Xu, D.; Wang, D. J. Cryst. Growth, 2007, 303: 537
-
[52]
[52] Shen, Q.; Wei, H.; Zhao, Y.; Wang, D. J.; Zheng, L. Q.; Xu, D. F. Colloid. Surf. A, 2004, 251: 87
-
[53]
[53] Wei, H.; Shen, Q.; Zhao, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 260: 545
-
[54]
[54] Shen, Q.; Wei, H.; Wang, L.; Zhou, Y.; Zhao, Y.; Zhang, Z.; Wang, D.; Xu, G.; Xu, D. J. Phys. Chem. B, 2005, 109: 18342
-
[55]
[55] Kontrec, J.; Kralj, D.; Brecevic, L.; Falini, G. J. Cryst. Growth, 2008, 310: 4554
-
[56]
[56] Matahwa, H.; Ramiah, V.; Sanderson, R. D. J. Cryst. Growth, 2008, 310: 4561
-
[57]
[57] wer, L. B.; Odom, D. J. J. Cryst. Growth, 2000, 210: 719
-
[58]
[58] Hernández-Hernández, A.; Vidal, M. L.; Gómez-Morales, J.; Rodríguez-Navarro, A. B.; Labas, V.; Gautron, J.; Nys, Y.; Ruíz, J. M. G. J. Cryst. Growth, 2008, 310: 1754
-
[59]
[59] Díaz-Dosque, M.; Aranda, P.; Darder, M.; Retuert, J.; Yazdani- Pedram, M.; Arias, J. L.; Ruiz-Hitzky, E. J. Cryst. Growth, 2008, 310: 5331
-
[60]
[60] Sondi, I.; Skapin, S. D.; Salopek-Sondi, B. Cryst. Growth Des., 2008, 8: 435
-
[61]
[61] Liu, X.; Zhang, L.; Wang, Y.; Guo, C.; Wang, E. Cryst. Growth Des., 2008, 8: 759
-
[62]
[62] Qi, L.; Li, J.; Ma, J. Adv. Mater., 2002, 14: 300
-
[63]
[63] Colfen, H.; Qi, L. Chem. Eur. J., 2001, 7: 106
-
[64]
[64] Gao, Y. X.; Yu, S. H.; Guo, X. H. Langmuir, 2006, 22: 6125
-
[65]
[65] Gao, Y. X.; Yu, S. H.; Cong, H.; Jiang, J.; Xu, A. W.; Dong, W. F.; Colfen, H. J. Phys. Chem. B, 2006, 110: 6432
-
[66]
[66] Hernández-Hernández, A.; Rodríguez-Navarro, A. B.; Gómez- Morales, J.; Jiménez-Lopez, C.; Nys, Y.; García-Ruiz, J. M. Cryst. Growth Des., 2008, 8: 1495
-
[67]
[67] Voinescu, A. E.; Touraud, D.; Lecker, A.; Pfitzner, A.; Kunz, W.; Ninham, B. W. Langmuir, 2007, 23: 12269
-
[68]
[68] Lee, S. W.; Choi, C. S. Cryst. Growth Des., 2007, 7: 1463
-
[69]
[69] Wang, X.; Sun, H.; Xia, Y.; Chen, C.; Xu, H.; Shan, H.; Lu, J. R. J. Colloid Interface Sci., 2009, 332: 96
-
[70]
[70] Roqu, J.; Molera, J.; Vendrell-Saz, M.; Salvad, N. J. Cryst. Growth, 2004, 262: 543
-
[71]
[71] Shen, F. H.; Feng, Q. L.; Wang, C. M. J. Cryst. Growth, 2002, 242: 239
-
[72]
[72] Xiang, J.; Cao, H.; Warner, J. H.; Watt, A. A. R. Cryst. Growth Des., 2008, 8: 4583
-
[73]
[73] Butler, M. F.; Glaser, N.; Weaver, A. C.; Kirkland, M.; Heppenstall-Butler, M. Cryst. Growth Des., 2006, 6: 781
-
[74]
[74] OlderΦy, M. Φ.; Xie, M. L.; Strand, B. L.; Flaten, E. M.; Sikorski, P.; Andreassen, J. P. Cryst. Growth Des., 2009, 9: 5176
-
[75]
[75] Sugawara, T.; Suwa, Y.; Ohkawa, K.; Yamamoto, H. Macromol. Rapid Commun., 2003, 24: 847
-
[76]
[76] Colfen, H.; Mann, S. Angew. Chem. Int. Edit., 2003, 42: 2350
-
[77]
[77] Wang, T.; Antonietti, M.; Colfen, H. Chem. Eur. J., 2006, 12: 5722
-
[78]
[78] Yao, C. L. Chin. J. Chem., 2008, 26: 1075
-
[79]
[79] Shen, X.; Belcher, A. M.; Hansma, P. K.; Stucky, G. D.; Morse, D. E. J. Biol. Chem., 1997, 272: 32472
-
[80]
[80] Li, J. H.; Yu, P.; Chen, P.; Luo, Y. B. Industrial Water Wastewater, 2006, 37:
-
[81]
[75] [李江华, 于 萍, 陈 平, 罗运柏. 工业用水与废水, 2006, 37: 75]
-
[82]
[81] Liu, Z. F.; Wang, Y. J.; Tian, C. L.; Zhang, Y. H. J. Chem. Ind. Eng., 2006, 57:
-
[83]
[2361] [刘振法, 王延吉, 田彩莉, 张彦河. 化工学报, 2006, 57: 2361]
-
[84]
[82] Cheng, Z. H.; Huang, J. L.; Zhang, Y. L.; Yu, X. Y.; Yang, S. L. J. Nanjing Univ. Sci. Technol.: Nature Science, 2007, 31:
-
[85]
[248] [程志辉, 黄君礼, 张玉玲, 于小英, 杨士林. 南京理工大学学报: 自然科学版, 2007, 31: 248]
-
[86]
[83] Cao, Y. X.; Yang, J.; Li, J. J. Tongji Univ.: Nature Science, 2004, 32:
-
[87]
[556] [曹英霞, 杨 坚, 李 杰. 同济大学学报:自然科学版, 2004, 32: 556]
-
[88]
[84] Deng, L. Q. Regulation of polymer on calcium oxalate urinary calculi grown in aqueous solutions [M]. Guangzhou: Jinan Unversity,
-
[89]
[2006] [邓兰青. 聚合物对草酸钙尿路结石的调控作用[M]. 广州: 暨南大学, 2006]
-
[90]
[85] Carlsen, A.; Lecommandoux, S. Curr. Opin. Colloid Interface Sci., 2009, 14: 329
-
[91]
[86] Xu, A. W.; Antonietti, M.; Yu, S. H.; Colfen, H. Adv. Mater., 2008, 20: 1333
-
[92]
[87] Wang, F.; Xu, G. Y.; Zhang, Z. Q.; Xiao, L. Acta Chim. Sin., 2003, 61:
-
[93]
[1488] [王 芳, 徐桂英, 张志庆, 肖 莉. 化学学报, 2003, 61: 1488]
-
[94]
[88] Yu, S. H.; Colfen, H. J. Mater. Chem., 2004, 14: 2124
-
[95]
[89] Colfen, H.; Yu, S. H. MRS Bulletin, 2005, 30: 727
-
[96]
[90] Liu, X.; Liu, B.; Wang, Z.; Zhang, B.; Zhang, Z. J. Phys. Chem. C, 2008, 112: 9632
-
[97]
[91] Huang, J.; Luo, M.; Wang, Y. J. Phys. Chem. B, 2008, 112: 6735
-
[98]
[92] Castillo, R. V.; Müler, A. J. Prog. Polym. Sci., 2009, 34: 516
-
[99]
[93] Colfen, H. Macromol. Rapid Commun., 2001, 22: 219
-
[100]
[94] Guvendiren, M.; Heiney, P. A.; Yang, S. Macromolecules, 2009, 42: 6606
-
[101]
[95] Zhang, P.; Zhong, X.; Chai, Y.; Liu, Y. Colloid. Polym. Sci., 2008, 286: 1135
-
[102]
[96] Colfen, H.; Antonietti, M. Langmuir, 1998, 14: 582
-
[103]
[97] Wada, N.; Kanamura, K.; Umegaki, T. J. Colloid Interface Sci., 2001, 233: 65
-
[104]
[98] Sedlák, M.; Colfen, H. Macromol. Chem. Phys., 2001, 202: 587
-
[105]
[99] Yang, H.; Su, Y.; Zhu, H.; Zhu, H.; Xie, B.; Zhao, Y.; Chen, Y.; Wang, D. Polymer, 2007, 48: 4344
-
[106]
[100] Wang, L.; Meng, Z.; Yu, Y.; Meng, Q.; Chen, D. Polymer, 2008, 49: 1199
-
[107]
[101] Qi, L.; Colfen, H.; Antonietti, M. Nano Lett., 2000, 1: 61
-
[108]
[102] Pecher, J.; Guenoun, P.; Chevallard, C. Cryst. Growth Des., 2009, 9: 1306
-
[109]
[103] He, L.; Xue, R.; Song, R. J. Solid State Chem., 2009, 182: 1082
-
[110]
[104] Ouhenia, S.; Chateigner, D.; Belkhir, M. A.; Guilmeau, E.; Krauss, C. J. Cryst. Growth, 2008, 310: 2832
-
[111]
[105] Tang, Y.; Yang, W.; Yin, X.; Liu, Y.; Yin, P.; Wang, J. Desalination, 2008, 228: 55
-
[112]
[106] Ouyang, X.; Qiu, X.; Lou, H.; Yang, D. Ind. Eng. Chem. Res., 2006, 45: 5716
-
[113]
[107] Yan, G. W.; Huang, J. H.; Zhang, J. F.; Qian, C. J. Mater. Res. Bull., 2008, 43: 2069
-
[114]
[108] Jiang, F.; Yang, Y.; Huang, L.; Chen, X.; Shao, Z. J. Appl. Polym. Sci., 2009, 114: 3686
-
[115]
[109] Kim, R.; Kim, C.; Lee, S.; Kim, J.; Kim, I. W. Cryst. Growth Des., 2009, 9: 4584
-
[116]
[110] Butler, M. F.; Frith, W. J.; Rawlins, C.; Weaver, A. C.; Heppenstall-Butler, M. Cryst. Growth Des., 2009, 9: 534
-
[117]
[111] Wu, Q. S.; Sun, D. M.; Liu, H. J.; Ding, Y. P. Cryst. Growth Des., 2004, 4: 717
-
[118]
[112] Sun, D. M.; Wu, Q. S. Chin. J. Chem., 2004, 22: 1067
-
[119]
[113] Park, W. K.; Ko, S. J.; Lee, S. W.; Cho, K. H.; Ahn, J. W.; Han, C. J. Cryst. Growth, 2008, 310: 2593
-
[120]
[114] Nightingale, E. R. J. Phys. Chem., 1959, 63: 1381
-
[121]
[115] Becker, A.; Ziegler, A.; Epple, M. Dalton Trans., 2005: 1814
-
[122]
[116] Levi-Kalisman, Y.; Raz, S.; Weiner, S.; Addadi, L.; Sagi, I. Adv. Funct. Mater., 2002, 12: 43
-
[123]
[117] Meldrum, F. C.; Hyde, S. T. J. Cryst. Growth, 2001, 231: 544
-
[124]
[118] Zhang, B.; He, P.; Zhang, M. L.; Liang, B.; Xu, S. L. China Surfactant Detergent Cosmetics, 2002, 32: 83 [张 彪, 何 萍, 张明玲, 梁 斌, 徐世玲. 日用化学工业, 2002, 32: 83]
-
[125]
[119] Chen, Z. P.; Wang, H. X.; Lu, Y. H. China Surfactant Detergent Cosmetics, 2003, 33: 87 [陈志萍, 王红霞, 陆用海. 日用化学工业, 2003, 33: 87]
-
[126]
[120] Yu, J.; Lei, M.; Cheng, B.; Zhao, X. J. Solid State Chem., 2004, 177: 681
-
[127]
[121] Tao, C.; Li, J. Langmuir, 2003, 19: 10353
-
[128]
[122] Tao, C.; Zheng, S.; Mohwald, H.; Li, J. Langmuir, 2003, 19: 9039
-
[129]
[123] Wang, L.; Chen, X.; Chai, Y.; Hao, J.; Sui, Z.; Zhuang, W.; Sun, Z. Chem. Commun., 2004: 2840
-
[130]
[124] Wang, L.; Chen, X.; Zhan, J.; Sui, Z.; Zhao, J.; Sun, Z. Chem. Lett., 2004, 33: 720
-
[131]
[125] Wang, L.; Chen, X.; Zhao, J.; Sui, Z.; Zhuang, W.; Xu, L.; Yang, C. Colloid. Surf. A, 2005, 257-258: 231
-
[132]
[126] Wang, L.; Chen, X.; Zhan, J.; Chai, Y.; Yang, C.; Xu, L.; Zhuang, W.; Jing, B. J. Phys. Chem. B, 2005, 109: 3189
-
[133]
[127] Szczes, A.; Chibowski, E.; Holysz, L. Colloid. Surf. A, 2007, 297: 14
-
[134]
[128] Szczes, A. Colloid. Surf. A, 2008, 320: 98
-
[135]
[129] Wei, H.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 264: 424
-
[136]
[130] Dong, S.; Li, X.; Xu, G.; Hoffmann, H. J. Phys. Chem. B, 2007, 111: 5903
-
[137]
[131] Tjandra, W.; Yao, J.; Ravi, P.; Tam, K. C.; Alamsjah, A. Chem. Mater., 2005, 17: 4865
-
[138]
[132] Guo, J.; Cao, J. M.; Zheng, M. B.; Deng, S. G.; Jiang, X. H.; Wang, H. Y.; Tao, J. Chin. J. Inorg. Chem., 2007, 23: 725 [郭 静, 曹洁明, 郑明波, 邓少高, 蒋锡华, 王海燕, 陶 杰. 无机化学学报, 2007, 23: 725]
-
[139]
[133] Yu, J.; Zhao, X.; Cheng, B.; Zhang, Q. J. Solid State Chem., 2005, 178: 861
-
[140]
[134] Donners, J. J. J. M.; Heywood, B. R.; Meijer, E. W.; Nolte, R. J. M.; Sommerdijk, N. A. J. M. Chem. Eur. J., 2002, 8: 2561
-
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