Citation: YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying. Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2087-2095. doi: 10.3866/PKU.WHXB20100639 shu

Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules

  • Received Date: 26 January 2010
    Available Online: 11 May 2010

    Fund Project: 国家自然科学基金(20833010)资助项目 (20833010)

  • The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our work. The mechanisms are interpreted based on the analysis of calcium carbonate crystallization in the presence of biomacromolecules, synthetic polymers, or mixtures of the polymer and surfactants. This paper provides not only the methods for the crystallization of calcium carbonate consisting of different resultant morphologies, polymorphs, and sizes, but also a theoretical guide for industrial production.

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    1. [1]

      [1] Stupp, S. I.; Braun, P. V. Science, 1997, 277: 1242

    2. [2]

      [2] Naka, K.; Chujo, Y. Chem. Mater., 2001, 13: 3245

    3. [3]

      [3] Cõlfen, H. Curr. Opin. Colloid Interface Sci., 2003, 8: 23

    4. [4]

      [4] Politi, Y.; Arad, T.; Klein, E.; Weiner, S.; Addadi, L. Science, 2004, 306: 1161

    5. [5]

      [5] Xu, A. W.; Ma, Y.; Cõlfen, H. J. Mater. Chem., 2007, 17: 415

    6. [6]

      [6] Porter, S. M. Science, 2007, 316: 1302

    7. [7]

      [7] Stanley, S. M. Chem. Rev., 2008, 108: 4483

    8. [8]

      [8] Wang, L.; Nancollas, G. H. Chem. Rev., 2008, 108: 4628

    9. [9]

      [9] Ouyang, J. M. The modulation and application of matrix in biomimetic mineralization. Beijing: Chemical Industry Press, 2006: 1-45 [欧阳健明. 生物矿化的基质调控及其仿生应用. 北京: 化学工业出版社, 2006: 1-45]

    10. [10]

      [10] Mount, A. S.; Wheeler, A. P.; Paradkar, R. P.; Snider, D. Science, 2004, 304: 297

    11. [11]

      [11] Sugawara, A.; Kato, T. Chem. Commun., 2000: 487

    12. [12]

      [12] Cheng, B.; Lei, M.; Yu, J.; Zhao, X. Mater. Lett., 2004, 58: 1565

    13. [13]

      [13] Cui, F. Z. Biomineralization. Beijing. Tsinghua University Press, 2007: 90-156 [崔福斋. 生物矿化. 北京: 清华大学出版社, 2007: 90-156]

    14. [14]

      [14] Lochhead, M. J.; Letellier, S. R.; Vogel, V. J. Phys. Chem. B, 1997, 101: 10821

    15. [15]

      [15] Wei, H. Controlled mineralization of calcium carbonate by organic additives [D]. Beijing: Institute of Chemistry, Chinese Academy of Sciences, 2005 [魏 浩. 有机质对碳酸钙矿化过程机理研究 [D]. 北京: 中国科学院化学研究所, 2005]

    16. [16]

      [16] Wolf, S. E.; Loges, N.; Mathiasch, B.; Panth?觟fer, M.; Mey, I.; Janshoff, A.; Tremel, W. Angew. Chem. Int. Edit., 2007, 46: 5618

    17. [17]

      [17] Heuer, A.; Fink, D.; Laraia, V.; Arias, J.; Calvert, P.; Kendall, K.; Messing, G.; Blackwell, J.; Rieke, P.; Thompson, D. Science, 1992, 255: 1098

    18. [18]

      [18] Mann, S. J. Mater. Chem., 1995, 5: 935

    19. [19]

      [19] Mann, S.; Heywood, B. R.; Rajam, S.; Birchall, J. D. Nature, 1988, 334: 692

    20. [20]

      [20] Arias, J. L.; Fernàndez, M. S. Chem. Rev., 2008, 108: 4475

    21. [21]

      [21] Evans, J. S. Chem. Rev., 2008, 108: 4455

    22. [22]

      [22] Dickerson, M. B.; Sandhage, K. H.; Naik, R. R. Chem. Rev., 2008, 108: 4935

    23. [23]

      [23] Cusack, M.; Freer, A. Chem. Rev., 2008, 108: 4433

    24. [24]

      [24] Sommerdijk, N. A. J. M.; With, G. D. Chem. Rev., 2008, 108: 4499

    25. [25]

      [25] Cai, G. B.; Wan, Y.; Yu, S. H. Chin. J. Inorg. Chem., 2008, 24: 673 [蔡国斌, 万 勇, 俞书宏. 无机化学学报, 2008, 24: 673]

    26. [26]

      [26] Sun, Z. Y.; Huang, J. B. Acta Phys. -Chim. Sin., 2006, 22: 172 [孙振亚, 黄江波. 物理化学学报, 2006, 22: 172]

    27. [27]

      [27] Gómez-Morales, J.; Hernández-Hernández, A.; Sazaki, G.; García- Ruiz, J. M. Cryst. Growth Des., 2010, 10: 963

    28. [28]

      [28] Tohse, H.; Saruwatari, K.; Kogure, T.; Nagasawa, H.; Takagi, Y. Cryst. Growth Des., 2009, 9: 4897

    29. [29]

      [29] Yao, Y.; Dong, W.; Zhu, S.; Yu, X.; Yan, D. Langmuir, 2009, 25: 13238

    30. [30]

      [30] Politi, Y.; Batchelor, D. R.; Zaslansky, P.; Chmelka, B. F.; Weaver, J. C.; Sagi, I.; Weiner, S.; Addadi, L. Chem. Mater., 2010, 22: 161

    31. [31]

      [31] You, C.; Zhang, Q.; Jiao, Q.; Fu, Z. Cryst. Growth Des., 2009, 9: 4720

    32. [32]

      [32] Yamanaka, S.; Ito, N.; Shimosaka, A.; Shirakawa, Y.; Hidaka, J. Cryst. Growth Des., 2009, 9: 3245

    33. [33]

      [33] Hou, W.; Feng, Q. J. Cryst. Growth, 2005, 282: 214

    34. [34]

      [34] Zhang, Z.; Gao, D.; Zhao, H.; Xie, C.; Guan, G.; Wang, D.; Yu, S. H. J. Phys. Chem. B, 2006, 110: 8613

    35. [35]

      [35] Orme, C. A.; Noy, A.; Wierzbicki, A.; McBride, M. T.; Grantham, M.; Teng, H. H.; Dove, P. M.; DeYoreo, J. J. Nature, 2001, 411: 775

    36. [36]

      [36] Mao, Z.; Huang, J. J. Solid State Chem., 2007, 180: 453

    37. [37]

      [37] Maas, M.; Rehage, H.; Nebel, H.; Epple, M. Colloid. Polym. Sci., 2007, 285: 1301

    38. [38]

      [38] Loste, E.; Wilson, R. M.; Seshadri, R.; Meldrum, F. C. J. Cryst. Growth, 2003, 254: 206

    39. [39]

      [39] Zhu, L.; Zhao, Q.; Zheng, X.; Xie, Y. J. Solid State Chem., 2006, 179: 1247

    40. [40]

      [40] Katsifaras, A.; Spanos, N. J. Gryst. Growth, 1999, 204: 183

    41. [41]

      [41] Ajikumar, P. K.; Wong, L. G.; Subramanyam, G.; Lakshminarayanan, R.; Valiyaveettil, S. Cryst. Growth Des., 2005, 5: 1129

    42. [42]

      [42] Nishino, Y.; Oaki, Y.; Imai, H. Cryst. Growth Des., 2009, 9: 223

    43. [43]

      [43] Vavouraki, A. I.; Putnis, C. V.; Putnis, A.; Koutsoukos, P. G. Chem. Geol., 2008, 253: 243

    44. [44]

      [44] Nebel, H.; Epple, M. Z. Anorg. Allg. Chem., 2008, 634: 1439

    45. [45]

      [45] Yan, R. X. Water-soluble macromolecules. Beijing: Chemical Industry Press, 1998: 1-41 [严瑞. 水溶性大分子. 北京: 化学工业出版社, 1998: 1-41]

    46. [46]

      [46] Yang, X.; Xu, G.; Chen, Y.; Wang, F.; Mao, H.; Sui, W.; Bai, Y.; ng, H. J. Cryst. Growth, 2009, 311: 4558

    47. [47]

      [47] Huang, Y.; Shen, Q.; Sui, W.; Guo, M.; Zhao, Y.; Wang, D.; Xu, D. Colloid. Polym. Sci., 2007, 285: 641

    48. [48]

      [48] Liang, P.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wei, H.; Lieberwirth, I.; Huang, Y.; Wang, D.; Xu, D. Langmuir, 2004, 20: 10444

    49. [49]

      [49] Li, X.; Shen, Q.; Su, Y.; Tian, F.; Zhao, Y.; Wang, D. Cryst. Growth Des., 2009, 9: 3470

    50. [50]

      [50] Liang, P.; Zhao, Y.; Shen, Q.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 261: 571

    51. [51]

      [51] Wei, H.; Shen, Q.; Wang, H.; Gao, Y.; Zhao, Y.; Xu, D.; Wang, D. J. Cryst. Growth, 2007, 303: 537

    52. [52]

      [52] Shen, Q.; Wei, H.; Zhao, Y.; Wang, D. J.; Zheng, L. Q.; Xu, D. F. Colloid. Surf. A, 2004, 251: 87

    53. [53]

      [53] Wei, H.; Shen, Q.; Zhao, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 260: 545

    54. [54]

      [54] Shen, Q.; Wei, H.; Wang, L.; Zhou, Y.; Zhao, Y.; Zhang, Z.; Wang, D.; Xu, G.; Xu, D. J. Phys. Chem. B, 2005, 109: 18342

    55. [55]

      [55] Kontrec, J.; Kralj, D.; Brecevic, L.; Falini, G. J. Cryst. Growth, 2008, 310: 4554

    56. [56]

      [56] Matahwa, H.; Ramiah, V.; Sanderson, R. D. J. Cryst. Growth, 2008, 310: 4561

    57. [57]

      [57] wer, L. B.; Odom, D. J. J. Cryst. Growth, 2000, 210: 719

    58. [58]

      [58] Hernández-Hernández, A.; Vidal, M. L.; Gómez-Morales, J.; Rodríguez-Navarro, A. B.; Labas, V.; Gautron, J.; Nys, Y.; Ruíz, J. M. G. J. Cryst. Growth, 2008, 310: 1754

    59. [59]

      [59] Díaz-Dosque, M.; Aranda, P.; Darder, M.; Retuert, J.; Yazdani- Pedram, M.; Arias, J. L.; Ruiz-Hitzky, E. J. Cryst. Growth, 2008, 310: 5331

    60. [60]

      [60] Sondi, I.; Skapin, S. D.; Salopek-Sondi, B. Cryst. Growth Des., 2008, 8: 435

    61. [61]

      [61] Liu, X.; Zhang, L.; Wang, Y.; Guo, C.; Wang, E. Cryst. Growth Des., 2008, 8: 759

    62. [62]

      [62] Qi, L.; Li, J.; Ma, J. Adv. Mater., 2002, 14: 300

    63. [63]

      [63] Colfen, H.; Qi, L. Chem. Eur. J., 2001, 7: 106

    64. [64]

      [64] Gao, Y. X.; Yu, S. H.; Guo, X. H. Langmuir, 2006, 22: 6125

    65. [65]

      [65] Gao, Y. X.; Yu, S. H.; Cong, H.; Jiang, J.; Xu, A. W.; Dong, W. F.; Colfen, H. J. Phys. Chem. B, 2006, 110: 6432

    66. [66]

      [66] Hernández-Hernández, A.; Rodríguez-Navarro, A. B.; Gómez- Morales, J.; Jiménez-Lopez, C.; Nys, Y.; García-Ruiz, J. M. Cryst. Growth Des., 2008, 8: 1495

    67. [67]

      [67] Voinescu, A. E.; Touraud, D.; Lecker, A.; Pfitzner, A.; Kunz, W.; Ninham, B. W. Langmuir, 2007, 23: 12269

    68. [68]

      [68] Lee, S. W.; Choi, C. S. Cryst. Growth Des., 2007, 7: 1463

    69. [69]

      [69] Wang, X.; Sun, H.; Xia, Y.; Chen, C.; Xu, H.; Shan, H.; Lu, J. R. J. Colloid Interface Sci., 2009, 332: 96

    70. [70]

      [70] Roqu, J.; Molera, J.; Vendrell-Saz, M.; Salvad, N. J. Cryst. Growth, 2004, 262: 543

    71. [71]

      [71] Shen, F. H.; Feng, Q. L.; Wang, C. M. J. Cryst. Growth, 2002, 242: 239

    72. [72]

      [72] Xiang, J.; Cao, H.; Warner, J. H.; Watt, A. A. R. Cryst. Growth Des., 2008, 8: 4583

    73. [73]

      [73] Butler, M. F.; Glaser, N.; Weaver, A. C.; Kirkland, M.; Heppenstall-Butler, M. Cryst. Growth Des., 2006, 6: 781

    74. [74]

      [74] OlderΦy, M. Φ.; Xie, M. L.; Strand, B. L.; Flaten, E. M.; Sikorski, P.; Andreassen, J. P. Cryst. Growth Des., 2009, 9: 5176

    75. [75]

      [75] Sugawara, T.; Suwa, Y.; Ohkawa, K.; Yamamoto, H. Macromol. Rapid Commun., 2003, 24: 847

    76. [76]

      [76] Colfen, H.; Mann, S. Angew. Chem. Int. Edit., 2003, 42: 2350

    77. [77]

      [77] Wang, T.; Antonietti, M.; Colfen, H. Chem. Eur. J., 2006, 12: 5722

    78. [78]

      [78] Yao, C. L. Chin. J. Chem., 2008, 26: 1075

    79. [79]

      [79] Shen, X.; Belcher, A. M.; Hansma, P. K.; Stucky, G. D.; Morse, D. E. J. Biol. Chem., 1997, 272: 32472

    80. [80]

      [80] Li, J. H.; Yu, P.; Chen, P.; Luo, Y. B. Industrial Water Wastewater, 2006, 37:

    81. [81]

      [75] [李江华, 于 萍, 陈 平, 罗运柏. 工业用水与废水, 2006, 37: 75]

    82. [82]

      [81] Liu, Z. F.; Wang, Y. J.; Tian, C. L.; Zhang, Y. H. J. Chem. Ind. Eng., 2006, 57:

    83. [83]

      [2361] [刘振法, 王延吉, 田彩莉, 张彦河. 化工学报, 2006, 57: 2361]

    84. [84]

      [82] Cheng, Z. H.; Huang, J. L.; Zhang, Y. L.; Yu, X. Y.; Yang, S. L. J. Nanjing Univ. Sci. Technol.: Nature Science, 2007, 31:

    85. [85]

      [248] [程志辉, 黄君礼, 张玉玲, 于小英, 杨士林. 南京理工大学学报: 自然科学版, 2007, 31: 248]

    86. [86]

      [83] Cao, Y. X.; Yang, J.; Li, J. J. Tongji Univ.: Nature Science, 2004, 32:

    87. [87]

      [556] [曹英霞, 杨 坚, 李 杰. 同济大学学报:自然科学版, 2004, 32: 556]

    88. [88]

      [84] Deng, L. Q. Regulation of polymer on calcium oxalate urinary calculi grown in aqueous solutions [M]. Guangzhou: Jinan Unversity,

    89. [89]

      [2006] [邓兰青. 聚合物对草酸钙尿路结石的调控作用[M]. 广州: 暨南大学, 2006]

    90. [90]

      [85] Carlsen, A.; Lecommandoux, S. Curr. Opin. Colloid Interface Sci., 2009, 14: 329

    91. [91]

      [86] Xu, A. W.; Antonietti, M.; Yu, S. H.; Colfen, H. Adv. Mater., 2008, 20: 1333

    92. [92]

      [87] Wang, F.; Xu, G. Y.; Zhang, Z. Q.; Xiao, L. Acta Chim. Sin., 2003, 61:

    93. [93]

      [1488] [王 芳, 徐桂英, 张志庆, 肖 莉. 化学学报, 2003, 61: 1488]

    94. [94]

      [88] Yu, S. H.; Colfen, H. J. Mater. Chem., 2004, 14: 2124

    95. [95]

      [89] Colfen, H.; Yu, S. H. MRS Bulletin, 2005, 30: 727

    96. [96]

      [90] Liu, X.; Liu, B.; Wang, Z.; Zhang, B.; Zhang, Z. J. Phys. Chem. C, 2008, 112: 9632

    97. [97]

      [91] Huang, J.; Luo, M.; Wang, Y. J. Phys. Chem. B, 2008, 112: 6735

    98. [98]

      [92] Castillo, R. V.; Müler, A. J. Prog. Polym. Sci., 2009, 34: 516

    99. [99]

      [93] Colfen, H. Macromol. Rapid Commun., 2001, 22: 219

    100. [100]

      [94] Guvendiren, M.; Heiney, P. A.; Yang, S. Macromolecules, 2009, 42: 6606

    101. [101]

      [95] Zhang, P.; Zhong, X.; Chai, Y.; Liu, Y. Colloid. Polym. Sci., 2008, 286: 1135

    102. [102]

      [96] Colfen, H.; Antonietti, M. Langmuir, 1998, 14: 582

    103. [103]

      [97] Wada, N.; Kanamura, K.; Umegaki, T. J. Colloid Interface Sci., 2001, 233: 65

    104. [104]

      [98] Sedlák, M.; Colfen, H. Macromol. Chem. Phys., 2001, 202: 587

    105. [105]

      [99] Yang, H.; Su, Y.; Zhu, H.; Zhu, H.; Xie, B.; Zhao, Y.; Chen, Y.; Wang, D. Polymer, 2007, 48: 4344

    106. [106]

      [100] Wang, L.; Meng, Z.; Yu, Y.; Meng, Q.; Chen, D. Polymer, 2008, 49: 1199

    107. [107]

      [101] Qi, L.; Colfen, H.; Antonietti, M. Nano Lett., 2000, 1: 61

    108. [108]

      [102] Pecher, J.; Guenoun, P.; Chevallard, C. Cryst. Growth Des., 2009, 9: 1306

    109. [109]

      [103] He, L.; Xue, R.; Song, R. J. Solid State Chem., 2009, 182: 1082

    110. [110]

      [104] Ouhenia, S.; Chateigner, D.; Belkhir, M. A.; Guilmeau, E.; Krauss, C. J. Cryst. Growth, 2008, 310: 2832

    111. [111]

      [105] Tang, Y.; Yang, W.; Yin, X.; Liu, Y.; Yin, P.; Wang, J. Desalination, 2008, 228: 55

    112. [112]

      [106] Ouyang, X.; Qiu, X.; Lou, H.; Yang, D. Ind. Eng. Chem. Res., 2006, 45: 5716

    113. [113]

      [107] Yan, G. W.; Huang, J. H.; Zhang, J. F.; Qian, C. J. Mater. Res. Bull., 2008, 43: 2069

    114. [114]

      [108] Jiang, F.; Yang, Y.; Huang, L.; Chen, X.; Shao, Z. J. Appl. Polym. Sci., 2009, 114: 3686

    115. [115]

      [109] Kim, R.; Kim, C.; Lee, S.; Kim, J.; Kim, I. W. Cryst. Growth Des., 2009, 9: 4584

    116. [116]

      [110] Butler, M. F.; Frith, W. J.; Rawlins, C.; Weaver, A. C.; Heppenstall-Butler, M. Cryst. Growth Des., 2009, 9: 534

    117. [117]

      [111] Wu, Q. S.; Sun, D. M.; Liu, H. J.; Ding, Y. P. Cryst. Growth Des., 2004, 4: 717

    118. [118]

      [112] Sun, D. M.; Wu, Q. S. Chin. J. Chem., 2004, 22: 1067

    119. [119]

      [113] Park, W. K.; Ko, S. J.; Lee, S. W.; Cho, K. H.; Ahn, J. W.; Han, C. J. Cryst. Growth, 2008, 310: 2593

    120. [120]

      [114] Nightingale, E. R. J. Phys. Chem., 1959, 63: 1381

    121. [121]

      [115] Becker, A.; Ziegler, A.; Epple, M. Dalton Trans., 2005: 1814

    122. [122]

      [116] Levi-Kalisman, Y.; Raz, S.; Weiner, S.; Addadi, L.; Sagi, I. Adv. Funct. Mater., 2002, 12: 43

    123. [123]

      [117] Meldrum, F. C.; Hyde, S. T. J. Cryst. Growth, 2001, 231: 544

    124. [124]

      [118] Zhang, B.; He, P.; Zhang, M. L.; Liang, B.; Xu, S. L. China Surfactant Detergent Cosmetics, 2002, 32: 83 [张 彪, 何 萍, 张明玲, 梁 斌, 徐世玲. 日用化学工业, 2002, 32: 83]

    125. [125]

      [119] Chen, Z. P.; Wang, H. X.; Lu, Y. H. China Surfactant Detergent Cosmetics, 2003, 33: 87 [陈志萍, 王红霞, 陆用海. 日用化学工业, 2003, 33: 87]

    126. [126]

      [120] Yu, J.; Lei, M.; Cheng, B.; Zhao, X. J. Solid State Chem., 2004, 177: 681

    127. [127]

      [121] Tao, C.; Li, J. Langmuir, 2003, 19: 10353

    128. [128]

      [122] Tao, C.; Zheng, S.; Mohwald, H.; Li, J. Langmuir, 2003, 19: 9039

    129. [129]

      [123] Wang, L.; Chen, X.; Chai, Y.; Hao, J.; Sui, Z.; Zhuang, W.; Sun, Z. Chem. Commun., 2004: 2840

    130. [130]

      [124] Wang, L.; Chen, X.; Zhan, J.; Sui, Z.; Zhao, J.; Sun, Z. Chem. Lett., 2004, 33: 720

    131. [131]

      [125] Wang, L.; Chen, X.; Zhao, J.; Sui, Z.; Zhuang, W.; Xu, L.; Yang, C. Colloid. Surf. A, 2005, 257-258: 231

    132. [132]

      [126] Wang, L.; Chen, X.; Zhan, J.; Chai, Y.; Yang, C.; Xu, L.; Zhuang, W.; Jing, B. J. Phys. Chem. B, 2005, 109: 3189

    133. [133]

      [127] Szczes, A.; Chibowski, E.; Holysz, L. Colloid. Surf. A, 2007, 297: 14

    134. [134]

      [128] Szczes, A. Colloid. Surf. A, 2008, 320: 98

    135. [135]

      [129] Wei, H.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 264: 424

    136. [136]

      [130] Dong, S.; Li, X.; Xu, G.; Hoffmann, H. J. Phys. Chem. B, 2007, 111: 5903

    137. [137]

      [131] Tjandra, W.; Yao, J.; Ravi, P.; Tam, K. C.; Alamsjah, A. Chem. Mater., 2005, 17: 4865

    138. [138]

      [132] Guo, J.; Cao, J. M.; Zheng, M. B.; Deng, S. G.; Jiang, X. H.; Wang, H. Y.; Tao, J. Chin. J. Inorg. Chem., 2007, 23: 725 [郭 静, 曹洁明, 郑明波, 邓少高, 蒋锡华, 王海燕, 陶 杰. 无机化学学报, 2007, 23: 725]

    139. [139]

      [133] Yu, J.; Zhao, X.; Cheng, B.; Zhang, Q. J. Solid State Chem., 2005, 178: 861

    140. [140]

      [134] Donners, J. J. J. M.; Heywood, B. R.; Meijer, E. W.; Nolte, R. J. M.; Sommerdijk, N. A. J. M. Chem. Eur. J., 2002, 8: 2561


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