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Citation: LIU Chang, XUE Li, HE Hong. Influence of Alkaline Earth Metals on Cobalt-Cerium Composite Oxide Catalysts for N₂O Decomposition[J]. Acta Physico-Chimica Sinica, ;2009, 25(06): 1033-1039. doi: 10.3866/PKU.WHXB20090604 shu

Influence of Alkaline Earth Metals on Cobalt-Cerium Composite Oxide Catalysts for N₂O Decomposition

1.
Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P. R. China

Received Date: 12 January 2009
Available Online: 26 March 2009

Catalysts of cobalt-cerium composite oxide doped with series of alkaline earth metals were prepared using the citrate method. Results of catalytic activity tests showed that the addition of alkaline earth metals enhanced the efficiency of N2O decomposition according to the following order: Mg<Ca<Sr,Ba. Characterization of these catalysts was done using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area measurement, X-ray photoelectron spectroscopy (XPS), oxygen temperature-programmed desorption (O2-TPD) and hydrogen temperature-programmed reduction (H2-TPR). Results indicated that the addition of alkaline earth metals did not change the crystal structures and specific surface areas of catalysts, but did enhance the electron donation ability of the active site (Co2+). The surface reaction of N2O with Co2+ involved electron donation from Co2+ to the anti-bonding orbital of N2O that resulted in the release of N2. The desorption of residual oxygen leads to the regeneration of the active site (Co2+) through the donation of electrons back to Co3+. We conclude that the addition of alkaline earth metals promotes surface reactions of N2O with Co2+ by facilitatingelectron donation from the active site. This process is the rate-determining step for purecobalt-cerium composite oxide catalysts and the catalytic activity for the decomposition of N2O is thus improved.
- N2O decomposition,
- Alkaline earth metal,
- Co3O4,
- CeO2,
- Composite oxide catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142

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Influence of Alkaline Earth Metals on Cobalt-Cerium Composite Oxide Catalysts for N2O Decomposition

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通讯作者: 陈斌, bchen63@163.com

Influence of Alkaline Earth Metals on Cobalt-Cerium Composite Oxide Catalysts for N₂O Decomposition