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Citation: HU Yi-Hua, LIN Jia-Yong, WU Hua, CHEN Ren, WANG Xiao-Juan, YANG Shi-He. Photo-induced Reaction of the Complex Mg⁺-S₂(CH₃)₂[J]. Acta Physico-Chimica Sinica, ;2006, 22(06): 744-746. doi: 10.3866/PKU.WHXB20060619 shu

Photo-induced Reaction of the Complex Mg⁺-S₂(CH₃)₂

1.
School of Physics & Opto-electronic Engineering; School of Continual Education, Guangdong University of Technology, Guangzhou 510090, P. R. China; Department of Chemistry, Hong Kong University of Science & Technology, Kowloon, Hong Kong

Received Date: 28 October 2005
Available Online: 31 May 2006

The single photon induced reaction of complex Mg+-S2(CH3)2 was studied in the spectral region of 230~440 nm. The mass spectrometry of the photo-induced reaction of the complex Mg+-S2(CH3)2 exhibits the existence of the products Mg+ and Mg+SCH3 throughout the whole wavelength range. The photodissociation spectrum consists of three broad peaks corresponding to the atomic transition of Mg+(32P←32S). The absorption spectrum by using CIS method of quantum chemistry calculation agrees with the experimental spectrum.
- Metal cation-molecule complex;Photo-induced reaction;Time of flight mass spectrum
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沈阳化工大学材料科学与工程学院沈阳 110142

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Photo-induced Reaction of the Complex Mg+-S2(CH3)2

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通讯作者: 陈斌, bchen63@163.com

Photo-induced Reaction of the Complex Mg⁺-S₂(CH₃)₂