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Citation: ZHANG Hui, CHEN Yuan-Chuan, WANG Fang, QIU Xiao-Ming, LI Li, CHEN Jian-Gu. Study on Solid-State Circular Dichroism Spectroscopy and Its Application to Chiral M(II) Schiff Base Complexes[J]. Acta Physico-Chimica Sinica, ;2006, 22(06): 666-671. doi: 10.3866/PKU.WHXB20060605 shu

Study on Solid-State Circular Dichroism Spectroscopy and Its Application to Chiral M(II) Schiff Base Complexes

1.
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Received Date: 7 December 2005
Available Online: 31 May 2006

An account on the application of solid-state CD on chiral metal complexes is briefly reviewed. Special focus is on the methods to record solid-state CD spectra of chiral solid sample, and then we switch to the comparison between solid-state and solution CD spectra of four pairs of chiral M(II) (M = Ni, Cu) Schiff base complexes. The solid-state CD spectra reveal that the chiral complexes mantain the same handeness found in solution states. But it is notable that there are some differences between the solid-state and solution CD spectra for the selective chiral complexes, which may be ascribed to some subtle tetrahedral distortion or conformational distinctions of the complexes between the two states.
- Solid-state circular dichroism(CD) spectroscopy;Method of measurement;Chirality;M(II) Schiff base complex
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