Home

Citation: JIANG Li-bo, MENG Ai-hua, ZHANG Qi-yun. The Three Pseudo-side-binary Systems in LiCl-(2ZnCl₂•KCl)-(ZnCl₂•2KCl) System[J]. Acta Physico-Chimica Sinica, ;2006, 22(02): 131-134. doi: 10.3866/PKU.WHXB20060201 shu

The Three Pseudo-side-binary Systems in LiCl-(2ZnCl₂•KCl)-(ZnCl₂•2KCl) System

1.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 3 June 2005
Available Online: 22 January 2006

Three pseudo-side-binary systems, LiCl-(2ZnCl2•KCl); LiCl-(ZnCl2•2KCl) and (2ZnCl2•KCl)-(ZnCl2•2KCl) in the pseudo-ternary LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl), have been investigated by visual-polythermal, DTA and XRD methods. Three new compounds were found in these systems. The ternary compound Li3K2Zn4Cl13 congruently melts at 245 ℃. The incongruent ternary compound Li12K2ZnCl16 and the binary incongruent compound K5Zn4Cl13 peritecticly melt at 432 ℃ and 249 ℃ respectively.
- Phase diagram;LiCl;KCl;ZnCl2
1. [1]
  Lifei Liu , Yali Du , Xia An , Xiufeng Shi , Xu Wu . Design of Ideological and Political Education in Phase Diagram Courses under the “Carbon Peaking and Carbon Neutrality Goals”: Guiding CO₂ Displacement for Natural Gas Hydrate Exploitation and CO₂ Sequestration. University Chemistry, 2026, 41(3): 242-247. doi: 10.12461/PKU.DXHX202504003
2. [2]
  Yujing Chen , Hongqun Ouyang , Dan Zhao , Yanyan Chu , Zhengping Qiao . Recommendations for the Content and Instruction of the Physical Chemistry Experiment “Construction of Ternary Liquid-Liquid Phase Diagrams”. University Chemistry, 2025, 40(7): 359-366. doi: 10.12461/PKU.DXHX202409120
3. [3]
  Yuxin Bai , Haiying Jiang . The Physical Chemistry behind Culinary Delights. University Chemistry, 2026, 41(2): 286-294. doi: 10.12461/PKU.DXHX202503082
4. [4]
  Xiao Liu , Hangqi Liu , Qian Wang , Dandan Zheng , Sibo Wang , Masakazu Anpo , Guigang Zhang . Rational synthesis of poly(heptazine imides) nanorod in ternary LiCl/NaCl/KCl for visible light hydrogen production. Chinese Chemical Letters, 2025, 36(12): 111621-. doi: 10.1016/j.cclet.2025.111621
5. [5]
  Yagang Yang , Hanqing Dong , Kai Yu , Qiushi Song , Zhiqiang Ning , Hongwei Xie . Electrochemical etching of photovoltaic micron-silicon scrap in molten KCl-LiCl for high-performance lithium-ion battery anodes. Chinese Chemical Letters, 2026, 37(4): 111492-. doi: 10.1016/j.cclet.2025.111492
6. [6]
  Yingyu Chen , Zhen Wang , Bowen Fan , Chenyang Zhang , Shanlin Li , Xueqing Tang , Yaowu Li , Xiaoyu Wang , Changhong Wang , De Li , Shan Cong , Zhigang Zhao . Temperature-tolerant electrochromic devices enabled by LiCl water-in-salt electrolyte with excellent performance. Chinese Chemical Letters, 2026, 37(4): 110824-. doi: 10.1016/j.cclet.2025.110824
7. [7]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
8. [8]
  Yanling Luo , Xuejie Qi , Rui Shen , Xuling Peng , Xiaoyan Han . Design and Implementation of Ideological and Political Education in the Physical Chemistry Course at Traditional Chinese Medicine Universities: A Case Study of the Phase Diagram of Water. University Chemistry, 2024, 39(11): 9-14. doi: 10.3866/PKU.DXHX202402003
9. [9]
  Yang Chen , Xiuying Wang , Nengqin Jia . Ideological and Political Design, Blended Teaching Practice of Physical Chemistry Experiment: Pb-Sn Binary Metal Phase Diagram. University Chemistry, 2025, 40(3): 223-229. doi: 10.12461/PKU.DXHX202405184
10. [10]
  Jiayin Hu , Yafei Guo , Long Li , Tianlong Deng . Teaching Innovation of Salt-Water System Phase Diagrams under the “Dual Carbon” Background: Introducing the Pressurized CO₂ Carbonization Phase Equilibria. University Chemistry, 2025, 40(11): 31-36. doi: 10.12461/PKU.DXHX202412031
11. [11]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
12. [12]
  Zhen-Qi Wang , Lin-Wen Wei , Zhao-Qing Wang , Yan-Jie Yang , Yu Zhao , Song Liu , Yuan Huang . Modular synthesis of polyfunctionalized axial-chiral 2-arylpyridines via cobalt-catalyzed asymmetric [2 + 2 + 2] cycloaddition of diynes and nitriles. Chinese Chemical Letters, 2026, 37(4): 111377-. doi: 10.1016/j.cclet.2025.111377
13. [13]
  Muzi Li , Xin Zhang , Xiang-Jing Kong , Qiancheng Chen , Xuefeng Bai , Tao He , Jian-Rong Li . Ion exchange for enhancing MOF adsorbents performance in humid C₂H₂/CO₂ separation. Chinese Chemical Letters, 2026, 37(3): 110709-. doi: 10.1016/j.cclet.2024.110709
14. [14]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
15. [15]
  Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348
16. [16]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
17. [17]
  Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
18. [18]
  Huirong Chen , Yingzhi He , Yan Han , Jianbo Hu , Jiantang Li , Yunjia Jiang , Basem Keshta , Lingyao Wang , Yuanbin Zhang . A new SIFSIX anion pillared cage MOF with crs topological structure for efficient C2H2/CO2 separation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100508-100508. doi: 10.1016/j.cjsc.2024.100508
19. [19]
  Zhiling Du , Zhiqi Zhou , Nan Sun , Cailiang Yue , Fuqiang Liu . Pyromellitic diimide induced TiO₂ mesocrystals with oxygen vacancies for synergistic photocatalytic H₂O₂ production and antibiotics degradation. Chinese Chemical Letters, 2026, 37(3): 111341-. doi: 10.1016/j.cclet.2025.111341
20. [20]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698

Get Citation

PDF

XML

Metrics

PDF Downloads(3283)
Abstract views(4141)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

The Three Pseudo-side-binary Systems in LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl) System

Metrics

通讯作者: 陈斌, bchen63@163.com

The Three Pseudo-side-binary Systems in LiCl-(2ZnCl₂•KCl)-(ZnCl₂•2KCl) System