Citation: Hua Rui-Mao. Homogeneous Catalytic Activation of Hetero-Carbon Bond and Its Addition to Alkynes[J]. Acta Physico-Chimica Sinica, ;2004, 20(08S): 989-994. doi: 10.3866/PKU.WHXB200408zk15
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This paper reviews the transition metal complexes such as Ni, Pd, Pt, Rh, Cu-catalyzed activation of hetero-carbon bonds and the related catalytic addition reactions with alkynes. These new addition reactions provide one-step, atom-economic methods for the preparation of the functionalized alkenes, which have R3Si, R3Sn, RS, RSe, Cl and Br groups. The addition reactions proceed with high stereoselectivities and regioselectivities.
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