Citation:
Li Huan-Jun, Guan Lun-Hui, Shi Zu-Jin, Gu Zhen-Nan. Synthesis and Characterization of C60@SWNTs[J]. Acta Physico-Chimica Sinica,
;2004, 20(04): 373-376.
doi:
10.3866/PKU.WHXB20040408
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Single-walled carbon nanotubes encapsulating C60 (peapods) C60@SWNTs have been successfully synthesized by a vapor diffusion method. High-resolution transmission electron microscopy (HRTEM) and Raman spectrum indicate high-density C60 chains inside the nanotubes. The distance between two adjacent C60 molecules in SWNTs is a little different from that in face centered cubic (fcc) C60 crystal,which reveals that there is a weak van der Waals interaction between the nanotubes and the encapsulated fullerenes. Moreover, in situ e-beam irradiation in the electron microscope caused coalescence of the neighboring C60 molecules inside the SWNTs.
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