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Citation: Yi Xiao-Dong, Lin Hong, He Yi-Ming, Huang Chuan-Jing, Weng Wei-Zheng, Wan Hui-Lin. Selective Oxidation of Propane over Mo-V-Zr-O Catalysts[J]. Acta Physico-Chimica Sinica, ;2004, 20(03): 309-312. doi: 10.3866/PKU.WHXB20040319 shu

Selective Oxidation of Propane over Mo-V-Zr-O Catalysts

1.
Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute of Physical Chemistry, Xiamen University, Xiamen　361005

Received Date: 29 August 2003
Available Online: 15 March 2004

A detailed study on the promotion effect of Zr on Mo-V mixed oxide catalysts in the selective oxidation of propane to acrolein was performed. The catalysts were characterized by BET, XRD, H2-TPR, NH3-TPD and isopropanol decomposition reaction. The addition of Zr modifies the catalysts phase composition and improves their redox and acid-base properties. As a result, the higher catalytic activity and selectivity were obtained over Mo2VZr0.5Ox catalyst.
- Propane;Selective oxidation;Acrolein;Mo-V-O based catalyst
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