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Citation: Hu Yi-Hua, Wu Huai-Xuan, Wang Xiao-Juan, Zhang Xing-Chu, Yang Shi-He. Resonant Two-photon Ionization Spectra of the van der Waals Complex C₆H₅CH₃…N₂[J]. Acta Physico-Chimica Sinica, ;2004, 20(02): 154-157. doi: 10.3866/PKU.WHXB20040209 shu

Resonant Two-photon Ionization Spectra of the van der Waals Complex C₆H₅CH₃…N₂

1.
Department of Applied Physics, School of Continual Education, Guangdong University of Technology, Guangzhou　510090; Department of Chemistry, Hong Kong University of Science ＆ Technology, Kowloon, Hong Kong

Received Date: 24 July 2003
Available Online: 15 February 2004

The resonant two-photons ionization technique is employed to study jet-cooled van der Waals (vdW) complex C6H5CH3…N2 through the S1←S0 transition. By Comparing the spectra of isotopic complex C6D5CD3…N2, we have tentatively assigned all the observed spectral features to the complex C6H5CH3…N2. The rich information about the complex intermolecular vdW viberational modes and internal rotation of N2 are obtained by the spectra. The binding energies for the complex C6H5CH3…N2 in the excited electronic state and in the ground electronic state are about 494 cm－1 and 474 cm－1, those are very close to the calculated values.
- van der Walls vibrations;Internal rotation;Binding energy
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Resonant Two-photon Ionization Spectra of the van der Waals Complex C6H5CH3…N2

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通讯作者: 陈斌, bchen63@163.com

Resonant Two-photon Ionization Spectra of the van der Waals Complex C₆H₅CH₃…N₂