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Citation: Li Zeng-He, Yin Chen, Wang Ru-Ji, Wang Ping, Guo Hong-You. Synthesis and Crystal Structure of an Inorganic-Organic Hybrid CompoundCo(μ₂-bpy)V₂O₆ (bpy=4,4’-bipyridine)[J]. Acta Physico-Chimica Sinica, ;2003, 19(12): 1133-1137. doi: 10.3866/PKU.WHXB20031208 shu

Synthesis and Crystal Structure of an Inorganic-Organic Hybrid CompoundCo(μ₂-bpy)V₂O₆ (bpy=4,4’-bipyridine)

1.
Department of Chemistry, Beijing University of Chemical Technology, Beijing 100029;Department of Chemistry, Tsinghua University, Beijing　100084

Received Date: 16 May 2003
Available Online: 15 December 2003

A novel inorganic/organic hybrid compound Co(μ2-bpy)V2O6 was synthesized by hydrothermal reaction of CoCl2•6H2O, 4,4′-bipyridine,NH4VO3,and H2O in a molar ratio of 1∶2∶2∶1950 at 170 ℃ for 72 h. The compound crystallized in triclinic space group Pī,with the cell parameters a=0.81599(7) nm, b=0.85826(7) nm, c=1.02031(8) nm, α=87.111(2)°, β=75.305(2)° and γ=74.782(2). As showed by single crystal X-ray diffraction, The crystal structure is constructed with inorganic bimetallic oxide layers, [Co2V4O12]n, and organic 4,4′-bipyridine μ2-ligands.The 4,4′-bipyridine ligands bridge the inorganic layers through N－Co coordination bonds to build up a three dimensional covalent framework with various open micropores. UV-Vis-NIR reflectance spectrum study revealed the nature of a semiconductor with an energy gap of ca.2.0 eV and thermal analysis showed thermal stability below 420 ℃ for the title compound.
- Co(μ₂-bpy)V₂O₆;Hydrothermal synthesis;Crystal structure;Thermal stability;Diffuse reflectance spectra
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Synthesis and Crystal Structure of an Inorganic-Organic Hybrid CompoundCo(μ2-bpy)V2O6 (bpy=4,4’-bipyridine)

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of an Inorganic-Organic Hybrid CompoundCo(μ₂-bpy)V₂O₆ (bpy=4,4’-bipyridine)