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Citation: Qin Cao, Wang Ting-Jie, Jin Yong. The Coating Process of Nano-scale Hydrous Silica Film on TiO₂ Particles by Chemical Deposition in Aqueous Solution[J]. Acta Physico-Chimica Sinica, ;2002, 18(10): 884-889. doi: 10.3866/PKU.WHXB20021004 shu

The Coating Process of Nano-scale Hydrous Silica Film on TiO₂ Particles by Chemical Deposition in Aqueous Solution

1.
Department of Chemical Engineering, Tsinghua University, Beijing　100084

Received Date: 21 January 2002
Available Online: 15 October 2002

The coating process of nano-scale hydrous silica film on TiO2 pigmentary particles by chemical deposition in aqueous solution has been investigated. Through the analysis of TEM images and dissolving the samples with hot sulfuric acid, it is proved that a uniform dense film of hydrous silica on TiO2 pigmentary particles is produced. Samples were taken in the coating process and analyzed by X-ray photoelectron spectroscopy (XPS),X-ray fluorescence (XRF),zeta-potential analyzer and transmission electron microscope (TEM). The silica composition and structure of the film on the coated particles in the coating process were measured and analyzed. It is inferred that polymeric silicate ions first hydrolyze into Si(OH)4,the later then reacts with OH－ groups on the surface of TiO2 particles. The silica acids subsequently produced condense on the surface of the core particles, forming a nano-scale film of polymerized silica. 　　According to the chemical shift of binding energy of Ti 2p,Si 2p and O 1s on the coated particles, the Ti－O－Si bond formation is inferred at the interface of the film and the surface of TiO2 particles. The thickness of the film increases with coating time and aging time. Zeta potential measurement shows that a very thin film coating of 0.5％ mass fraction can change the electrokinetic’s behavior of the particle surface remarkably.
- Titanium dioxide;Coating;Silica;Chemical deposition;Modification
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  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
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沈阳化工大学材料科学与工程学院沈阳 110142

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The Coating Process of Nano-scale Hydrous Silica Film on TiO2 Particles by Chemical Deposition in Aqueous Solution

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

The Coating Process of Nano-scale Hydrous Silica Film on TiO₂ Particles by Chemical Deposition in Aqueous Solution