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Citation: Zhang Hao, Suo Quan-Ling, Wang Yi-Bin, Wang Li, Weng Lin-Hong, Leng Xue-Bing. Synthesis and Crystal Structure of (μ₃-S)FeCo₂(CO)₇(dppfe)[J]. Acta Physico-Chimica Sinica, ;2002, 18(08): 746-749. doi: 10.3866/PKU.WHXB20020815 shu

Synthesis and Crystal Structure of (μ₃-S)FeCo₂(CO)₇(dppfe)

1.
Chemical Engineering College, Inner Mon lia Polytechnic University, Hohhot　010062; 1Institute of Elemento-organic Chemistry, Nankai University, Tianjin　300071

Received Date: 31 December 2001
Available Online: 15 August 2002

The new mixed metal cluster (μ3-S)FeCo2(CO)7(dppfe) (2) (dppfe= Ph2PC5H4FeC5H4PPh2) has been synthesized by facile substitution reaction, in which dppfe replaces two equatorial carbonyls from two Co(CO)3 groups, respectively. IR, 1H NMR, MS and X-ray crystallography characterized the new cluster 2. The cluster 2 crystallizes in triclinic space group Pī,with a=1.132 4(15) nm, b=1.367 0(17) nm, c=1.576 9(2) nm,α=114.646(2)°,β=100.340(2)°,γ=100.113(3)°,V=2.095 3(5) nm3.
- Fe-Co cluster;Ferrocenyl diphosphine ligand;Crystal structure
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Synthesis and Crystal Structure of (μ3-S)FeCo2(CO)7(dppfe)

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of (μ₃-S)FeCo₂(CO)₇(dppfe)