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Citation: ng Yan-Jun, Li Zhi-Hong, Wu Dong, Sun Yu-Han, Deng Feng, Luo Qing, Yue Yong. Synthesis of Vinyl-functionalized MSU-X Silicates[J]. Acta Physico-Chimica Sinica, ;2002, 18(06): 572-576. doi: 10.3866/PKU.WHXB20020621 shu

Synthesis of Vinyl-functionalized MSU-X Silicates

1.
State Key Laboratory of Coal Conversion, Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan　030001;State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan　430071

Received Date: 30 October 2001
Available Online: 15 June 2002

Vinyl-functionalized MSU-X silicates were prepared by one-pot synthesis methodology at the pre-sence of Tx-15 and AEO9 surfactants respectively. The solids were characterized by XRD, FT-IR, 29Si MASNMR, HRTEM, SEM, N2 physisorption techniques. The surface morphology and textural properties of such materials varied with the synthesis mechanism and content of vinyl groups in the channel. The effects of the organic groups on the modified MSU-2 were investigated carefully. The vinyl-modified mesopore with 10％(x) VTES templated by AEO9 was of 3.1nm pore diameter, but that templated by Tx-15 displayed a bimodal mesoporous channels, in which the smaller pore size was about 3 nm, while the bigger one was in the range of 40～46 nm.
- Mesoporous materials;Vinyl-modified-MSU-X;MSU-X
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