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Citation: Fu Tie-Xiang, Cao Jun, Tang Yue-Qun, Huang Dao-Chang, Li He-Ping. Synthesis and Properties of Polynuclear Complex of Co（Ⅱ） with 2,2’-bipyridine-1,1’-Dioxide[J]. Acta Physico-Chimica Sinica, ;2002, 18(06): 563-566. doi: 10.3866/PKU.WHXB20020619 shu

Synthesis and Properties of Polynuclear Complex of Co（Ⅱ） with 2,2’-bipyridine-1,1’-Dioxide

1.
Chemistry Department, Changsha University of Electric Power, Changsha　410077

Received Date: 2 November 2001
Available Online: 15 June 2002

A polynuclear complex was synthesized by the reaction of CoCl2 with 2,2’-bipyridine-1,1’-dioxide in DMF solution. Elemental analysis, IR, UV and molar conductivity measurements indicated the composition of the complex corresponding to the formula [Co3(bipyO2)4Cl4]Cl2.Study of the properties showed that the complex has od sensitivity and selectivity for ammonia. The output voltage of sensor produced by the complex responses non-linearly to the change of ammonia concentration in the range of 3.0×10－5～1.2×10－4 mol•L－1,but linear response was found in the range of 1.4×10－4～1.3×10－3 mol•L－1.The sensor manufactured by the complex could be used to detect and control the concentration of NH3 in production.
- Synthesis;Sensor;Cobalt chloride;Polynuclear complex;2,2’-bipyridine-1,1’-dioxide
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