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Citation: Ng Seikweng, Hu Sheng-Zhi. Reformulation of two Ni(Ⅱ)-8-hydroxyquinoline complexes from Calculated Structure Factors[J]. Acta Physico-Chimica Sinica, ;2001, 17(11): 1040-1044. doi: 10.3866/PKU.WHXB20011116 shu

Reformulation of two Ni(Ⅱ)-8-hydroxyquinoline complexes from Calculated Structure Factors

1.
Institute of Postgraduate Studies,University of Malaya　50603 Kuala Lumpur,Malaysia;Department of Chemistry,Xiamen University,Xiamen　361005,China

Received Date: 16 April 2001
Available Online: 15 November 2001

The compound that had been crystallographically identified as Na[NiQ2(HQ)](ClO4)(HQ=8-hydroxyqu- inoline) contains no sodium,and instead is [H3O][NiQ2(HQ)](ClO4).The lanthanum-nickel complex [YQ(HQ)2][NiQ3](ClO4) that had been similarly identified contains no yttrium,and its formula is [H3O][Ni2Q3(HQ)3](ClO4)2.The revision of the description of the crystal structures was effected by an examination of the bond dimensions that were derived by calculating the structure factors from the published atomic coordinates.
- Structure revision;Nickel(II) complex;Calculated structure factors
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