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Citation: Tang Jie-Yuan, Zhang Wen- ng, Gao Feng. Study on the Coordination Polymer of Electropolyurushiol and Rare Earth[J]. Acta Physico-Chimica Sinica, ;2000, 16(12): 1086-1092. doi: 10.3866/PKU.WHXB20001206 shu

Study on the Coordination Polymer of Electropolyurushiol and Rare Earth

1.
Institute of Polymer Science,Fujian Teachers University,Fuzhou 350007

Received Date: 28 March 2000
Available Online: 15 December 2000

The coordination polymer of rare earth was prepared by the reaction of rare earth triisopropoxide(Pr,Nd,Eu) with electropolyurushiol polymerization(EPU).The structure and properties of the coordination polymer were characteized by FI-IR,Fluorescence,XPS,DMTA and AES.The results indicated that there is of coordination interaction between rare earth ion with electropolyurushilo in the coordination polymer,thus cross-link was formed.Therefore the coordination polymer was insoluble in most organic solvects,and glass.transition temperature increase and heat resistance were enhanced considerably.
- Urushiol,
- Electrochemical polymerization,
- Rare earths,
- Coordination polymer
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