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Citation: Shao Ke, Ma Ying, Cao Ya-An, Chen Chao-Hui, Ji Xue-Hai, Yao Jian-Nian. Inclusion of Poly(TMPD) into MoO₃ via a Cooperative Formation Route[J]. Acta Physico-Chimica Sinica, ;2000, 16(10): 865-868. doi: 10.3866/PKU.WHXB20001001 shu

Inclusion of Poly(TMPD) into MoO₃ via a Cooperative Formation Route

1.
Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080

Received Date: 16 June 2000
Available Online: 15 October 2000

Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions. XRD data showed a layered structure along c axis. IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers. TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism, a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.
- Polymer/MoO3,
- Layered structure,
- Cooperative formation route
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

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Inclusion of Poly(TMPD) into MoO3 via a Cooperative Formation Route

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通讯作者: 陈斌, bchen63@163.com

Inclusion of Poly(TMPD) into MoO₃ via a Cooperative Formation Route